Electronic supplementary informations
Synthesis, crystal structure and properties of coordination polymers from copper(II) adipate
Danica Čechová Ingrid Svoboda Klaudia Jomová Zdeňka Růžičková Marián Valko Ján Moncol
Table S1 Hydrogen bonding geometry for 1–5
D—H···A
Symmetry codes
D—H (Å)
H···A (Å)
D···A (Å)
D—H···A (°)
1
O1—H1B···O3A
x, -y+1, z-1/2
1.16
1.91
2.817(13)
131
O1—H1B···O3B
x, -y+1, z-1/2
1.16
2.03
2.984(10)
137
O1—H1A···O3A
-x+1, -y+1, -z+1
1.16
1.78
2.817(13)
146
O1—H1A···O3B
-x+1, -y+1, -z+1
1.16
1.97
2.984(10)
144
N2—H2···O2A
x+1/2, -y+1/2, z+1/2
0.86
2.02
2.86(3)
165
N2—H2···O2B
x+1/2, -y+1/2, z+1/2
0.86
1.84
2.675(19)
162
O5—H50···O4
-x+1/2, y-1/2, -z+1/2
0.82
1.85
2.662(3)
171
O5—H50···O2
-x+1, -y+1, -z+1
0.80
1.94
2.691(3)
156
O6—H701···O5
-x+1, y, -z+1/2
0.81
2.03
2.834(3)
174
O6—H702···O3
-x+1, -y, -z+1
0.81
1.94
2.754(3)
178
0.82
1.88
2.699(3)
174
2
3
O7—H7A···O2
O7—H7B···N4
-x, -y+2, -z
0.82
2.66
3.224(4)
128
N3—H3A···O5
-x-1, -y+1, -z+1
0.86
2.05
2.901(3)
173
N3—H3B···O1
x-1, y, z
0.86
2.30
3.072(2)
150
N4—H4A···O6
-x, -y+3, -z
0.86
2.06
2.911(3)
172
N4—H4B···O7
-x-1, -y+2, -z
0.86
2.09
2.929(4)
165
N2—H22···O1
-x+1, -y+1, -z+1
0.84
2.14
2.933(3)
158
N2—H21···O4
-x+1, y, -z+3/2
0.85
1.99
2.828(3)
168
N3—H32···O2
-x+3/2, y+1/2, -z+3/2
0.84
2.08
2.900(3)
167
N3—H31···O3
-x+3/2, y-1/2, -z+3/2
0.85
2.14
2.986(3)
172
N2—H22···O1
-x+1, -y+1, -z+1
0.85
2.17
2.964(3)
157
N2—H21···O4
-x+1, y, -z+3/2
0.86
2.00
2.845(3)
168
N3—H32···O2
-x+3/2, y+1/2, -z+3/2
0.84
2.10
2.923(3)
168
N3—H31···O3
-x+3/2, y-1/2, -z+3/2
0.85
2.18
3.013(3)
172
O6—H6A···O7
0.87
1.95
2.822(4)
177
O7—H7D···O5
0.87
1.81
2.626(5)
156
4
4
5
O7—H7E···O5
-x+2, -y, -z+1
0.87
2.03
2.849(4)
157
O6—H6B···O2
x+1, y, z+1
0.87
2.42
3.135(4)
139
O6—H6B···O4
1+x,-1+y,1+z
0.87
2.68
3.319(4)
131
1
N2—H2···O4
x, y-1, z+1
0.88
2.11
2.932(3)
156
2
Fig. S1 The 3-D supramolecular framework of 1. The hydrogen atoms are omitted for clarity.
3
Fig. S2 The O–H∙∙∙O hydrogen bonds of 2. The hydrogen atoms are omitted for clarity.
4
Fig. S3 The N–H∙∙∙O and O–H∙∙∙O hydrogen bonds of 3. The hydrogen atoms are omitted for
clarity.
5
Fig. S4 The N–H∙∙∙O and O–H∙∙∙O hydrogen bonds of 4. The hydrogen atoms are omitted for
clarity.
6
Fig. S5 The N–H∙∙∙O hydrogen bonds of 5. The hydrogen atoms are omitted for clarity.
Fig. S6 The 3-D supramolecular framework of 2. The hydrogen atoms are omitted for clarity.
7
Fig. S7 The O–H∙∙∙O hydrogen bonds of 5. The hydrogen atoms are omitted f
8