80.0
75
70
FRL4
65
60
%T
55
50
45
40.0
4000.0
3000
2000
1500
cm-1
Fig.1:
Fig.I: FT-IR
FT-IR Spectrum
Spectrum of
of the
the ligand
ligand HL
HL
Fig. II: 1HNMR Spectrum of the ligand HL
1000
450.0
Fig. III: Mass Spectrum of the ligand HL
Fig. IV: 1HNMR Spectrum of the Zn(II) complex
Fig. V: Powder XRD pattern of the ligand HL
700
600
counts
500
400
300
200
100
0
10
20
30
40
50
60
70
2 Theta
Fig. VI: Powder XRD pattern of the Co(II) complex
80
70.0
65
60
55
50
Co[FRL4]
45
%T
40
35
30
25
20.0
4000.0
3000
2000
1500
1000
500
350.0
1000
500
350.0
cm-1
Fig. VII: IR Spectrum of Co(II) complex
63.5
60
55
50
45
Ni[FRL4]
40
%T 35
30
25
20
15
10.0
4000.0
3000
2000
1500
cm-1
Fig. VIII: IR Spectrum of Ni(II) complex
70.0
65
60
55
50
45
40
35
%T
Cu[FRL4]
30
25
20
15
10
5
0.0
4000.0
3000
2000
1500
1000
500
350.0
500
350.0
cm-1
Fig.
Fig. IX:
7: IR
IR Spectrum
Spectrum of
of Cu(II)
Cu(II) complex
complex
75.0
70
65
60
%T
Zn[FRL4]
55
50
45
42.0
4000.0
3000
2000
1500
cm-1
Fig. X: IR Spectrum of Zn(II) complex
1000
76.0
70
65
Cd[FRL4]
60
%T
55
50
45
40
35.0
4000.0
3000
2000
1500
1000
500
350.0
cm-1
Fig. XI: IR Spectrum of Cd(II) complex
75.0
70
65
60
Hg[FRL4]
55
50
45
%T 40
35
30
25
20
15
10.0
4000.0
3000
2000
1500
cm-1
Fig. XII: IR Spectrum of Hg(II) complex
1000
500
350.0