Supporting Tables Table S2. Major products detected via py-GC/MS in SbMyb60 and wild-type plants. Values are expressed as % weight of biomass and standard errors are presented. Samples with different levels are statistically different at α=0.05. Compound Retention time 1,2,4 –Trimethylbenzene Wild type MYB ZG-124-1-2a MYB ZG-129-4-10a MYB ZG-129-4-15a Group 0.00325±0.0003 (a) 0.002±0.0000 (b) 0.0015±0.0010 (b) 0.00200±0.0000 (b) Aromatic 2-Methyl naphthalene 39.92 0.00150±0.0010 (a) 0.00200±0.0000 (a) 0.00125±0.0004 (a) 0.000750±0.0004 (a) Aromatic Benzene 7.41 0.00675±0.0004 (ab) 0.00550±0.0003(b) 0.00625±0.0003 (b) 0.00775±0.001 (a) Aromatic Ethylbenzene 15.44 0.00800±0.0004 (a) 0.00575±0.001 (b) 0.00650±0.001 (b) 0.00650±0.0003 (b) Aromatic Napthalene 35.4 0.001±0.001 (a) 0.001±0.000 (a) 0.001±0.000 (a) 0.001±0.000 (a) Aromatic o-xylene 17.37 0.00375±0.0005 (a) 0.00225±0.0004 (a) 0.00300±0.0003 (a) 0.00325±0.001 (a) Aromatic p-xylene 15.87 0.0173±0.0004 (a) 0.0108±0.001 (b) 0.0108±0.001 (b) 0.0130±0.0003 (b) Aromatic Toluene 11.01 0.0705±0.007 (a) 0.0575±0.006 (a) 0.0560±0.006 (a) 0.0675±0.002 (a) Aromatic 2,3-Butanedione 6.75 0.424±0.0143 (a) 0.319±0.0191 (b) 0.316±0.009 (b) 0.339±0.007(b) Carb 0.00775±0.003 (a) 0.00450±0.002 (a) 0.00450±0.002 (a) 0.0035±0.002 (a) Carb Acetic acid 9.21 5.73±0.139 (a) 4.98175±0.205 (b) 4.328±0.211 (c) 4.61575±0.217 (bc) Carb Acetol 10.74 3.02±0.0810 (a) 1.77±0.252 (b) 1.90±0.0749 (b) 2.06±0.142 (b) Carb Levoglucosan 58.6 0.615±0.0794 (b) 1.10±0.126 (a) 0.596±0.109 (b) 0.771±0.118 (b) Carb Maltol 34.59 0.0838±0.009 (a) 0.0700±0.014 (a) 0.0695±0.010 (a) 0.06675±0.007 (a) Carb Methyl pyruvate 13.23 0.0115±0.003 (a) 0.00325±0.004 (a) 0.00975±0.004 (a) 0.0100±0.0003 (a) Carb Propanoic acid 13.63 0.347±0.007 (a) 0.199±0.028 (c) 0.2075±0.008 (bc) 0.254±0.018 (b) Carb 2(5H)-Furanone 27.47 0.381±0.0150 (a) 0.359±0.0080 (a) 0.30775±0.0170 (b) 0.373±0.00756 (a) Furan 2-Furanmethanol 20.91 0.146±0.011 (ab) 0.154±0.007 (a) 0.121±0.009 (b) 0.163±0.011 (a) Furan Furfural 18.6 0.392±0.0005 (a) 0.442±0.0005 (a) 0.273±0.0003 (b) 0.3655±0.033 (ab) Furan Hydroxymethylfurfural 45.05 0.898±0.171 (a) 1.168±0.296 (a) 0.419±0.00861 (a) 1.654±0.885 (a) Furan Acetovanillone 53.75 0.0325±0.004 (b) 0.0275±0.002 (b) 0.0448±0.002 (a) 0.0363±0.005 (ab) Guaiacol 3-Pentanone 1 Creosol (2-methoxy-4methylphenol) Guaiacol (2methoxyphenol) Guaiacylacetone 36.95 0.0278±0.00165 (a) 0.0355±0.00126 (b) 0.0323±0.00118 (b) 0.0120±0.00284 (c) Guaiacol 31.97 0.160±0.007 (ab) 0.133±0.0011 (b) 0.166±0.014 (a) 0.135±0.0011 (b) Guaiacol 55.13 0.0145±0.001 (a) 0.0135±0.002 (a) 0.0150±0.001 (a) 0.0128±0.001 (a) Guaiacol Isoeugenol 48.94 0.242±0.018 (a) 0.294±0.021 (a) 0.262±0.013 (a) 0.241±0.025 (a) Guaiacol Vanillin 40.47 0.0538±0.002 (ab) 0.0445±0.004 (b) 0.0605±0.004 (a) 0.0473±0.0002 (b) Guaiacol 2,4-Dimethylphenol 37.49 0.0153±0.0009 (a) 0.0103±0.0004 (b) 0.0118±0.0001 (b) 0.012±0.0004 (b) Phenol m-Cresol 35.29 0.0223±0.00155 (a) 0.0160±0.00408(b) 0.0188±0.00149(ab) 0.0195±0.00144 (ab) Phenol o-Cresol (2methylphenol) p-Cresol 33.58 0.0334±0.002 (a) 0.0218±0.001 (b) 0.0280±0.003 (ab) 0.0280±0.001 (ab) Phenol 34.73 0.0635±0.0068 (a) 0.06±0.0021 (a) 0.0658±0.0062 (a) 0.0715±0.0033 (a) Phenol Phenol 31.23 0.219±0.0160 (a) 0.167±0.0050 (b) 0.2405±0.0245 (a) 0.215±0.00111 (ab) Phenol Acetosyringone 63.05 0.0313±0.007 (a) 0.0258±0.001 (a) 0.0543±0.004 (b) 0.0280±0.001 (a) Syringol Syringaldehyde 60.63 0.0308±0.003 (c) 0.0473±0.003 (b) 0.0760±0.006 (a) 0.0360±0.0030 (bc) Syringol Syringol (2,6dimethoxyphenol) 45.64 0.146±0.009 (a) 0.186±0.0014 (a) 0.369±0.0030 (b) 0.191±0.0023 (a) Syringol 2