Effect of ligand exchange of Cu2ZnSnS4 nanocrystals on the charge transport and photovoltaic performance of nanostructured depleted bulk heterojunction solar cell Zhuo-Xi Zhang a,b, Zheng-Ji Zhou a,b *, Bing Bai a,b, Ming-Hua Liu a,b, Wen-Hui Zhou a,b, Dong-Xing Kou a,b, Si-Xin Wu a,b * a Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004, Henan Province, P R China b Collaborative Innovation Center of Nano Functional Materials and Applications, Henan University,Kaifeng 475004, Henan Province, P R China * Corresponding author. E-mail: zzj@henu.edu.cn, wusixin@henu.edu.cn. Fig. S1 Raman spectra of CZTS nanocrystals. Fig. S2 (ahv)2 as a function of photon energy (hv) for CZTS nanocrystals. Fig. S3 Size distribution of CTZS nanocrystals. Fig. S4 Size distribution of ZnO nanorod.