一、聚合物（polymers）
1、样品名称：C60 end-functionalized four-armed polymers
分子结构
出 处 ： Wu, Hui-Xia; Cao, Wei-Man; Cai, Rui-Fang; Song, Ying-Lin; Zhao, Li, C-60
end-functionalized four-armed polymers: synthesis and optical limiting properties, JOURNAL OF
MATERIALS SCIENCE, 42(16): 6515-6523, DOI:10.1007/s10853-007-1566-1, 2007
2、样品名称：dpff,[HgI2(doff)]
分子结构：
出 处 ： Niu, YY; Song, YL; Liu, SX; Xin, XQ, A mercury iodide adduct with
1,1-bis(diphenylphosphino)ferrocene - Synthesis, crystal structure, and nonlinear refractive
properties, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 628(1):
179-182
3 、 样 品 名 称 ： interpenetrating cationic and anionic
three-dimentsional
diamondoid
cluster
coordination
polymers
分子结构图
The cationic cluster coordination polymer unit [WS4Cu4(4,4′-bipy)4]2+.
a)
The
diamondoid
structure
of
the
cationic
b) The diamondoid structure
{[WS4Cu4I4(4,4′-bipy)2]2−}n.
of
the
anionic
cluster coordination polymer
{[WS4Cu4(4,4′-bipy)4]2+}n.
cluster coordination polymer
a) View of the cationic cluster coordination polymer. Each node and rod represents a cluster
cation [WS4Cu4]2+ and a pair of 4,4′-bipy ligands, respectively;
b) space-filling picture showing the twofold interpenetrating cationic cluster coordination polymer
{[WS4Cu4(4,4′-bipy)4]2+}n;
c) view of the anionic cluster coordination polymer. Each node and rod represents a cluster anion
[WS4Cu4I4]2− and a single 4,4′-bipy ligand, respectively;
d) space-filling picture showing the twofold interpenetrating anionic cluster coordination polymer
{[WS4Cu4I4(4,4′-bipy)2]2−}n.
The anionic cluster coordination polymer unit [WS4Cu4I4(4,4′-bipy)2]2−.
the cluster coordination polymer
Schematic view of
出处：Liang, K; Zheng, HG; Song, YL; Lappert, ME; Li, YZ; Xin, XQ; Huang, ZX; Chen, JT; Lu,
SF, Self-assembly of interpenetrating coordination nets formed from interpenetrating cationic and
anionic three-dimentsional diamondoid cluster coordination polymers, ANGEWANDTE
CHEMIE-INTERNATIONAL EDITION, 43(43): 5776-5779, DOI:10.1002/anie.200460681, 2004
4、样品名称：a new polymeric silver(I)-propyl-benzotriazole
complex
分子结构图
Two-dimensional structure of {[Ag2(pbbt)3](NO3)2·0.5H2O}n with hexagonal-shaped units (NO
was deleted for clarity).
出处：Xu, Hong; Song, Ying-Lin; Meng, Xiang-Ru; Hou, Hong-Wei; Fan, Yao-Ting; Strong
nonlinear optical effects from a new polymeric silver(I)-propyl-benzotriazole complex,
JOURNAL OF APPLIED POLYMER SCIENCE, 125(1):682-689, DOI: 10.1002/app.34872, 2012
5、样品名称：Organic-Inorganic Nanohybrids via Directly
Grafting Gold Nanoparticles onto Conjugated Copolymers
分子结构图
Chemical structure of PPE-F1-3
出处：Liu, Xiao-Feng; Zhu, Mei; Chen, Song-Hua; Yuan, Ming-Jian; Guo, Yan-Bing; Song,
Ying-Lin; Liu, Hui-Biao;Li, Yu-Liang,Organic-Inorganic Nanohybrids via Directly Grafting Gold
Nanoparticles
onto
Conjugated
Copolymers
through
the
Diels-Alder
Reaction ,LANGMUIR,24(20): 11967-11974, DOI: 10.1021/la8020639, 2008
6、样品名称：two Ag(I)-bridged metal-organic polymers
分子结构图
The synthesis of polymers 1 and 2
出处：Xu, Hong; Song, Ying-Lin; Meng, Xiang-Ru; Hou, Hong-Wei; Tang, Ming-Sheng; Fan,
Yao-Ting, Strong optical limiting effects of two Ag(I)-bridged metal-organic polymers,
CHEMICAL PHYSICS, 359(1-3):101-110, DOI: 10.1016/j.chemphys.2009.03.011, 2009
7、样品名称：Soluble functional polyacetylenes
分子结构图
Synthesis route.
出处：Su, Xin-Yan; Xu, Hong-Yao; Yang, Jun-Yi; Lin, Nai-Bo; Song, Ying-Lin, Soluble
functional polyacetylenes for optical limiting: Relationship between optical limiting properties and
molecular structure, POLYMER, 49(17): 3722-3730, DOI:10.1016/j.polymer.2008.06.022, 2008
8 、 样 品 名 称 ： Thermally stable oxadiazole-containing
polyacetylenes
分子结构图
Synthetic routes to P1 and P2
出处：Wang, Xin; Guang, Shan-Yi; Xu, Hong-Yao; Su, Xin-Yan; Yang, Jun-Yi; Song, Ying-Lin;
Lin, Nai-Bo; Liu, Xiang-Yang, Thermally stable oxadiazole-containing polyacetylenes:
Relationship between molecular structure and nonlinear optical properties, JOURNAL OF
MATERIALS CHEMISTRY, 18(35) : 4204-4209 , DOI: 10.1039/b807004k, 2008
9、样品名称：polycarbonates containingfullerene unit
分子结构图
The chemical structures of TCNEO-C60–PC and MPYLD-C60–PC
出处：Li, YL; Wang, S; Li, FY; Du, CM; Shi, ZQ; Zhu, DB; Song, YL, Preparation and optical
limiting properties of polycarbonates containing fullerene unit, CHEMICAL PHYSICS LETTERS,
337(4-6): 403-407, DOI:10.1016/S0009-2614(01)00211-1, 2001
11、样品名称：polycarbonates containing fullerene derivative
分子结构图
出处：Li, FY; Li, YL; Ge, ZX; Zhu, DB; Song, YL; Fang, GY, Synthesis and optical limiting
properties of polycarbonates containing fullerene derivative, JOURNAL OF PHYSICS AND
CHEMISTRY OF SOLIDS, 61(7): 1101-1103, DOI:10.1016/S0022-3697(99)00368-6, 2000
12 、 样 品 名 称 ： {[Zn(Ac)2(bbbm)]
(CH3OH)2}n
(bbbm=1,1-(1,4-butanediyl)
分子结构图：
出处：Xiao, B; Han, HY; Meng, XR; Song, YL; Fan, YT; Hou, HW; Zhu, Y, A helical chain
coordination polymer {[Zn(Ac)(2)(bbbm)] (CH3OH)(2)}(n) (bbbm=1,1 '-(1,4-butanediyl)
bis-1H-benzimidazole): synthesis, crystal structure and the third-order nonlinear optical property ,
INORGANIC
CHEMISTRY
COMMUNICATIONS,
7(3):378-381,
DOI:
10.1016/j.inoche.2003.12.019, 2004
13、样品名称：C60 end-functionalized four-armed polymers
分子结构
出 处 ： Wu, Hui-Xia; Cao, Wei-Man; Cai, Rui-Fang; Song, Ying-Lin; Zhao, Li, C-60
end-functionalized four-armed polymers: synthesis and optical limiting properties, JOURNAL OF
MATERIALS SCIENCE, 42(16): 6515-6523, DOI:10.1007/s10853-007-1566-1, 2007
样品名称：two Ag(I)-bridged metal-organic polymers （固体）
分子结构图
The synthesis of polymers 1 and 2
出处：Xu, Hong; Song, Ying-Lin; Meng, Xiang-Ru; Hou, Hong-Wei; Tang, Ming-Sheng; Fan,
Yao-Ting, Strong optical limiting effects of two Ag(I)-bridged metal-organic polymers,
CHEMICAL PHYSICS, 359(1-3):101-110, DOI: 10.1016/j.chemphys.2009.03.011, 2009
14、样品名称：Organic-Inorganic Nanohybrids via Directly
Grafting Gold Nanoparticles onto Conjugated Copolymers
分子结构图
Chemical structure of PPE-F1-3
出处：Liu, Xiao-Feng; Zhu, Mei; Chen, Song-Hua; Yuan, Ming-Jian; Guo, Yan-Bing; Song,
Ying-Lin; Liu, Hui-Biao;Li, Yu-Liang,Organic-Inorganic Nanohybrids via Directly Grafting Gold
Nanoparticles
onto
Conjugated
Copolymers
through
the
Diels-Alder
Reaction ,LANGMUIR,24(20): 11967-11974, DOI: 10.1021/la8020639, 2008
15、样品名称：Soluble functional polyacetylenes
分子结构图
Synthesis route.
出处：Su, Xin-Yan; Xu, Hong-Yao; Yang, Jun-Yi; Lin, Nai-Bo; Song, Ying-Lin, Soluble
functional polyacetylenes for optical limiting: Relationship between optical limiting properties and
molecular structure, POLYMER, 49(17): 3722-3730, DOI:10.1016/j.polymer.2008.06.022, 2008
16、样品名称：{[AgI(inh)]6(KI)}n
分子结构图：
出处：Niu, YY; Song, YL; Hou, HW; Zhu, Y, Synthesis, structure, and large optical limiting effect
of the first coordination polymeric cluster based on an {I@[AgI(inh)](6)} hexagram block,
INORGANIC CHEMISTRY, 44(7): 2553-2559, DOI: 10.1021/ic0487023, 2005
17 、 样 品 名 称 ： {[Zn(Ac)2(bbbm)]
(CH3OH)2}n
(bbbm=1,1-(1,4-butanediyl)
分子结构图：
出处：Xiao, B; Han, HY; Meng, XR; Song, YL; Fan, YT; Hou, HW; Zhu, Y, A helical chain
coordination polymer {[Zn(Ac)(2)(bbbm)] (CH3OH)(2)}(n) (bbbm=1,1 '-(1,4-butanediyl)
bis-1H-benzimidazole): synthesis, crystal structure and the third-order nonlinear optical property ,
INORGANIC
CHEMISTRY
COMMUNICATIONS,
7(3):378-381,
DOI:
10.1016/j.inoche.2003.12.019, 2004
18
、
样
品
名
称
：
Co(II)
coordination
polymers{[Co(H2O)2(CH3OH)2(4-bpfp)](NO3)2}n
1(4-bpfp1/4N;N-bis(4-pyridylformyl)piperazine)and[Co(NC
S)2(CH3OH)2(3-bpfp)]n
-bis(3-pyridylformyl)piperazine)
分子结构图：
2(3-bpfp1/4N;N
出处：Xu, H; Song, YL; Hou, HW, Crystal structures and third-order NLO properties in DMF
solution of Co(II)-bpfp coordination polymers (bpfp = N,N '-bis(pyridylformyl)piperazine),
INORGANICA CHIMICA ACTA, 357(12): 3541-3548, DOI:10.1016/j.ica.2004.05.007, 2004
19、样品名称：β-Ferrocenylacrylate Metal Polymers
分子结构：
Crystal structure of
[Pb6(μ2-OOCCH=CHFc)2(μ3-OOCCH=CHFc)2(μ2-η2-OOCCH=CHFc)2(η2-OOCCH=CHFc)2(μ4-O)2] (1) with heteroatom labeling scheme
Perspective view of the 1D chain structure of [Pb(η1-μ2-OOCCH=CHFc)2(phen)]n(2) with only
the heteroatoms labeled
One-dimensional chain structure of {[Cd(μ2-η2-OOCCH=CHFc)(η2-OOCCH=CHFc)
(H2O)2](H2O)4}n(3) with only heteroatoms labeled
The solid-state structure of
{[Cd(μ2-η2-OOCCH=CHFc)(η2-OOCCH=CHFc)(H2O)2](H2O)4}n(3)
ORTEP
diagram
showing
the
structure
unit
{[Cd(η2-OOCCH=CHFc)(bbbm)1.5Cl]·1.5H2O}n(4). H atoms have been omitted for clarity
Two-dimensional sheet structure of
{[Cd(η2-OOCCH=CHFc)(bbbm)1.5Cl]·1.5H2O}n(4). H atoms have beenomitted for clarity
of
出处：Li, LK; Song, YL; Hou, HW; Fan, YT; Zhu, Y, Syntheses, structures, and optical properties
of beta-ferrocenylacrylate metal polymers, EUROPEAN JOURNAL OF INORGANIC
CHEMISTRY, (16): 3238-3249, DOI: 10.1002/ejic.200500069, 2005
20、样品名称：polyacetylenes
分子结构：
a group of soluble functional polyacetylenes containing NLO chromophores
Synthesis of the functional monomer
出处：Yin, SC; Xu, HY; Shi, WF; Gao, YC; Song, YL;Wing, J; Lam, Y; Tang, BZ, Synthesis and
optical properties of polyacetylenes containing nonlinear optical chromophores, POLYMER,
46(18):7670-7677, DOI:10.1016/j.polymer.2005.05.118, 2005
21 、 样 品 名 称 ： [Mn(SO4)(4,4′-bpy)(H2O)2]n (1), and
[Mn(N3)2(4,4′-bpy)]n
(2)
and
[{Mn(NCS)2(4,4′-bpy)(H2O)2}(4,4′-bpy)]n (3)
分子结构：
3-D network structure of [Mn(SO4)(4,4′-bpy)(H2O)2]n.
diagram (30% probability
[Mn(SO4)(4,4′-bpy)(H2O)2]n
ORTEP
ellipsoids)
showing
Layered structure of [Mn(SO4)(4,4′-bpy)(H2O)2]n.
The linking modes of μ2-SO42− in [Mn(SO4)(4,4′-bpy)(H2O)2]n
the
structural
unit
of
出处：Hou, HW; Wei, YL; Fan, YT; Du, CX; Zhu, Y; Song, YL; Niu, YY; Xin, XQ, Third-order
nonlinear optical properties of three Mn(II)-4,4 '-bpy coordination polymers and crystal structure
of three-dimensional network [Mn(SO4)(4,4 '-bpy)(H2O)(2)](n), INORGANICA CHIMICA
ACTA, 319(1-2): 212-218, DOI:10.1016/S0020-1693(01)00443-1, 2001
22 、 样 品 名 称 ：
[Pb(bbbm)2(NO3)2]n
(bbbm
1,1′-(1,4-butanediyl)bis-1H-benzimidazole) 1,)
[Zn(bbbt)(NCS)2]n
1,1′-(1,4-butanediyl)bis-1H-benzotriazole)
[Zn(pbbt)(NCS)2]n
(bbbt
2,
and
(pbbt
1,1′-(1,3-) )propylene)bis-1H-benzotriazole) 3
分子结构图：
出处：Meng, XR; Song, YL; Hou, HW; Fan, YT; Li, G; Zhu, Y, Novel Pb and Zn coordination
polymers: Synthesis, molecular structures, and third-order nonlinear optical properties,
INORGANIC CHEMISTRY, 42(4): 1306-1315, DOI: 10.1021/ic0259282 , 2003
23、样品名称：
{[n-Bu4N][W2Ag3S8]}n
分子结构图：
出处： Zhou, JL; Wang, YX; Wang, Y; Song, YL; Zheng, G; Li, YZ; Yang, LP; Xin, XQ,
Synthesis, crystal structure and non-linear optical properties of the heterobimetallic polymeric
compound {[n-Bu4N][W2Ag3S8]}(n), CRYSTENGCOMM, 62-64, DOI: 10.1039/b210937a,
2003
24、样品名称：M(bbbt)2(NCS)2]n (M=Co, 1; Mn, 2; Cd, 3)
分子结构图：
出处： Hou, HW; Meng, XR; Song, YL; Fan, YT; Zhu, Y; Lu, HJ; Du, CX; Shao, WH,
Two-dimensional rhombohedral grid coordination polymers [M(bbbt)(2)(NCS)(2)](n) (M=Co, Mn,
or Cd; bbbt=1,1 '-(1,4-butanediyl) bis-1H-benzotriazole): Synthesis, crystal structures, and
third-order nonlinear optical properties , INORGANIC CHEMISTRY, 41(15): 4068-4075, DOI:
10.1021/ic0255858, 2002
25 、 样 品 名 称 ： ferrocenylthiocarboxylate-containing
coordination compounds
分子结构图
(a) Perspective view of the repeating unit in [Cd2(η2-SOCFc)2(η1- μ2-SOCFc)2(4,4′-bpy)]n (1).
(Hydrogen atoms are omitted for clarity.) (b) A segment of the 1-D polymer 1.
ORTEP drawing with atom-labeling scheme of the one-dimensional chain polymer
[Cd(SOCFc)2(tmp)]n (2). (Hydrogen atoms are omitted for clarity.)
出处：Yang, Hai-Yan; Li, Lin-Ke; Song, Ying-Lin; Hou, Hong-Wei; Fan, Yao-Ting, Syntheses and
characterization of ferrocenylthiocarboxylate-containing coordination compounds for nonlinear
optics, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 693(15): 2624-2630,
DOI:10.1016/j.jorganchem.2008.05.017, 2008
26、样品名称： [Cd(btx)2) (NO3)2]n (1),[Cd(btx)2Cl2]n (2),
[Cd(btx)(SO4)(H2O)2]n (3), and [Cd(btx)(S2O7)(H2O)]n (4)
分子结构图：
出处：Meng, XR; Song, YL; Hou, HW; Han, HY; Xiao, B; Fan, YT; Zhu, Y, Hydrothermal
syntheses, crystal structures, and characteristics of a series of Cd-btx coordination polymers
(btx=1,4-bis(triazol-1-ylmethyl)benzene), INORGANIC CHEMISTRY, 43(11): 3528-3536, DOI:
10.1021/ic0354670, 2004