KINETICS OF REACTION OF TRIETHYLAMMONIUM
CARBOXYLATES WITH ALPHA-HALOGENO CARBONYLCOMPOUNDS IN ORGANIC-SOLVENTS .3. EFFECT OF
SOLVENTS ON THE REACTION OF PHENACYL BROMIDE
WITH TRIETHYLAMMONIUM ACETATE
By:PILLAY, MK (PILLAY, MK); MUTHULAKSHMI, B (MUTHULAKSHMI, B)
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL
THEORETICAL & ANALYTICAL CHEMISTRY
Volume: 31
Issue: 7
Pages: 427-431
Published: JUL 1992
View Journal Information
Abstract
Kinetics of the reaction of phenacyl bromide with acetic acid in the presence of triethylamine in
aqueous acetone and in various solvents have been investigated. The rate constant of the reaction is
50 to 300 times higher in aprotic solvent than in protic solvents. The simple regression and multiple
regression of log k2 with various solvent parameters have led to the conclusion that in addition to the
solvent polarity, various other solvent properties simultaneously influence the reaction rate.
Keywords
KeyWords Plus:ACETONE; ACIDS
Author Information
Reprint Address: PILLAY, MK (reprint author)
BHARATHIDASAN UNIV,DEPT CHEM,TIRUCHCHIRAPPALLI 620024,INDIA.
Publisher
COUNCIL SCIENTIFIC INDUSTRIAL RESEARCH, PUBL & INFO DIRECTORATE, NEW DELHI
110012, INDIA
Categories / Classification
Research Areas:Chemistry
Web of Science Categories:Chemistry, Multidisciplinary
Document Information
Document Type:Article
Language:English
Accession Number: WOS:A1992JB68700008
ISSN: 0376-4710
Other Information
IDS Number: JB687
Cited References in Web of Science Core Collection: 21
Times Cited in Web of Science Core Collection: 2