524B-Assignment1 Solutions

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CE/ABE/ENSCI 524B – Assignment #1 Solutions
Global Atmospheric Change
8.1
Suppose the ratio of (18𝑂 ⁄16𝑂 ) in standard ocean water is 0.00200. If another sample of ocean water
has an (18𝑂 ⁄16𝑂 ) ratio of 0.00199, what would be the value of 𝛿18𝑂 ? Would the sample correspond to
a warmer or colder climate?
The principle used is that less ice on Earth leads to more dilution with lighter water and
therefore a warmer climate.
(18𝑂 ⁄16𝑂 )π‘ π‘Žπ‘šπ‘π‘™π‘’
0.00199
οƒΌ 𝛿18𝑂 = [(18
𝑂 ⁄16𝑂 )π‘ π‘‘π‘Žπ‘›π‘‘π‘Žπ‘Ÿπ‘‘
− 1] × 103 = [0.00200 − 1] × 103 = −5.
οƒΌ The sample with a ratio of 0.00199 , would correspond to a warmer climate. A lower
(18𝑂 ⁄16𝑂 ) ratio means a lower amount of 18𝑂 . A lower amount of 18𝑂 in ocean water
means warmer temperatures.
8.2
A relationship between the mean annual surface temperature of Greenland and the value of
𝛿18𝑂 of the snow pack on the Greenland ice sheet is given by
𝑇(℃) = 1.5𝛿18𝑂 (0⁄00) + 20.4
An ice core sample dating back to the last glaciations has a value of 𝛿18𝑂 equal to −35. What
would the estimated surface temperature have been at that time?
οƒΌ 𝑇(℃) = 1.5𝛿18𝑂 (0⁄00) + 20.4 = 1.5(−35) + 20.4 = −32.1℃.
8.5
The solar flux 𝑆 arriving at the outer edge of the atmosphere varies by ±3.3 π‘π‘’π‘Ÿπ‘π‘’π‘›π‘‘ as the
earth moves in its orbit (reaching its greatest value in early January). By how many degrees
would the effective temperature of the earth vary as a result?
οƒΌ The solar flux 𝑆, arriving at the outer edge of the atmosphere, is represented by the solar
π‘Š
constant of 1,370 π‘š2 . For this problem we are assuming that the solar flux varies by
π‘Š
±3.3 π‘π‘’π‘Ÿπ‘π‘’π‘›π‘‘ as the earth moves in its orbit. So, 𝑆 = 1,370 ± 45.21 π‘š2 .
οƒΌ We also know that the energy absorbed by Earth is π‘†πœ‹π‘… 2 (1 − 𝛼) and the energy radiated
back to space by earth is 𝜎4πœ‹π‘… 2 𝑇𝑒 4 , assuming that the earth is a blackbody and behaves
according to the Stefan-Boltzmann Law.
οƒΌ As we know that the energy absorbed by Earth equals the energy radiated back to space,
we can set the two equations equal and solve for the effective blackbody temperature.
1
π‘†πœ‹π‘…
2 (1
2
4
− 𝛼) = 𝜎4πœ‹π‘… 𝑇𝑒 . This leads us to 𝑇𝑒 =
𝑆(1−𝛼) 4
[ 4𝜎 ] .
π‘Š
οƒΌ The average albedo for Earth constant, 𝛼 = 0.31. We also know that 𝜎 = 5.67 × 10−8 π‘š2 𝐾4 ,
where 𝜎 is the Stefan-Boltzmann Constant. We also know, from previously, that
π‘Š
οƒΌ 𝑆 = 1,370 ± 45.21 π‘š2 . Using these quantities and solving for 𝑇𝑒 , we get 𝑇𝑒 =
1
π‘Š
1,370±45.21 2 (1−0.31) 4
π‘š
[
π‘Š
4(5.67×10−8 2 4 )
π‘š 𝐾
] = 254 ± 2 𝐾. The earth would vary from 252 𝐾 to 256 𝐾
Any atmospheric heat retention has been ignored, but the 4K variation is correct.
8.8
π‘Š
In Figure 8.13, the average rate at which energy is used to evaporate water is given as 78 π‘š2 .
Using 2465 π‘˜π½/π‘˜π‘” as the latent heat of vaporization of water, along with the surface area of the
earth, which is about 5.1 × 1014 π‘š2 , estimate the total world annual precipitation in π‘š3 /π‘¦π‘Ÿ
(which is equal to the total water evaporated). Averaged over the globe, what is the average
annual precipitation in meters of water?
o Assuming average conditions everywhere and also that there is enough water for
evaporation everywhere, we can estimate what the total world annual precipitation in
π‘š3 /𝑦 would be. This is not realistic, of course.
π‘Š
o Using the average rate at which energy is used to evaporate water, 78 π‘š2 , and the
surface area of the earth, we can solve for the total power used to evaporate water over
the surface of the earth.
78 π‘Š
π‘š2
5.1 × 1014 π‘š2 = 3.978 × 1016 π‘Š =
3.978×1016 𝐽
𝑠
=
3.978×1013 π‘˜π½
𝑠
.
o Using the total power used to evaporate water over the surface of the earth, we can
solve for the total energy used to evaporate water over the surface of the earth in the
course of a year.
3.978×1013 π‘˜π½ 3600 𝑠 24 β„Ž 365 𝑑
𝑠
β„Ž
𝑑
𝑦
=
1.25×1021 π‘˜π½
𝑦
.
o Using the latent heat of vaporization of water, we can solve for the total mass water
evaporated from the total energy used to evaporate water per year.
5.08×1017 π‘˜π‘”
𝑦
1.25×1021 π‘˜π½
π‘˜π‘”
π‘¦π‘Ÿ
2465 π‘˜π½
=
.
o Using the density of water, we can solve for the total volume of water evaporated from
the total mass of water evaporated =
5.09×1017 π‘˜π‘”
𝑦
π‘š3
=
1000 π‘˜π‘”
5.09×1014 π‘š3
𝑦
, a rough estimate
of the total volume of precipitation per year, worldwide is therefore 5.09 × 1014 π‘š3 .
o By dividing by the surface area of the earth, we can find the average annual
precipitation in meters of water.
5.09×1014 π‘š3
5.1×1014 π‘š2
= 0.998 π‘š, say 1m.
A better approach would have been to accept water for evaporation only available on 70% of the
Earth’s surface, but that precipitation is spread over all of Earth. That would result in an average
rainfall of 0.7m per year on average, which is close to reality.
8.14
The radiative forcing as a function of concentration for 𝑁2 𝑂 is modeled as a square root
dependence:
Δ𝐹 = π‘˜2 (√𝐢 − √𝐢0 )
Assuming it has been in that region since preindustrial times when the concentration was
275 𝑝𝑝𝑏, find an appropriate π‘˜2 if the current concentration is 311 𝑝𝑝𝑏 and the forcing is
π‘Š
estimated to be 0.14 π‘š2 . Estimate the added radiative forcing in 2100 if it reaches a
concentration of 417 𝑝𝑝𝑏.
(a) Find an appropriate π‘˜2 if the current concentration is 311 𝑝𝑝𝑏
οƒΌ Using the preindustrial concentration for nitrous oxide, listed on page 481, we know that
π‘˜2 = (
Δ𝐹
√𝐢−√𝐢0
=(
)
0.14 π‘Š π‘š−2
√311−√275)
= 0.133.
(b) Estimate the added radiative forcing in 2100 if it reaches a concentration of 417 𝑝𝑝𝑏
οƒΌ Using the π‘˜2 that we calculated for nitrous oxide, we can solve for the added radiative
forcing, if the concentration reaches 417 𝑝𝑝𝑏. The added forcing that results from an
increase in concentration from 311 𝑝𝑝𝑏 in 2010 to 417 𝑝𝑝𝑏 in 2100 is Δ𝐹 = π‘˜2 (√𝐢 −
π‘Š
√𝐢0 ) = 0.133(√417 − √311) = 0.371 π‘š2 .
8.20
Compute the global warming potential for a greenhouse gas having atmospheric lifetime 𝜏 =
42 π‘¦π‘’π‘Žπ‘Ÿπ‘  and relative forcing per unit mass that is 1630 times that of 𝐢𝑂2 over the following
time periods:
οƒΌ To calculate the Global Warming Potential (GWP) of a gas we need to know the radiative
forcing of the gas, 𝐹𝑔 , the exponential decay of that gas, 𝑅𝑔 (𝑑), and the time period for
cumulative effects, 𝑇, and use them in the equation
𝑇
πΊπ‘Šπ‘ƒπ‘” =
∫0 𝐹𝑔 βˆ™ 𝑅𝑔 (𝑑) 𝑑𝑑
𝑇
∫0 𝐹𝐢𝑂2 βˆ™ 𝑅𝐢𝑂2 (𝑑) 𝑑𝑑
.
οƒΌ In this problem, we know the relative forcing as compared to carbon and we know the
atmospheric lifetime, which gives us the exponential decay function of the gas 𝑅𝑔 (𝑑) =
𝑑
𝑅0 𝑒 −42 .
Assuming an average lifetime of 100 years for CO2, and a decay function of
𝑑
𝑅𝐢𝑂2 (𝑑) = 𝑅0 𝑒 −100
The GWP for three different time periods are as follows.
(a) 20 years
𝑇
a. πΊπ‘Šπ‘ƒπ‘” =
b. πΊπ‘Šπ‘ƒπ‘” =
𝑇
∫0 𝐹𝐢𝑂2 βˆ™π‘…πΆπ‘‚2 (𝑑) 𝑑𝑑
1630(−26.09+42)
(−81.87+100)
=
20
−
1630𝐹𝐢𝑂2 ∫0 𝑅0 𝑒 42 𝑑𝑑
𝑑
20
−
𝐹𝐢𝑂2 ∫0 𝑅0 𝑒 100
0
−
−
1630[(−42𝑒 42 )−(−42𝑒 42 )]
𝑑
20
∫0 𝐹𝑔 βˆ™π‘…π‘” (𝑑) 𝑑𝑑
=
𝑑𝑑
20
0
−
−
[(−100𝑒 100 )−(−100𝑒 100 )]
=
1630(−26.09+42)
.
(−81.87+100)
= 1431
(b) 100 years
a. πΊπ‘Šπ‘ƒπ‘” =
b. πΊπ‘Šπ‘ƒπ‘” =
𝑇
∫0 𝐹𝑔 βˆ™π‘…π‘” (𝑑) 𝑑𝑑
𝑇
∫0 𝐹𝐢𝑂2 βˆ™π‘…πΆπ‘‚2 (𝑑) 𝑑𝑑
1630(−3.88+42)
(−36.7+100)
=
𝑑
100
−
1630𝐹𝐢𝑂2 ∫0 𝑅0 𝑒 42 𝑑𝑑
𝑑
100
−
𝐹𝐢𝑂2 ∫0 𝑅0 𝑒 100 𝑑𝑑
100
0
−
−
1630[(−42𝑒 42 )−(−42𝑒 42 )]
=
=
100
0
−
−
[(−100𝑒 100 )−(−100𝑒 100 )]
= 983
(c) 500 years
𝑇
a. πΊπ‘Šπ‘ƒπ‘” =
b. πΊπ‘Šπ‘ƒπ‘” =
∫0 𝐹𝑔 βˆ™π‘…π‘” (𝑑) 𝑑𝑑
𝑇
∫0 𝐹𝐢𝑂2 βˆ™π‘…πΆπ‘‚2 (𝑑) 𝑑𝑑
500
=
1630(−0.0002838+42)
(−0.6738+100)
1630𝐹𝐢𝑂2 ∫0
500
𝐹𝐢𝑂2 ∫0
= 689
500
𝑑
−
𝑅0 𝑒 100 𝑑𝑑
0
−
−
1630[(−42𝑒 42 )−(−42𝑒 42 )]
𝑑
−
𝑅0 𝑒 42 𝑑𝑑
=
500
0
−
−
[(−100𝑒 100 )−(−100𝑒 100 )]
.
1630(−3.88+42)
.
(−36.7+100)
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