Chemistry Topic 2 Atoms and elements Improving practical work Introduction This topic does not lend itself easily to laboratory practical work. This is because it is not possible to observe atoms directly. The concept of atoms is abstract – it is a model used to explain observations. However, by providing practical activities in which students observe chemical and physical changes, you can encourage them to think about the changes that occur at the particle level and provide opportunities for them to use their new level of understanding when discussing laboratory chemistry. The practical detailed here will give students such an opportunity by guiding them through a simple physical change, leading to an explanation of what happens at the particle level during a chemical reaction. The use of atomic models, either pre-purchased or created using modelling dough and cocktail sticks, will increase engagement and allow the abstract ideas presented here to become concrete. If students are first allowed to create 3D models, they will find it easier to visualise the atomic make-up of a substance and later to represent it on paper. A few ideas for some classic practical activities Investigating samples and molecular make-up Prepare samples of a range of elements for students to look at – create accompanying atomic models or prepare atomic diagrams so they can begin to link names to molecular make-up. A good representative set of samples and models would be hydrogen (H2), oxygen (O2) and chlorine (Cl2); a range of metals with images of the solid particle diagram (molecular modelling kits are not appropriate for metals as they cannot show the nature of the metallic bond); and coal, where the accompanying atomic model is a single black atom of carbon. Investigating elements reacting with water Students can investigate elements and their reactions with water and air – the rusting of iron and the conditions required for this to take place is a straightforward investigation which highlights planning a fair test and the relative speed of chemical changes. Three tests tubes can be prepared into which an iron nail is placed: air (in which the iron will rust, owing to the moisture in the air); boiled water with a layer of oil (boiling eliminates oxygen from the water and the oil keeps the oxygen away from the nail, which therefore will not rust); and air with calcium chloride and a bung (CaCl2 is a drying agent which eliminates the water and so prevents rusting). These can be left for a week and then viewed again, or ask the technicians to prepare a set in advance so you can show the one made earlier, stressing the time it took for the reactions to occur. Investigating the properties of elements Students can investigate the properties of elements, defining them as metal and non-metal or grouping them according to their states at room temperature. They can also group them according to other easily tested properties. An engaging way to do this is to present groups of students with Teach Better KS3 Chemistry Dynamic Learning © Hodder and Stoughton 2013 1 Chemistry • Topic 2 • Atoms and elements some labelled samples for which they are to create an identification key, together with suitable apparatus for carrying out tests on their samples. Also provide each group with a second set of the same samples marked with letters only. Once the keys have been prepared, take in the labelled samples. Groups then swap samples, testing equipment and keys, and identify the unlabelled samples. A good set of examples would be: iron (magnetic) copper (will conduct electricity but not magnetic) calcium (will not conduct but will react with water) carbon powder (will not conduct and will not react with water). You would need to provide ways of testing conduction of electricity, reaction with water and magnetic properties. A second set could be: zinc (solid and reacts with acid) carbon powder (solid but won’t react with acid) oxygen gas sealed in a test tube (a gas and will re-light a glowing splint) carbon dioxide, again sealed in a test tube (can be air – a gas and won’t re-light a glowing splint). You would need to provide 1 M HCl, glassware, a lit Bunsen and splints. Students may need to be prompted to make the first classification of solid or gas. Teacher demonstrations Iron and sulfur Comparisons of elements and the compounds they form is an engaging and often awe-inspiring activity. The classic teacher demonstration of iron reacting with sulfur allows a comparison of the properties of the reactants, iron and sulfur, and the properties of the compound, iron sulfide. Properties that can be compared include colour, magnetic properties and density. For instructions, follow this link to the Nuffield Foundation website and search for ‘iron and sulfur reaction’: www.nuffieldfoundation.org/ This idea can be extended to class activities comparing other elements and compounds: water with samples of hydrogen and oxygen a copper sulfate crystal with samples of copper, sulfur and oxygen calcium carbonate with samples of calcium metal, carbon and oxygen. Sodium and chlorine Another excellent teacher demonstration is the reaction of sodium metal with chlorine gas to make sodium chloride. Again, for instructions, follow the link above to the Nuffield Foundation website and search for ‘heating Group 1 metals in air and chlorine’. This is a visually spectacular experiment and students’ familiarity with the properties of the product (table salt) can enhance their engagement with the properties of the reactants, especially the toxic nature of chlorine. Teach Better KS3 Chemistry Dynamic Learning © Hodder and Stoughton 2013 2 Chemistry • Topic 2 • Atoms and elements Practical work in everyday teaching Here are a few ideas to help you incorporate skills building for practical work into your everyday lessons on this topic. Always show students samples of any elements you make reference to. This helps to keep an abstract idea rooted in the concrete, observable arena. Make use of practical starter activities, such as providing a sample of an element and asking students to investigate a specified property: ‘does your sample float on water?’ or ‘is your sample magnetic?’ Have a set of testing equipment available every lesson including ice cream tubs to fill with water, a set of magnets, a power pack and wires with a bulb to test electrical conductivity and nails to test hardness. Students can then develop the skill of selecting equipment to investigate properties of materials. Some good examples which work well include copper, iron, aluminium foil, graphite (carbon) and sulfur. Offer a model for measuring the mass of atoms. You can use finding the mass of a grain of sand as an analogy for how scientists could find the mass of an atom. Show students that one grain of sand does not register on an electronic balance. Give them a tub of sand and ask them to plan how they could determine the mass of a single grain of sand. They should present a results table, with headings and units, and the calculation required. Students will quickly arrive at the idea of measuring a sample and dividing the mass by the number of sand grains – however, the trick is to have a sample small enough so they do not need to count out thousands of sand grains but large enough to register on the balance. The results table should include – mass, number of grains of sand and the calculation mass/number of grains. They should include five different sample sizes to identify a trend (in this case a linear relationship) and three repeats to ensure reliability. If time allows, a graph could be drawn where the gradient of the (hopefully straight) line will be the mass of one grain of sand. Activity: Investigating atoms Follow this link to a video of this practical activity: Video: Investigating atoms. The aim is to allow students to make links between observation and particle theory ideas, and begin to write word equations using state symbols. The worksheet for the practical activity gives directions for three simple experiments: melting, dissolving and a chemical reaction. Each one is performed quickly by students in pairs at their bench. There should be adequate time for all three in a lesson. If other activities also need to be completed, students could complete the experiments, record their observations and develop their explanations for homework. The questions progress in terms of complexity of concepts and the demand of the particle diagrams. Depending on the placement of the topic you may need to recap how to represent solutions and diatomic elements, and how to draw substances made of different atoms. The activity will work equally well if these ideas have yet to be studied, but the level of detail expected in the particle diagrams will need to be adjusted. Follow this link for the student worksheet: Activity: Investigating atoms. Teach Better KS3 Chemistry Dynamic Learning © Hodder and Stoughton 2013 3 Chemistry • Topic 2 • Atoms and elements Answers to the activity Experiment 1 This is a change of state. Students should choose a representation of the solid wax and show a solid formation change to liquid and back to solid. All particles should be drawn to be identical throughout. Experiment 2 Experiment 2 is dissolving. Students should represent water as a liquid and sodium chloride as a solid (depending on approach and timing of this activity, students may represent sodium and chlorine as two different atoms or as one – either is fine if appropriate for the class). The final box must show both water and dissolved sodium chloride – based on the note above, if they show sodium chloride as two atoms, these must then be separated in the solution; if they have not made this distinction for compounds then the same representation, but spread through the water, is acceptable. Teach Better KS3 Chemistry Dynamic Learning © Hodder and Stoughton 2013 4 Chemistry • Topic 2 • Atoms and elements Experiment 3 This is a chemical change. Magnesium should be represented as a solid and hydrochloric acid as a solution – liquid formation showing water and hydrochloric acid (the representation of the acid will depend on placement of this topic before or after understanding acids as solutions. Judge the expected level of detail for your class.) The products show hydrogen as a gas (diatomic if this idea has been covered) and magnesium chloride solution. Hazard assessment Safety glasses needed for 1 M acid Usual laboratory safety around heating – standing, hair tied back and procedure if burnt Technician notes Equipment needed Each pair of students will need: A sample of solid steric acid set up in a boiling tube Bunsen burner, mat Boiling tube holder Measuring cylinder Boiling tube and boiling tube rack Spatula Sodium chloride solid 1 M HCl Mg pieces Procedure The procedure is described on the student worksheet. Teach Better KS3 Chemistry Dynamic Learning © Hodder and Stoughton 2013 5