Study Buddy Unit 2: Energy and States of Matter (STATES) Terms Compressibility Pressure Temperature Energy Kinetic Molecular Theory (KMT) Ideal Gas Description Symbol Unit A measure of how much the volume of matter decreases under pressure. Results from the force exerted by a gas per unit P mmHg, surface area of an object atm, kPa °C, K A measure of the average kinetic energy of T particles in matter The capacity for doing work or producing heat J, cal Joule, calorie Assumes gas particles: 1. Do not attract or repel, 2. Are spread out 3. Are constantly moving, 4. Have elastic collisions. A theoretical gas that perfectly follows the gas laws at all conditions of pressure and temperature Representations: Solid Liquid Gas Particle Model Attraction between particles Space between particles Shape Volume Compressibility High Medium Low a. particles do not attract or repel no forces shown Low; packed tightly Definite Medium High; lots of space Indefinite b. particles are spread out lots of space between Definite or fixed Almost none Definite or fixed Almost none Indefinite Indefinite Easily compressed Why are gases more easily compressed than solids or liquids? Gases have an indefinite shape and volume because there is so much space between the particles. Gas particles can compress easier because of the empty space between the particles. Identify the particle diagrams below as showing kinetic or potential energy. Then, explain which in each pair is showing higher energy and why. A. B. Kinetic energy. The left diagram shows larger arrows, which indicates faster motion and more KE. 9/2/15 Draw gas particles in the balloon that show the KMT properties. In a few words, tell how each is shown. Potential energy. The right diagram shows more space between the particles, which indicates the particles are further apart and have more energy due to their position and thus more PE. c. particles are constantly moving shown by arrows d. particles have elastic collisions when they hit each other, particles bounce off On each SCUBA tank, draw and explain these terms and what particles would have to do to increase each variable: 1. temperature Temp. is a measurement of average kinetic energy, so higher temperature is shown by particles moving faster (longer arrows). 2. pressure Pressure is caused by particles hitting the sides of the container and bouncing off. Higher pressure is caused by particles hitting the container more frequently or with more force. SCIE_CHEM_STATES_MAT_STUDYBUDDYTE_AL copyright © CFISD 2015 1 Gas Pressure, Volume, Temperature, and number of Moles Relationships Look at each gas situation below. Then, determine the change in the missing pressure, volume or temperature. Before After Before After Before After Before After Before After Before After Before After Gas Laws *Make sure to use your STAAR Chemistry Reference Materials* Value with Units 0°C and 1 atm Standard Temperature and Pressure (STP) Volume of ideal gas at STP Kelvin conversion Pressure conversion Ideal gas constant (R) 22.4 L/mol 0°C = 273 K or K = °C+273 1 atm = 760 mmHg = 101.3 kPa 0.0821 L*atm/mol*K (or others) For each pair of variables, draw a line representing their relationship and label as direct or inverse. P P V Inverse 9/2/15 P n V T Direct Direct V T n Direct Direc What volume at STP do 2.00 moles of Oxygen gas (O2) occupy? Show all work in your calculations. T = 0°C = 273K P = 1 atm n = 2.00 mol PV = nRT (1 atm)(V)=(2 mol)(0.0821 L*atm/mol*K)(273K) V = 44.8 L Does your answer make sense? Why? This answer makes sense because 1 mole of an ideal gas at STP is 22.4 L, so 2 moles should be double 22.4, which is 44.8 L. SCIE_CHEM_STATES_MAT_STUDYBUDDYTE_AL copyright © CFISD 2015 2