Nano”Teach”nology and NanoFluids Subject Area(s) Physical Science, Science and Technology Associated Unit Matter/Energy Lesson Title Making Ferrofluids Header Image file: ferrofluidspikes.jpg ADA Description: A ferrofluid in a glass container with a magnet underneath. Source/Rights: magnet.engr.uga.edu Grade Level Time Required 8 2 Fifty five minute sessions Summary Mixtures, Solutions, Energy Input/output Engineering Connection Engineers are using nanofluids for a variety of applications. They are used in devices and applications that the students are familiar with such as their cell phones, the field of medicine (nanofluids with cortisol), cooling of computers and other machines, etc. This can also expose the students to many careers in this field. Engineering Category = Relating science and/or math concept(s) to engineering Keywords matter, substance, solid, liquid, gas, fluid, temperature, thermal energy, heat, melting point, freezing, vaporization, evaporation, boiling, boiling point, condensation, particle Educational Standards NEXT GENERATION SUNSHINE STATE STANDARDS 2009-2015 Big Idea 8: Physical Science SC.8.P.8.4 Classify and compare substances on the basis of characteristic physical properties that can be demonstrated or measured; for example, density, thermal or electrical conductivity, solubility, magnetic properties, melting and boiling points, and know that these properties are independent of the amount of the sample. Big Idea 8: Properties of Matter Version: August 2013 1 SC.8.P.8.1 Explore the scientific theory of atoms (also known as atomic theory) by using models to explain the motion of particles in solids, liquids, and gases. Big Idea 9: Changes in Matter SC.8.P.9.3 Investigate and describe how temperature influences chemical changes. ITEEA Standard Standard 9 (F) - Design involves a set of steps, which can be performed in different sequences and repeated as needed. Standard 9 (G) - Brainstorming is a group problem-solving design process in which each person in the group presents his or her ideas in an open forum. Standard 11 (I) - Specify criteria and constraints for the design. Standard 11 (J) - Make two-dimensional and three-dimensional representations of the designed solution Standard 11 (K) - Test and evaluate the design in relation to pre-established requirements, such as criteria and constraints, and refine as needed. Standard 12 (H) - Use information provided in manuals, protocols, or by experienced people to see and understand how things work. Standard 12 (J) - Use computers and calculators in various applications Pre-Requisite Knowledge: Students should know the Nano scale, they should be familiar with some measurement conversions, and students should also have a basic knowledge of the scientific method, lab safety and equipment and creating a lab report. Students should be able to distinguish between types of mixtures (heterogeneous and homogenous). They should know all the forms of matter (elements, compounds and mixtures). Learning Objectives After this lesson, students should be able to: Undertake a design project to construct, test, and modify a device that either releases or absorbs thermal energy by chemical processes. Understand what nanofluids are and their significance in today’s society. Use the scientific process to complete a lab activity. Work cooperatively to complete a lab and analyze the data. Explain what applications that nanofluids are used for. Understand the difference between a ferrofluid and a nanofluid. Create an experiment for a particular investigation. Version: August 2013 2 Introduction / Motivation First I will show the students the YouTube video “How to Make Magnetic Fluid (Ferrofluid)” https://www.youtube.com/watch?v=vsQh1AT6qUE The students will then see the procedure, materials and process. This should motivate them to want to create their own ferrofluid and maybe try some modifications to the mixture. Lesson Background & Concepts for Teachers In the “references” section of the lesson plan are some good resources to read on nanofluids. The papers explain what they are and the many findings and difficulties in research. It also goes over what the current applications are for the nanofluids in today’s studies. Image Some examples of the Nano Scale (Picture from Saidur, Leong, & Mohammad 2011) see references Vocabulary / Definitions Word Definition Nanofluid A fluid containing nanometer-sized particles, called nanoparticles. These fluids are engineered colloidal suspensions of nanoparticles in a base fluid. The nanoparticles used in nanofluids are typically made of metals, oxides, carbides, or carbon nanotubes Colloidal suspension The term colloidal suspension is referring to a substance that has a solid permanently Version: August 2013 3 suspended in a liquid. Nanoparticle Nanotechnology Ferrofluid Surfactant Particles between 1 and 100 nanometers in size. The branch of science/technology that deals with dimensions and tolerances of less than 100 nanometers (nm). Control and manipulation of 100120 nm scale. a fluid containing a magnetic suspension a substance that tends to reduce the surface tension of a liquid in which it is dissolved Associated Activities Introduction This is an Inquiry Lab about making your own Ferrofluid. Students will be divided into groups of 3-4. Groups will have assigned jobs: Project Director, Safety Director, Technical Manager, and Materials Manager. Before experimentation, students will be completing the first part of their lab report. This includes Problem Statement, Hypothesis, Materials, Procedures, Variables and Data Set Up. This requires them to create or come up with their own experiment with the ferrofluids they create. Students (in their groups) will use available materials to experiment and collect data for their investigation. Materials Needed: MICR Toner (Amazon.com) Earth magnet (Neodymium magnets from Fischer Scientific) Pure Vegetable Oil (Grocery) Beakers Graduated Cylinders Stirring rods Test tubes with caps Plastic Bowls Distilled water Thermometers Iron Filings Version: August 2013 4 Safety Materials: Goggles, gloves, apron or shirt Procedures (Sample): 1) Pour about 50 mL of Magnetic Ink into container. 2) Pour about 2 tablespoons (30 mL) of vegetable oil in same container. 3) Stir it until you get a nice thin consistency. More oil may need to be added depending on amount of Ink. 4) Pour into a smaller jar or Erlenmeyer flask. 5) Test the fluid by holding the magnet under the jar or flask. 6) It may require a surfactant if result is not adequate. 7) Continue with experimentation and record data. Final Lab Report should include: Start-End Date, Title, Benchmarks, Problem Statement, Hypothesis, Variables, Materials, Procedures, Data (Table and graph min), Results/Discussion and Conclusion (CER) Lesson Closure Lesson will conclude with a peer evaluation and discussion session (3rd session). This will involve the students critique and scoring of their peer’s presentations. Individuals will use the rubric and additional aspects to rubric to rate the work. This will involve an explanation of what worked (strengths) and what did not work (weaknesses). The discussion will review the warm and cool thoughts for each presentation. Assessment Pre-Lesson Assessment Students will have completed a PowerPoint activity differentiating ferrofluids from nanofluids Lesson Summary Assessment Lab report will be used for individual assessment. Conclusion (CER): Claim, Evidence and Reasoning. Rubric will be provided Version: August 2013 5 (see below) and students will share their conclusions with the class. Component 0 Claim - A conclusion that answers the original question. Evidence – Scientific data that supports the claim. The data needs to be appropriate and sufficient to support the claim. Reasoning – A justification that links the claim and evidence. It shows why the data count as evidence by using appropriate and sufficient scientific principles. Does not make a claim, or makes an inaccurate claim. Does not provide evidence, or only provides inappropriate evidence (evidence that does not support the claim). Does not provide reasoning, or only provides reasoning that does not link evidence to claim Level 1 Makes an accurate but incomplete claim. Provides appropriate but insufficient evidence to support claim. May include some inappropriate evidence. Provides reasoning that links the claim and evidence. Repeats the evidence and/or includes some – but not sufficient – scientific principles. 2 Makes an accurate and complete claim. Provides appropriate and sufficient evidence to support claim. Provides reasoning that links evidence to claim. Includes appropriate and sufficient scientific principles. Homework Students will bring in clothing protections and any research, extra materials or completion of lab report. Version: August 2013 6 Lab – Making Ferrofluids Start: End: Group Members (jobs): SC.8.P.8.4 Classify and compare substances on the basis of characteristic physical properties that can be demonstrated or measured; for example, density, thermal or electrical conductivity, solubility, magnetic properties, melting and boiling points, and know that these properties are independent of the amount of the sample. SC.8.P.8.1 Explore the scientific theory of atoms (also known as atomic theory) by using models to explain the motion of particles in solids, liquids, and gases. Research (Vocabulary): Nanofluid – NanotechnologyFerrofluid – Surfactant – 1 additional word Uses for ferrofluids and/or nanofluids: Problem Statement: Hypotheses: H1- H2- H3- Null Materials: Version: August 2013 7 Variables: (Test Variable (independent), Outcome (dependent), Constants, Control) Procedures: Data: (Table, Graph, Pictures) Results (paragraph): Conclusion (3 paragraphs – Claim, Evidence, Reasoning): Lesson Extension Activities (see URL) The Wheatstone bridge Homemade spectroscope Magnetic Lines Experiment Additional Multimedia Support www.BrainPop.com – Nanotechnology lesson and quiz http://nanoyou.eu/ – Great reference tool for all things Nano https://www.youtube.com/watch?v=vsQh1AT6qUE -Making Ferrofluid https://www.zotero.org/ - For organizing and citing research Redirect URL: http://thehappyscientist.com/science-experiment/magnetic-lines Version: August 2013 8 http://www.livescience.com/41548-spectroscopy-science-fairproject.html References 1) Gangadevi, R., Agarwal, S., & Roy, S. (2013). A Novel Hybrid Solar System Using Nanofluid. International Journal of Engineering, 6(6), 747–752. 2) P. Sivashanmugam. (2012). Application of Nanofluids in Heat Transfer. In An Overview of Heat Transfer Phenomena. 14 (1-30), 411-440.http://dx.doi.org/10.5772/52496 3) Saidur, R., Leong, K. Y., & Mohammad, H. A. (2011). A review on applications and challenges of nanofluids. Renewable and Sustainable Energy Reviews, 15(3), 1646–1668. http://doi.org/10.1016/j.rser.2010.11.035 4) Taylor, R., Coulombe, S., Otanicar, T., Phelan, P., Gunawan, A., Lv, W., Tyagi, H. (2013). Small particles, big impacts: A review of the diverse applications of nanofluids. Journal of Applied Physics, 113(1), 1–20. http://doi.org/http://dx.doi.org/10.1063/1.4754271 Contributors Oscar Badillo Supporting Program www.dadeschools.net/employees (Learning Village) Amazon.com – MICR Ink Refill purchase FIU RET Program 2015 Acknowledgements I would like to give a special thanks to Dr. Cheng Xian (Charlie) Lin and PhD Candidate Robel Kiflemariam for their help and mentoring during the 6 week program. I feel our time has really been a great learning experience and a life-long connection towards education. Classroom Testing Information NGSSS Standards are (AA) or Annually Assessed. These objectives will be tested during their FCAT Science Test in the spring of 2016 Version: August 2013 9