Product Name: Auto Sani Dishmate Liquid
Page: 1 of 6
This revision issued: August, 2013
Chemical nature:
Trade Name:
Water solution of detergent, sodium hydroxide, sodium hypochlorite and other ingredients.
Product Use:
Creation Date:
This version issued:
Dish cleaner.
August, 2013
August, 2013 and is valid for 5 years from this date.
This product is classified as: C, Corrosive. Hazardous according to the criteria of SWA.
Dangerous according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R35. Causes severe burns.
Safety Phrases: S20, S23, S28, S36, S46, S24/25. When using, do not eat or drink. Do not breathe mists or spray.
After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing. If swallowed, contact a doctor or Poisons Information Centre immediately and show this SDS or label. Avoid contact with skin and eyes.
SUSMP Classification: S6
ADG Classification: Class 8: Corrosive Substances.
UN Number: 3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
HAZARD STATEMENT:
H290: May be corrosive to metals.
H314: Causes severe skin burns and eye damage.
PREVENTION
P234: Keep only in original container.
P260: Do not breathe fumes, mists, vapours or spray.
P264: Wash contacted areas thoroughly after handling.
P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE
P310: Immediately call a POISON CENTRE or doctor/physician.
P363: Wash contaminated clothing before reuse.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove immediately all contaminated clothing. Rinse skin with water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice.
P337+P313: If eye irritation persists: Get medical advice.
P391: Collect spillage.
P370+P378: Not combustible. Use extinguishing media suited to burning materials. Water fog or fine spray is the preferred medium for large fires.
STORAGE
P402+P404: Store in a dry place. Store in a closed container.
P403+P235: Store in a well-ventilated place. Keep cool.

Product Name: Auto Sani Dishmate Liquid
Page: 2 of 6
This revision issued: August, 2013
DISPOSAL
P501: If they can not be recycled, dispose of contents and containers to landfill (see Section 13 of this SDS).
Physical Description & Colour : Clear liquid.
Odour: Characteristic chlorine odour.
Major Health Hazards: causes severe burns.
Short Term Exposure: Available data indicates that this product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. If liquid enters nasal passages, it will cause pain and burn nasal membranes. Patients with inhalation burns may develop acute pulmonary oedema. Long Term Exposure: No data for health effects associated with long term inhalation.
Short Term Exposure: Available data indicates that this product is corrosive to the skin. Capable of causing moderate to severe burns with ulceration. Can penetrate to deeper layers of skin, resulting in third degree burns. Corrosion will continue until product is removed or neutralised. Severity depends on concentration and duration of exposure. Burns may not be immediately painful; the onset of pain may be minutes to hours. Long Term Exposure: No data for health effects associated with long term skin exposure.
Short Term Exposure : This product is very corrosive to eyes. It will quickly cause severe pain, and corrosion of the eye and surrounding facial tissues. Unless exposure is immediately treated, permanent blindness and facial scarring will occur.
Long Term Exposure : No data for health effects associated with long term eye exposure.
Short Term Exposure : Significant oral exposure is considered to be unlikely. However, this product is very corrosive to the gastrointestinal tract. Capable of causing severe burns with deep ulceration, and can penetrate to deeper layers of skin resulting in third degree burns. Corrosion will continue until product is removed or neutralised. Severity depends on concentration and duration of exposure.
Long Term Exposure : No data for health effects associated with long term ingestion.
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Ingredients CAS No
2 Peak
Sodium hypochlorite
Water
Conc,% TWA (mg/m 3 ) STEL (mg/m 3 ) Sodium hydroxide 1310-73-2 10
Other non hazardous ingredients
10022-70-5 <3 various 5-15
7732-18-5 to 100 not set not set not set not set not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a
5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the
STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times.
Have this SDS with you when you call.
Issued by: Dakota
SAFETY DATA SHEET
Phone: 02 8117 4465
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Product Name: Auto Sani Dishmate Liquid
Page: 3 of 6
This revision issued: August, 2013
Inhalation: No first aid measures normally required. However, if inhalation has occurred, and irritation has developed, remove to fresh air and observe until recovered. If irritation becomes painful or persists more than about 30 minutes, seek medical advice.
Skin Contact: Flush contaminated area with lukewarm, gently flowing water for at least 40 minutes, by the clock. DO
NOT INTERRUPT FLUSHING. If necessary, keep emergency vehicle waiting (show paramedics this MSDS and take their advice). Under running water, remove contaminated clothing, shoes and leather goods (e.g. watchbands and belts).
Strongly basic ingredients tend to penetrate the skin and so need longer rinsing than other substances. If irritation persists, repeat flushing. Seek medical attention.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for at least 60 minutes, by the clock, while holding the eyelid(s) open. Neutral saline solution may be used as soon as it is available. DO NOT
INTERRUPT FLUSHING. If necessary, keep emergency vehicle waiting (show paramedics this MSDS and take their advice). Take care not to rinse contaminated water into the unaffected eye or onto face. Call a Poisons Information
Centre or a doctor urgently. Take special care if exposed person is wearing contact lenses.
Ingestion: If swallowed, do NOT induce vomiting; rinse mouth thoroughly with water and contact a Poisons Information
Centre. Urgent hospital treatment is likely to be needed. Give activated charcoal if instructed.
Fire and Explosion Hazards : The major hazard in fires is usually inhalation of heated and toxic or oxygen deficient (or both), fire gases. There is little risk of an explosion from this product if commercial quantities are involved in a fire.
Only small quantities of decomposition products are expected from this product at temperatures normally achieved in a fire. This will only occur after heating to dryness.
Fire decomposition products from this product are likely to be irritating if inhaled.
Extinguishing Media : Not combustible. Use extinguishing media suited to burning materials. Water fog or fine spray is the preferred medium for large fires. Try to contain spills, minimise spillage entering drains or water courses. Fire
Fighting : If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal protective equipment is liquid-tight chemical protective clothing and breathing apparatus. Flash point : Does not burn.
Upper Flammability Limit: Does not burn.
Lower Flammability Limit: Does not burn.
Autoignition temperature: Not applicable - does not burn.
Flammability Class: Does not burn.
Accidental release : In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate the spill area and deny entry to unnecessary and unprotected personnel. Wear full protective chemically resistant clothing including eye/face protection, gauntlets and self contained breathing apparatus. See below under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include rubber, Viton, Nitrile, butyl rubber, Barricade, neoprene, Teflon, polyethylene, PE/EVAL, Saranex, Responder.
Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned below (section 8). Otherwise, not normally necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Because of the corrosiveness of this product, special personal care should be taken in any cleanup operation. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.
Contaminated area may be neutralised by washing with weak or dilute acid. Vinegar, citrus juice and most soft drinks may be suitable. This material may be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Handling : Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
SAFETY DATA SHEET
Issued by: Dakota Phone: 02 8117 4465
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Product Name: Auto Sani Dishmate Liquid
Page: 4 of 6
This revision issued: August, 2013 persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.
Storage : This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage of this schedule of poison. Store in a cool, well ventilated area. Check containers periodically for corrosion and leaks.
Containers should be kept closed in order to minimise contamination. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. If you keep more than 2500kg or L of Dangerous
Goods of Packaging Group II, you may be required to license the premises or notify your Dangerous Goods authority. If you have any doubts, we suggest you contact your Dangerous Goods authority in order to clarify your obligations. Check packaging - there may be further storage instructions on the label.
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set
2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
SWA Exposure Limits TWA (mg/m 3 )
2 Peak
STEL (mg/m 3 ) Sodium hydroxide
No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a fan is suggested.
Eye Protection: Your eyes must be completely protected from this product by splash resistant goggles with face shield.
All surrounding skin areas must be covered. Emergency eye wash facilities must also be available in an area close to where this product is being used.
Skin Protection: Because of the dangerous nature of this product, make sure that all skin areas are completely covered by impermeable gloves, overalls, hair covering, apron and face shield. See below for suitable material types.
Material Types: We suggest that protective clothing be made from the following materials: rubber,
Protective
Viton, nitrile, butyl rubber, Barricade, neoprene, Teflon, polyethylene, PE/EVAL, Saranex, Responder.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the
Australian Standard mentioned above. Otherwise, not normally necessary.
Safety deluge showers should, if practical, be provided near to where this product is being handled commercially.
Physical Description & colour : Clear liquid.
Odour:
Boiling Point:
Freezing/Melting Point:
Characteristic chlorine odour.
Approximately 100
°
C at 100kPa.
Below 0
°
C.
Volatiles:
Vapour Pressure:
Vapour Density:
Specific Gravity:
Water component.
2.37 kPa at 20
°
C (water vapour pressure).
As for water.
No data.
Water Solubility: Completely soluble in water. pH: Approx 14 Volatility: No data.
Odour Threshold: No data.
Evaporation Rate:
Coeff Oil/water Distribution :
Autoignition temp:
As for water.
No data
Not applicable - does not burn.
Reactivity: Most strong alkalis and bases react with inorganic and organic acids to form salts. They can also react with some metals liberating hydrogen gas. These reactions may be rapid and sometimes liberate much heat. They can also decompose many organic materials such as esters, in a reaction called hydrolysis.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30
°
C. Keep containers tightly closed. Keep containers and surrounding areas well ventilated. Incompatibilities: acids, zinc, tin, aluminium and their alloys.
Fire Decomposition: Only small quantities of decomposition products are expected from this product at temperatures normally achieved in a fire. This will only occur after heating to dryness. Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke. Water is also formed. May form hydrogen chloride gas, other compounds of chlorine. Sodium compounds. Carbon monoxide poisoning produces headache, weakness,
SAFETY DATA SHEET
Issued by: Dakota Phone: 02 8117 4465
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

Product Name: Auto Sani Dishmate Liquid
Page: 5 of 6
This revision issued: August, 2013 nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Local Effects:
Target Organs:
Ingredient
Sodium Hydroxide
There is no data to hand indicating any particular target organs.
Risk Phrases
Conc>=5%: C; R35
This product is unlikely to adversely effect the environment. Salts, acids and bases are typically diluted and neutralised when released to the environment in small quantities. However, until diluted or neutralised it will kill all aquatic organisms it contacts due to extreme pH.
Disposal: This product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to separate the contamination in some way. Only if neither of these options is suitable, consider landfill, but we recommend that it be neutralised in a controlled manner before disposal.
ADG Code: 3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
Hazchem Code: 2X
Special Provisions: 274
Limited quantities: ADG 7 specifies a Limited Quantity value of 1 L for this class of product.
Dangerous Goods Class: Class 8: Corrosive Substances.
Packaging Group: II
Packaging Method: P001, IBC02
Class 8 Corrosive Substances shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), 6
(Toxic Substances where the Toxic Substances are cyanides and the Corrosives are acids), 7 (Radioactive Substances),
Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the same freight container with Classes 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Poisonous Gases), 3
(Flammable liquids), 4.1 (Flammable Solids), 4.2 (Spontaneously Combustible Substances), 6 (Toxic Substances except where the Toxic Substances are cyanides and the Corrosives are acids) and 9 (Miscellaneous Dangerous Goods).
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredients: Sodium hydroxide, Sodium hypochlorite, are mentioned in the SUSMP.
This SDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code
AICS
SWA
CAS number
Hazchem Code
IARC
NOS
NTP
R-Phrase
Australian Code for the Transport of Dangerous Goods by Road and Rail (7 th edition)
Australian Inventory of Chemical Substances
Safe Work Australia, formerly ASCC and NOHSC
Chemical Abstracts Service Registry Number
Emergency action code of numbers and letters that provide information to emergency services especially firefighters
International Agency for Research on Cancer
Not otherwise specified
National Toxicology Program (USA)
Risk Phrase
SAFETY DATA SHEET
Issued by: Dakota Phone: 02 8117 4465
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)

SUSMP
UN Number
This revision issued: August, 2013
Standard for the Uniform Scheduling of Medicines & Poisons
United Nations Number
Product Name: Auto Sani Dishmate Liquid
Page: 6 of 6
THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD STATEMENT: INFORMATION OF THE PRODUCT
AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE
USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO
OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
This SDS is prepared in accord with the SWA document
“
Preparation of Safety Data Sheets for Hazardous
Chemicals - Code of Practice
”
(December 2011)
Copyright
©
Kilford & Kilford Pty Ltd, August, 2013. http://www.kilford.com.au/ Phone (02)9251 4532
Issued by: aiMix Chemicals Pty Ltd
SAFETY DATA SHEET
Phone: 02 9623 3288
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)