Air Quality Monitoring Lab Pre-Lab Questions: 1. Create a chart showing the six air pollutants, causes, and concerns from the information in the pre-lab. Pollutants Causes Concerns Ozone Motor vehicle exhaust and industrial emissions, gasoline vapors, and chemical solvents are some of the major sources of NOx and VOC, that help to form ozone. Ozone can irritate lung airways and cause inflammation much like sunburn. Ground-level ozone interferes with the ability of plants to produce and store food. Particulate Matter Particles are directly emitted into the air from cars, trucks, buses, factories, construction sites, tilled fields, unpaved roads, stone crushing, and burning of wood. Many health problems for example aggravated asthma, and increases in respiratory symptoms. PM is also the major cause of reduced visibility. The matter can get carried into lakes and make them acidic. Nitrogen Oxides Nitrogen oxides form when fuel is burned at high temperatures, as in a combustion process like, motor vehicles, electric utilities, and other industrial, commercial, and residential sources that burn fuels. Nitrogen oxides cause: ground level ozone, acid rain, particles, water quality detrition, global warming, toxic chemicals, and visibility impartment. Sulfur Dioxide SO2 is released to the air from electric utilities, especially those that burn coal. It can cause respiratory problems, visibility impartment, acid rain, and aesthetic damage. Lead Monoxide Lead Monoxide comes from waste incinerators, utilities, and lead-acid battery manufacturers. It can damage organs, affect the brain and nerves, damage the heart and lungs, and affect the animals. Carbon Monoxide Woodstoves, gas stoves, cigarette smoke, and unvented gas and kerosene space heaters are sources of carbon monoxide indoors. Carbon Monoxide can have major cardiovascular effect, it can damage the nervous systems, and cause smog. 2. Why is ground level ozone highest in the summer and almost nonexistent in the winter? How might this affect our results as we test the air during this part of the year? Ground level ozone is produced in the heat and sunlight, so the results might not be the same year round. 3. Many third world countries still use leaded gasoline (since they have older cars or since they have not forced changes). What concerns may the governments of these countries need to deal with? Leaded gas can cause lead monoxide which comes along with many health risk that these countries cant afford to treat. 4. Use the internet to find what parts of North Carolina are not in compliance with the Standards of the Clean Air Act. You may give either general areas or specific counties. The division of air quality says there is several plants in New Hanover county releasing a significant amount of Sulfur dioxide. Sulfur dioxide is one of six criteria or major pollutants specified in the federal Clean Air Act, it is unhealthy to breathe, can damage vegetation and materials such as buildings. Hypothesis: If filter paper is placed in the cafeteria and outside, the paper outside will receive more ozone and particulate matter then the one cafeteria Variables: Independent Variable: the filter paper placed around the school and outside. Dependent Variable: the amount of ozone and particulate matter absorbed Controlled Variables: the filter paper placed in a petrey dish. Problem: What is the air quality of Wake Forest using Ozone and PM measurements? Materials: Cornstarch Beakers Spatulas Cylinders Filter paper Test tube rack Microscope slides Petroleum jelly q-tips Microscope Potassium iodide Procedure: 1. Place the strips in and add cornstarch. Then heat and stir the mixture until it gels. Remove the solution from heat, add potassium iodide, stir, and allow cooling. After the solution has cooled, lay a piece of filter paper on a petri and brush the paste onto the filter paper. Turn the filter paper and brush the paste on the other side. Hang up and allow the filter paper to dry. Cut the papers into 1 inch-wide strips. Store the strips in a plastic bag out of sunlight. 2. Then prepare Particulate matter collectors by smearing a thin layer of petroleum jelly onto a microscope slides use a q-tip to lightly smear it each slide. Place both the strip and the paper somewhere inside and another outside. Observations and Data: The paper inside the cafeteria had more PM and ozone then the strips placed outside. The ozone strip from inside turned a dark purple, while the one placed inside was still white. The paper outside had more particle matter then the paper placed inside. Ozone Group Control 1 2 3 4 5 6 7 8 Location Classroom in petri dish Tree in courtyard Library Shop behind theatre Tree in parking lot Tree in parking lot Mr. Bullock’s room 600 stairwell inside On the ground by practice fields Cafeteria on TV Outside near the buses Boys locker room Courtyard on bush Tree corner of school building Behind a door inside Result 0 ppb 0 ppb 20 ppb 160 ppb 50 ppb 160 ppb 140 ppb 140 ppb 0 ppb 140 ppb 0 ppb 80 ppb 0 ppb 140 ppb 60 ppb Group Control 1 2 3 4 5 6 7 8 Particle Matter Location Classroom in petri dish Library Tree in courtyard Shop behind theatre Tree in parking lot No samples survived Mr. Bullock’s room Other did not survive 600 stairwell Practice fields Cafeteria Outside near the buses Boy’s locker room Outside courtyard Outside by tree corner of building Door by the stairs Result None Light Heavy None Light Light Light Light Light None None None Medium Light Data collected 9/7/12-9/10/12 Weather: Sunny on Friday, Sunday, and Monday, Rain on Saturday Temperature on 9/10/12: 22°C Relative Humidity on 9/10/12: 65% Analysis and Conclusions: Questions Specific to Lab: 1. 1. The highest rating the EPA will allow for a community for ground level ozone is 80 ppb. Any community with over 80 ppb for an average over three years is in noncompliance with the Clean Air Act. Compare your number to this standard. Did Wake Forest meet the standard on this day? Using what you know about the formation of ozone, decide if you believe the measurement you made was an accurate measurement of the air quality and why. No, it went way over. In fact it reached 160 in some areas. While the samples were outside it rained but that shouldn’t have affected it too much. Most of the places with the highest ozone where inside. 2. 13% of counties in the US are not meeting the Ozone requirements of the Clean Air Act. Use the chart below and information from class to explain the reason for the location of the counties in Non-attainment. Most places around the coast don’t meet the clear air act regulations because people build plants closer to the ocean so they can use the water to cool down their machines. 3. Particulate matter has recently been added to the requirements of the Clean Air Act. Theorize reasons that it was not part of the act until the 1990’s. In the 1990s there probably wasn’t as much particle matter in the atmosphere or if there was people weren’t as aware of it as they are now. 4. Compare and contrast the different PM samples – did they meet your expectations? Why or why not? Both PM samples came out pretty clean, I didn’t expect the paper that was placed inside to have any but I was surprised not to see too much PM in the sample outside. While the paper was outside it had rain so that probably washed some particles off, causing us to have unclear data. 5. Explain why air quality monitoring is important for the health of the economy. It the air quality is really bad in some areas it could affect people with asthma and lung problems so its definitely important to monitor air quality and warn people incase there results are bad, so people don’t get sick. General Conclusions: 1) Evaluate Your Hypothesis: no, the strips placed inside actually had more ozone. 2) Possible Sources of Error: while the strips where outside it rained, so that could have possibly changed the results. 3) Application: this lab shows how to measure the ozone and PM in an area.