Name _______________________________________ Block __________ Investigating Chemical Reactions, Reaction Rates and Equilibrium Systems Over the course of several days, you and your group will be experimenting with a reaction between copper (II) sulfate and aluminum. The chemical equation for this reaction is: 3CuSO4 + 2Al 3Cu + Al2(SO4)3 Safety In lab, it is required that you wear safety goggles at all times, and wash hands thoroughly after Copper (II) Sulfate: toxic by ingestion, eye, skin, respiratory irritant Aluminum Sulfate: mildly toxic, eye and skin irritant Copper: dangerous if inhaled or ingested Aluminum: skin irritant It is incredibly important that you are very careful while handling all of these chemicals. In addition to them being hazardous to your health, your group will only get a limited amount each day. Day 1: Observing the Reaction of Copper Sulfate and Aluminum You will be collecting data about the reaction between copper II sulfate and aluminum, including the amount of copper produced and the rate of the reaction. Pre-Lab Questions 1. Explain how you know a chemical reaction is happening. 2. What type of reaction is the reaction between copper (II) sulfate and aluminum? 3. Why is it important to collect both quantitative and qualitative data? Hypothesis With your group members, write a hypothesis in the if ____, then ____ format. _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ Name _______________________________________ Materials - Scale 2 Squares of Aluminum Foil 50mL of copper (II) sulfate solution 0.1g sodium chloride 150mL beaker Stopwatch 2 pieces of Filter Paper Block __________ - Funnel 250mL Erlenmeyer flask Stirring Rod Watch glass Thermometer Water bottle Forceps Procedure Be sure to take note of any little changes (or mistakes!) your group makes! 1. Gather all materials listed. 2. Measure 25mL of copper (II) sulfate, and pour into 150mL beaker. Record the exact volume of the copper (II) sulfate in the data table 3. Measure 0.1g of sodium chloride. Record the exact mass in the table below. 4. Add the sodium chloride to the copper (II) sulfate solution, mix with the stirring rod. 5. Take the mass of the one piece of aluminum. Record in the data table below. 6. Record the temperature of the starting solution. Keep the thermometer in the beaker throughout the entire reaction. 7. Place the aluminum foil into the beaker with the copper (II) sulfate. Start the stopwatch immediately when placing the aluminum foil in the beaker. 8. Observe the reaction. Record observations in the data table. 9. Allow the reaction to continue until almost all of the foil has been dissolved. When the foil is completely dissolved, stop the stopwatch and record the amount of time the reaction took. Record the final temperature. 10. Remove any excess aluminum foil using the forceps. Be careful to not take any copper out with the aluminum! 11. Fold the piece of filter paper as demonstrated by the teacher. 12. Measure the mass of just the filter paper. Record in the data table. 13. Put the filter paper in the funnel, and the funnel over the Erlenmeyer flask. 14. Slowly pour the solution into the funnel lined with filter paper. Be careful to make sure all of the solid product gets caught in the filter. 15. Use a squeeze bottle of water to rinse all of the copper from the beaker into the funnel. Make sure that all of the copper gets caught in the filter. 16. When all the liquid has passed through, carefully remove the filter paper and place on a watch glass to dry. 17. Repeat steps 1-12 for a second trial. 18. Clean up the lab station entirely. Name _______________________________________ Data Collection Block __________ Copper Sulfate and Aluminum Reaction Trial 1 Trial 2 Molarity of Copper (II) Sulfate Mass of Sodium Chloride Mass of Aluminum Initial Temperature Final Temperature Change in Temperature (Final – Initial) Mass of Filter Paper Mass of Filter Paper + Product Mass of Product Time for Reaction to Complete Qualitative Observations Calculations 1. Based on the balanced equation for this reaction, what is the mass of copper that was supposed to be in your product? (This is your theoretical yield) 2. Determine the percent yield of copper for each of the trials. The equation for percent yield is shown below: Actual Yield % Yield = ( ) × 100 Theoretical Yield Name _______________________________________ Analysis Block __________ 1. What was your percent yield, and what does it mean? 2. Why do you think that you do not have a 100% yield? Explain. 3. Was the reaction endothermic or exothermic? How do you know? Day 2: The Effect of a Catalyst You will be observing the effect of a catalyst on the reaction. The catalyst that will be used is sodium chloride (NaCl). Pre Lab Questions 1. What is a catalyst, and what does it do? 2. Explain how catalysts should affect the rate of a reaction. Hypothesis With your group members, write a hypothesis in the if ____, then ____ format. _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ Materials - Scale 2 Squares of Aluminum Foil 50mL of copper (II) sulfate solution 2.0g NaCl (sodium chloride) 150mL beaker Stopwatch Forceps - 2 pieces of Filter Paper Funnel 250mL Erlenmeyer flask Stirring Rod Watch glass Thermometer Name _______________________________________ Procedure Block __________ 1. Gather all materials listed. 2. Measure 25mL of copper (II) sulfate, and pour into 150mL beaker. Record the exact volume of the copper (II) sulfate in the data table 3. Take the mass of the one piece of aluminum. Record in the data table below. 4. Add 1.0g of sodium chloride to the solution. 5. After the sodium chloride is completely dissolved, record the temperature of the starting solution. Keep the thermometer in the beaker throughout the entire reaction. 6. Place the aluminum foil into the beaker with the copper (II) sulfate. Start the stopwatch immediately when placing the aluminum foil in the beaker. 7. Observe the reaction. Record observations in the data table. 8. Allow the reaction to continue until all of the foil has been dissolved. When the foil is completely dissolved, stop the stopwatch and record the amount of time the reaction took. Record the final temperature. 9. Fold the piece of filter paper as demonstrated by the teacher. 10. Measure the mass of just the filter paper. Record in the data table. 11. Put the filter paper in the funnel, and the funnel over the Erlenmeyer flask. 12. Slowly pour the solution into the funnel lined with filter paper. Be careful to make sure all of the solid product gets caught in the filter. 13. Use a squeeze bottle of water to rinse all of the copper from the beaker into the funnel. Make sure that all of the copper gets caught in the filter. 14. When all the liquid has passed through, carefully remove the filter paper and place on a watch glass to dry. 15. Repeat steps 1-12 for a second trial. Data Collection Trial 1 Molarity of Copper (II) Sulfate Mass of Aluminum Mass of Sodium Chloride Initial Temperature Final Temperature Change in Temperature (Final – Initial) Mass of Filter Paper Mass of Filter Paper + Product Mass of Product Time for Reaction to Complete Trial 2 Name _______________________________________ Qualitative Observations Block __________ Calculations 1. Based on the balanced equation for this reaction, what is the mass of copper that was supposed to be in your product? (This is your theoretical yield) 2. Determine the percent yield of copper for each of the trials. The equation for percent yield is shown below: Actual Yield % Yield = ( ) × 100 Theoretical Yield Analysis 1. What was your percent yield, and what does it mean? 2. Why do you think that you do not have a 100% yield? Explain. 3. Did you have a better or worse percent yield during these trials than the first experiment? Why do you think this is? 4. Which experiment proceeded at a faster rate? Why do you think this is? Name _______________________________________ Day 3: Designing an Equilibrium Assignment Block __________ You need to design an experiment to either defend or reject LeChatelier’s principle. You will need to use previous data that has been collected in this lab, as well as new data collected. Pre-Lab Questions 1. Define equilibrium. 2. Explain LeChatelier’s Principle. 3. Identify the factors that affect equilibrium. Brainstorm 1. What are some things that you can adjust in the previous experiments to demonstrate LeChatelier’s Principle? 2. What evidence would be necessary to support or reject LeChatelier’s Principle? (Think about different calculations, quantitative data, and qualitative data. Name _______________________________________ Design Block __________ Together with your group, design an experiment to test LeChatelier’s Principle. Each group needs to submit a copy via GoogleDocs of their research question, hypothesis, materials list, procedure, and blank data table(s). All of these will be assessed and the three best labs will be selected for all groups to choose from. Materials Available - 0.25M copper (II) sulfate 0.50M copper (II) sulfate Aluminum foil squares of various sizes Stirring rod Funnel Forceps Thermometer Sodium chloride - Beakers Filter paper Watch Glass Hot plate Ice Water Stopwatch If there are any other materials your group would like, please ask the teacher before adding them to your own materials list. ** Each group will be limited to a total of 100mL for their labs!** Grading This lab will count as two separate grades. Grade 1: Formal Lab Report You will be assessed on criteria A and C for this grade. It will be based solely on the completion of the lab and your formal write up. This grade will not include your group’s design part of the lab! This will be an individual grade. Each student needs to turn in the following pieces in this order for this assignment 1. 2. 3. 4. Rubrics Lab Packet Rough Draft Final Draft This will be weighted the same as a test grade! Grade 2: Design of Equilibrium Lab You will be assessed on Criteria B for this grade. It will be based solely on your group’s design of a lab to support or reject LeChatelier’s Principle. Only one needs to be submitted for your group! This will be submitted via GoogleDrive. This will be weighted the same as a quiz grade!