Chemistry I Honors – Final Exam Study Guide 2014-2015 Chapter 1 – Matter and Change: Physical vs chemical properties Physical vs chemical changes Particle model of gas/liquid/solid states of matter Law of Conservation of Energy Mixture vs pure substance Distinguish elements, compounds, mixtures Element names and symbols Arrangement of periodic table Methods for separating mixtures (filter, distill) Chapter 2 – Measurements and Calculations Scientific method – steps Qualitative vs quantitative observations Metric units for length, mass, time, volume, and density – also Metric unit conversions Density calculations Accuracy vs precision Significant figures – rules for math operations Scientific notation – be able to use it Chapter 3 – Atoms – Building Blocks of Matter Dalton’s Atomic theory Laws of Conservation of Mass, Definite Proportions, Multiple Proportions Rutherford’s experiment Properties of protons, neutrons, electrons Isotopes-use isotope masses and percent abundances to calculate average atomic mass Atomic number and mass number – how they are related Determine the number of protons, neutrons, and electrons in a nuclide given its symbol Define ‘mole’ , Avogadro’s number, molar mass Convert between mass, moles, and number of particles (atoms or molecules) Chapter 4 – Arrangement of Electrons in Atoms Bohr model of the hydrogen atoms – basic ideas What causes atomic line (absorption and emission) spectra Electromagnetic spectrum – relationships between energy, frequency, and wavelength Quantum model of the atom Orbitals and quantum numbers Write electron configurations for atoms and ions Identify elements from their electron configuration (either electron configuration notation or orbital notation) Chapter 5 – The Periodic Law Describe how elements of a group are related Relationship between electron configuration and the structure of the Periodic table. Name 4 blocks of the periodic table Periodic trends in atomic radius, ionization energy, electron affinity, and electronegativity Define valence electrons and state the number present in atoms of each main group element Know the common group/family names and typical properties for elements of Groups 1, 2, 17, and 18. Chapter 6 – Chemical Bonding Distinguish between ionic and covalent bonding Classify bond type by electronegativity differences Write Lewis electron dot structures Describe the differences in bond length and bond energy in single, double, and triple bonds Describe the electron-sea model of metallic bonding and relate to properties of metals Predict shapes and polarities of molecules and ions using VSEPR theory Discuss the types of intermolecular forces and relate them to physical properties Chapter 7 – Chemical Formulas and Chemical Compounds Write formulas for ionic compounds and name them Name binary molecular compounds using prefixes Write the formula of binary molecular compounds given the name Give oxidation numbers for each element in a compound or ion. Calculate molar mass for a given compound. Calculate mass percent of an element in a given compound Convert between mass, moles, and number of particles Define empirical formula and explain the relationship between the empirical formula and the molecular formula of a compound Calculate empirical formula from percent composition Calculate molecular formula from percent composition and molar mass Chapter 8 – Chemical Equations and Reactions List observations that indicate a chemical reaction is occurring Balance formula equations by inspection List the five types of chemical reactions and classify a given reaction according to type Use an activity series and/or a solubility table to predict whether a given reaction will occur and predict the probably products formed. Chapter 9 – Stoichiometry Define stoichiometry Write a mole ratio relating two substances in a chemical equation Determine the amount (grams or moles) of product formed from a given amount (grams or moles) of reactant Calculate percentage yield, given theoretical yield and actual yield. Chapter 10 – States of Matter State the kinetic-molecular theory of matter and describe how it explains macroscopic properties of a gas. Describe the motion of particles in liquids and solids, and the properties of liquids and solids according to the kinetic-molecular theory. Discuss changes of state as equilibrium processes Interpret phase diagrams Define vapor pressure and explain its relationship to state changes Describe the structure of a water molecule and its relationship to the physical properties of water Chapter 11 - Gases Define ‘pressure’, know units of pressure, use Dalton’s Law of partial pressures to calculate partial pressure, total pressure, and mole fraction of gases in a mixture. Know Avogadro’s Law and use it to compare properties of different samples of gases. Know the standard conditions of temperature and pressure used in gas law problems. Use kinetic-molecular theory to explain relationships between gas volume, temperature, and pressure. Use the ideal gas law to calculate pressure, volume, temperature, or moles of gas when the other three quantities are known. Define ‘standard molar volume’ and use it to calculate gas masses and volumes. Chapter 12 - Solutions Distinguish between electrolytes and nonelectrolytes Explain solution equilibrium and distinguish between saturated, unsaturated, and supersaturated solutions Explain the meaning of ‘like dissolves like” in terms of polar and nonpolar substances Perform calculations related to solution concentration (e.g. molarity, molality, and dilutions) Chapter 13 – Ions in Aqueous Solutions and Colligative Properties Write equations for the dissolution of soluble ionic compounds in water Distinguish between strong and weak electrolytes Predict whether a precipitate will form when solutions of soluble ionic compounds are combined, and write net ionic equations for precipitation reactions. Calculate freezing point depression, boiling point elevation, and solution molality of nonelectrolyte and electrolyte solutions. Chapter 14 – Acids and Bases List properties of aqueous acids and bases, and identify Arrhenius and Bronsed-Lowry acids/bases. Name common binary acids and oxoacids Explain the difference between strong and weak acids and bases. Define a conjugate acid, a conjugate base, and an amphoteric compound Give the products of an acid-base neutralization reaction Chapter 15 – Acid-Base Titration and pH Write the equilibrium equation for the self-ionization of water Define pH and explain the pH scale. Identify the most acidic or most basic solution from a list, given pH or [OH-] or [ H3O+]. Perform calculations relating pH and pOH to [H3O]+ and [OH] – Explain how to perform an acid-base titration and how an indicator works Calculate solution molarity from titration data Chapter 16 – Reaction Energy Distinguish ‘heat’ and its units from ‘temperature’ and its units. Perform specific heat calculations (choose the best material for heat storage based on Specific.Heat values) Explain enthalpy change, enthalpy of reaction, enthalpy of formation, and enthalpy of combustion Calculate the heat released or absorbed for a given reaction, given the ΔH and amounts of reactants Distinguish exothermic from endothermic chemical reactions and changes of state Explain enthalpy, entropy, and free energy, and their relationship to the driving force for reactions to occur Chapter 17 – Reaction Kinetics Explain the concept of a reaction mechanism Define activated complex Relate activation energy to enthalpy of reaction Discuss the factors that affect reaction rate. Define ‘chemical kinetics’ and explain the two conditions necessary for a reaction to occur. Define ‘catalyst’, explain how a catalyst works to speed up the reaction. Give examples of catalyzed reactions Chapter 18 – Chemical Equilibrium Define equilibrium and state the conditions necessary for a system to be at equilibrium Write chemical equilibrium expressions and perform calculations involving them List factors that disturb equilibrium and predict shifts in equilibrium using LeChatelier’s Principle Explain acid ionization constants and write the Ka expressions Explain and calculate values for Ksp (solubility product constants) and molarity of ions in solubility equilibria. Chapter 19 – Oxidation – Reduction Reactions Define oxidation and reduction Assign oxidation numbers to reactant and product species Identify redox reactions, and write oxidation and reduction half-reactions for a given redox reaction. Relate chemical activity to oxidizing and reducing strength Chapter 20 – Electrochemistry Identify the parts of an electrochemical cell and their functions. Distinguish a voltaic cell from an electrolytic cell Calculate cell potentials from a table of standard electrode potentials. Identify cathode and anode and write the halfreactions occurring at each electrode in a given electrochemical cell Chapter 21 – Nuclear Chemistry Explain why nuclear reactions occur and know how to balance a nuclear equation Define half-life and explain how it relates to the stability of the nucleus; work simple half-life problems Define and relate the terms ‘radioactive decay’ and ‘nuclear radiation.’ Chapter 22 – Organic Chemistry Identify functional groups in a molecule Give names of simple organic compounds, given their structural formulas