Percent Purity, Percent Yield Name: __________________________ Date: _________________ 1. The roasting of siderite ore, FeCO3, produces iron (III) oxide: FeCO3 + O2 Fe2O3 + CO2 a. What is the balanced equation? 4 FeCO3 + O2 2 Fe2O3 + 4 CO2 b. A 15.0 g FeCO3 sample is 42.0% pure. What mass of Fe2O3 can the sample produce? (6.30 g pure FeCO3 will react) 4.34 g Fe2O3 c. A second sample of FeCO3, with a mass of 55.0 g is roasted so as to produce 37.0g of Fe2O3. What is the percentage purity of FeCO3? (53.7g pure FeCO3) 53.7g / 55.0 g * 100% = 97.6 % d. A 35.0 g sample of pure FeCO3 produces 22.5 g of Fe2O3. What is the percentage yield of the reaction? (24.1g pure Fe2O3 produced) 22.5g / 24.1 g *100% = 93.3% e. What mass of siderite ore with a purity of 62.8% is needed to make 1.00 kg of Fe2O3? 2310 g 2. A 100. g sample of impure FeS2 is roasted to produce Fe2O3 + SO2: 4 FeS2 + 11 O2 2 Fe2O3 + 8 SO2 If 4.50 L of SO2 is collected at STP, what percentage of FeS2 is in the sample? (find the mass of FeS2 required to make 4.50L of SO2 = 12.1 g FeS2) 12.1% 3. When 5.000 kg of malachite ore containing 4.30% of malachite, Cu2(OH)2CO3, is heated, the product is copper (II) oxide: Cu2(OH)2CO3 CO2 + CuO + H2O a. What is the balanced equation? Cu(OH)2CO3 CO2 + 2 CuO + H2O b. If the reaction has an 84.0% yield, how many grams of CuO are produced? 1.30 x 102 g c. If the decomposition reaction has an 87.0% yield, what mass of ore containing 3.70% malachite is required to produce 100.0g of CuO? 4.32 x 103 g 4. A mine produces a silver ore named argentite, Ag2S. The ore is smelted according to the overall reaction Ag2S + C + O2 Ag + CO2 + SO2 a. What is the balanced equation? Ag2S + C + 2 O2 2 Ag + CO2 + SO2 b. A 250.0 kg load of argentite ore contains 0.135% pure Ag2S. What mass of silver metal can be produced from the load of core? 294 g c. A 76.4 g test sample of ore from a new ore vein produces 0.261g of pure silver. What is the percentage of pure argentite in the ore? 0.392% d. A sample of pure Ag2S has a mass of 152.6 g. When smelted, the sample produces 117.4 g of pure Ag. What is the percentage yield of the smelting process? 88.38% e. What mass of ore containing 0.795 % Ag2S is required to produce a 50.0 kg ingot of silver metal? f. 7.22 x 106 g If 89.2% of the Ag2S present is extracted from 3.50x104 kg of ore containing 1.86% Ag2S, what mass of silver metal can be produced? 5.05 x 105 g 5. ***This question is quite challenging*** The reaction: SiO2 (g) + HF (g) SiF4 (g) + 2 H2O (g) produces 2.50g of H2O when 12.20g of SiO2 is treated with a small excess of HF? a. What is the balanced equation? SiO2 + 4 HF SiF4 + 2 H2O b. What mass of SiF4 is formed? 7.23g c. What mass of SiO2 is left unreacted? 8.03g d. What is the percentage yield of SiF4? 34.2%