Hayfield Secondary AP Summer Assignment Cover Sheet Course Teacher Names & Email Addresses Assignment Title Date Assigned Date Due Objective/Purpose of Assignment Description of how Assignment will be Assessed Grade Value of Assignment Tools/Resources Needed to Complete Assignment Estimated Time Needed to Complete Assignment Sara Hubbart (szhubbart@fcps.edu) Chemistry 1 Review May, 2013 2nd class of AP Chemistry To review important concepts of Chemistry 1 which are essential to success in AP Chemistry. Assignment will be assessed based on completion. Please do not leave any questions blank. Contact me over the summer if you need help. I will make every effort to respond to your questions within 1 week. 5% of first quarter grade Chemistry 1 notes. Internet if needed. 4-5 hours Name: Date: AP Chemistry: Summer Assignment Section 1: Naming, Formula and Equation Writing 1. Please fill in this grid on naming and formula writing: Formula Name Bonding Type (Ionic, Covalent or Both) Aluminum Sulfide P2O5 Manganese (IV) Oxide Magnesium Phosphate Ti(SO4)2 Diboron Tetrabromide K3N Iron(III) Hydroxide 2. Write balanced molecular equations and identify the type of reaction (decomposition, etc) for the following reactions: Silicon Tetrachloride and Magnesium react to form Magnesium Chloride and Silicon Hydrochloric acid and Ammonia react to form Ammonium Chloride Methane (CH4) combusts Aluminum Nitrate and Barium Hydroxide react to form Aluminum Hydroxide and Barium Nitrate 3. Write and balance the following reactions. You must predict the products. Also identify the type of reaction. Al + HCl ? CoCl2 + Na2CO3 ? C3H8 + O2 ? Na + N2 4. Write balanced equations for the following reactions. Use a solubility chart (see last page) to determine the aqueous species and the precipitate. Then, write a net ionic equation. A) Potassium Oxide + Iron (III) Chloride Molecular: Net Ionic: B) Tin (IV) Bromide + Sodium Sulfide ? Molecular: Net Ionic: C) Barium Hydroxide + Potassium Phosphate Molecular: Net Ionic: 5. Adrenaline is 56.79% C, 6.56% H 28.37% O and 8.28% N by mass. What is the empirical formula? Section 2: Elements and Compounds 6. Write Lewis Structures and identify the shape for the following molecules: OCl2 NF3 CF4 CO32- SO3 HCN 7. Write Lewis Structures for the following molecules: C2H4 C5H12 CH3CH2OH CH2BrCH2CH2Cl 8. Identify the number of protons, neutrons and electrons in each species Species 14 C P358 Fe2+ Protons Neutrons Electrons Section 3: Moles and Stoichiometry 9. Answer the following questions about this reaction: __C2H4 + __O2 __ CO2 + __H2O A) .495 moles of oxygen produces how many moles of water? B) 2.25g C2H4 produces how many moles of carbon dioxide? C) 12.5 moles of O2 produces how many molecules of carbon dioxide? D) 49g of ethylene (C2H4) produces how many grams of water? 10. Answer the following questions about this reaction: __ Fe2O3 (s) + __ C(s) __Fe (s) + __ CO (g) A) If 13.25g C react, how many grams of Fe are produced? B) If you perform the experiment in 10A and 4.25g Fe form, what is the percent yield? C) 225g of Fe2O3 react. How many molecules of CO are produced? D) If .445 moles C and .229 Fe2O3 moles react, what is the limiting reactant? E) What is the maximum mass of CO that may be produced in 10D? F) How many moles of excess reactant are consumed in 10D? G) If 12.45g C and 25.29g Fe2O3 react, what is the limiting reactant? H) How many grams of Fe may be produced in 10G? I) If 44.0g C and 22.0g Fe2O3 react, how many grams of CO may be produced? J) How many grams of excess reactant are consumed and left over in 10I? 11. The percentage by mass of calcium carbonate (CaCO3) in eggshell was determined by adding excess hydrochloric acid (HCl) to ensure that all the calcium carbonate had reacted. The excess acid left was then reacted with aqueous sodium hydroxide (NaOH). A) A student added 27.20mL of 0.200M HCl to 0.188 g of eggshell. Calculate the amount, in mol, of HCl added. B) The excess acid requires 23.80mL of 0.100M NaOH for neutralization. Calculate the amount, in mol, of acid that reacts with the NaOH. C) Using the amount of excess acid in part B and the original amount in part A, determine the amount, in mol, of HCl that reacted with the calcium carbonate in the eggshell. D) Write the equation for the reaction of HCl with the calcium carbonate in the eggshell. E) Determine the amount, in mol, of calcium carbonate in the sample of the eggshell. F) Calculate the mass and the percentage by mass of calcium carbonate in the eggshell sample. Section 4: Thermochemistry 12. The specific heat capacity of silver is .24 J/goC A) Calculate the energy required to raise the temperature of 150.0g Ag from 0oC to 25oC. B) Calculate the energy required to raise the temperature of 1.25 moles Ag by 2.0oC. C) What is the mass of a sample of Ag if it takes 1.25kJ of energy to heat it from 12.0oC to 15.2oC? 13. An experiment requires the preparation of a water bath at 37.0oC. The temperature of the cold tap water is 22.0oC and the temperature of the hot tap water is 55.0oC. If a student starts with 90.0g of cold water, what mass of hot water must be added to reach 37.0oC? Cwater is 4.18 J/goC 14. Consider this reaction: 2H2 + O2 2H2O ∆H = -572kJ A) What is the energy change if 1.00 moles of H2O are produced? B) What is the energy change when 4.03g hydrogen reacts in excess oxygen? C) What is the energy change when 186g oxygen reacts in excess hydrogen? D) What is the maximum energy change if 25.0g hydrogen reacts with 14.0g oxygen? (Hint: find the limiting reactant first!) 15. Consider the following reaction: C2H6 + Cl2 CH3CH2Cl + HCl A) Write Lewis Structures for each molecule. B) Using the list of bond energies below, calculate ∆H for the reaction. C-C 347kJ C-H 413kJ Cl-Cl 239kJ H-Cl 427kJ C-Cl 339kJ Section 5: Gas Laws and STP 16. What is the pressure of 85.0g argon gas that is held at 45.2oC and 775mL? 17. A sample of gas is held at 1.25atm, .25L and 45.2oC. The volume is changed to .75L and the temperature to 75.2oC. What is the final pressure? 18. A sample of gas is held at 2.25atm and 1.25L. What is the final volume if the pressure is changed to 912mmHg? Assume the temperature remains constant. 19. Consider the following reaction at STP: 2SO2(g) + O2(g) 2SO3 A) 25.2g oxygen occupies what volume at STP? B) 2.95L O2 produces what volume of SO3 at STP? C) 3.5L SO2 produces what mass of SO3 at STP? D) What is the maximum volume of SO3 that may be produced if 24.0g SO2 and 25.0g O2 react at STP?