Supporting Information
Acrylate–Vinylidene Chloride Copolymers Derived
from Corresponding Water-Borne Latexes: Influence
of Acrylate Units on their Potential as Heavy-Duty
Anticorrosive Coating Materials
Ce Fu,1 Hong-Wei Qin,1 Hai-Jie Ben,1 Jing Han,1 Wen-Zhu Cui,2 Fa Cheng,1 Yu Chen1
1
Department of Chemistry, School of Sciences, Tianjin University, 300072 Tianjin, People’s Republic
of China
2
COSCO Kansai Paint & Chemicals Co. Ltd., No. 42, 5th Avenue TEDA , 300457，Tianjin, People’s
Republic of China
1
Table S1. The physical properties of the obtained latex solutions
Latex
Content of VDC
Solid content
Yield
Viscosity
abbreviation
wt %
mol%
(%)
(%)
(mPa s)
Particle
diameter/nm
MA-VDC90
90
89
56.4
96.2
12
106
1.79
1.24
MA-VDC 85
85
84
56.5
96.3
15
115
2.98
1.45
MA-VDC 80
80
78
56.8
96.8
18
104
4.65
1.40
MA-VDC 75
75
73
57.7
98.4
23
118
2.68
1.47
MA-VDC 70
70
68
57.3
97.7
25
112
3.22
1.50
MA-VDC 65
65
63
57.7
98.4
16
112
5.18
2.50
EA-VDC 90
90
90
57.3
97.7
15
123
2.36
1.87
EA-VDC 85
85
85
58.0
98.9
16
129
3.64
2.22
EA-VDC 80
80
80
58.6
99.9
15
122
3.71
2.39
EA-VDC 75
75
75
57.4
97.9
12
126
3.91
3.95
EA-VDC 70
70
71
57.3
97.7
15
106
1.67
2.94
EA-VDC 65
65
66
58.2
99.2
27
129
5.25
1.97
BA-VDC 90
90
91
58.1
99.0
27
120
2.83
1.68
BA-VDC 85
85
87
58.4
99.6
28
118
2.26
1.69
BA-VDC 80
80
83
58.6
99.9
22
122
2.41
1.81
BA-VDC 75
75
79
58.3
99.4
19
112
8.93
1.07
BA-VDC 70
70
75
58.2
99.2
23
109
7.71
2.31
BA-VDC 65
65
70
58.3
99.4
22
115
6.87
1.19
HA-VDC 90
90
92
57.7
98.4
20
117
5.62
1.52
HA-VDC 85
85
89
57.3
97.7
18
118
10.0
1.04
HA-VDC 80
80
85
58.1
99.0
17
130
17.8
1.38
HA-VDC 75
75
81
58.1
99.0
22
112
15.0
1.31
HA-VDC 70
70
78
57.6
98.2
27
121
13.6
1.21
HA-VDC 65
65
74
56.5
96.3
24
118
7.14
1.50
EHA-VDC 90
90
92
57.4
97.7
25
120
6.54
2.31
EHA-VDC 85
85
89
58.1
99.0
27
121
5.05
1.29
EHA-VDC 80
80
86
58.3
99.4
23
123
1.26
1.09
EHA-VDC 75
75
83
58.0
98.9
26
115
3.54
1.95
EHA-VDC 70
70
80
58.3
99.4
26
118
2.88
1.81
EHA-VDC 65
65
76
58.5
99.7
29
121
9.23
1.15
.
Mn/105
PDI
2
Table S2. The thermal properties of the formed films
Latex
Thermal property of the formed membrane
Tg (oC)
Tm(oC)
MA-VDC 90
15.23
—
MA-VDC 85
24.50
—
MA-VDC 80
33.66
—
MA-VDC 75
40.34
—
MA-VDC 70
42.00
—
MA-VDC 65
47.21
—
EA-VDC 90
14.50
—
EA-VDC 85
18.01
—
EA-VDC 80
24.65
—
EA-VDC 75
27.05
—
EA-VDC 70
30.45
—
EA-VDC 65
34.36
—
BA-VDC 90
8.10
147.57
BA-VDC 85
8.82
—
BA-VDC 80
11.69
—
BA-VDC 75
12.39
—
BA-VDC 70
15.25
—
BA-VDC 65
14.04
—
HA-VDC 90
7.27
151.32
HA-VDC 85
5.94
—
HA-VDC 80
4.71
—
HA-VDC 75
4.45
—
HA-VDC 70
3.09
—
HA-VDC 65
2.04
—
EHA-VDC 90
6.44
141.12
EHA-VDC 85
3.56
—
EHA-VDC 80
3.24
—
EHA-VDC 75
2.10
—
EHA-VDC 70
1.91
—
EHA-VDC 65
1.79
—
3


(B)
-20
20
40
60
80
100
120
140
160
-20


0
EA-VDC90
EA-VDC85
EA-VDC80
EA-VDC75
EA-VDC70
EA-VDC65
Endothermic

MA-VDC90
MA-VDC85
MA-VDC80
MA-VDC75
MA-VDC70
MA-VDC65
Endothermic

(A)
0
20
40
60
o
T/ C
20
40
140
160
60
80
100
120
140
100
120
140
160
HA-VDC90
HA-VDC85
HA-VDC80
HA-VDC75
HA-VDC70
HA-VDC65
160
-20

Endothermic


0
120

(D)
BA-VDC90
BA-VDC85
BA-VDC80
BA-VDC75
BA-VDC70
BA-VDC65
Endothermic

-20
100
T/ C

(C)
80
o
0
20
40
60
o
80
o
T/ C
T/ C

EHA-VDC90
EHA-VDC85
EHA-VDC80
EHA-VDC75
EHA-VDC70
EHA-VDC65
-20

Endothermic

(E)
0
20
40
60
80
100
120
140
160
o
T/ C
Figure S1. The DSC diagrams of acrylate-VDC copolymers: (A) MA-VDC, (B) EA-VDC, (C) BAVDC, (D) HA-VDC, (E) EHA-VDC
4

2000
1800
1600
1400
Wavenumber/cm
1200
1000
800
2000


Transmittance
MA-VDC90
MA-VDC85
MA-VDC80
MA-VDC75
MA-VDC70
MA-VDC65
Transmittance
(B)
(A)
EA-VDC90
EA-VDC85
EA-VDC80
EA-VDC75
EA-VDC70
EA-VDC65
1800
-1
1600
1400
Wavenumber/cm
1200
1000
800
-1

2000
1800
1600
1400
1200
-1
Wavenumber/cm
1000
800
2000


HA-VDC90
HA-VDC85
HA-VDC80
HA-VDC75
HA-VDC70
HA-VDC65
Transmittance
(D)
Transmittance
(C)
EHA-VDC90
EHA-VDC85
EHA-VDC80
EHA-VDC75
EHA-VDC70
EHA-VDC65
1800
1600
1400
1200
-1
Wavenumber/cm
1000
800
Figure S2. FTIR-ATR spectra of VDC-acrylate copolymers: (A) MA-VDC, (B) EA-VDC, (C) HAVDC, (D) EHA-VDC
5