GENERAL CHEMISTRY II CHEM 1312.006 CRN: 58132 FALL 2011 COURSE SYLLABUS Meeting Days / TImes: This class meets on the Internet at times chosen by the individual student. The course is structured so that its activities can be completed asynchronously. Students do not have to be logged on simultaneously to pursue course activities. Each student can work on his or her own schedule, as long as the course deadlines are adhered to. Course Description: This course is a continuation of CHEM 1311 including kinetics, molecular and ionic equilibria, elementary thermodynamics, electrochemistry, nuclear chemistry, and other topics. Students needing a laboratory should also enroll in CHEM 1112. This course is equivalent to the lecture portion of CHEM 1412. Instructor: Dale Robinson Office: San Jacinto Hall, Room 206 Phone: 210-486-3375 Office Hours: To Be Announced E-Mail: drobinson@alamo.edu Chat: http://elluminatelive.alamo.edu Use your first and last name (spaces are allowed) for the user ID. Currently, no password is required. Website: http://www.alamo.edu/pac/faculty/drobinson Text: Chemistry, A Molecular Approach, second edition Nivaldo J. Tro, Pearson © 2011 You must have a subscription to the Mastering Chemistry homework grading system that accompanies this textbook. If you purchased the textbook as a combo-pack from the Palo Alto bookstore, it includes an access code to register for your account. If you have a used textbook, you will need to purchase your subscription as a stand-alone item. This can be done in the Palo Alto College Bookstore, or online at www.masteringchemistry.com. When you set up your online homework account, you will have the option to add the eBook to your subscription for an additional fee. The eBook is not required if you have a paper book, although you can choose to have both a paper book and an eBook if you like. The lowest cost option is to purchase the eBook with your homework subscription and do without a paper book. This will save you money, since the eBook is cheaper, but not having a paper book can sometimes be an inconvenience. When registering for your Mastering Chemistry account, you will need to specify the course ID for the class you wish to add to your account. The course ID for this class is "CHEM58132". Enter this course ID exactly as shown between the quote marks (but don't enter the quote marks themselves). You will also be asked for your Banner ID. This is a 9-digit number that begins with 900. If you don't know your Banner ID, please contact your instructor for assistance. If asked for the zip code of your school, use 78224. Grading: Exam Average (drop lowest grade) Quiz Average (drop 2 lowest grades) Mastering Chemistry Homework (drop 2 lowest grades) Comprehensive Final Exam Letter Grade: A: Semester Score ≥ 90 B: 80 ≤ Semester Score < 90 C: 70 ≤ Semester Score < 80 D: 60 ≤ Semester Score < 70 F: Semester Score < 60 50% 10% 10% 30% Semester Score = 0.50 * exam avg + 0.10 * quiz avg + 0.10 * homework avg + 0.30 * final COURSE POLICIES Student Responsibilities -- Internet Connection & Computer; Dealing with Technical Failures: This is an online course. With the exception of major exams, the student may participate in the course anywhere an Internet connection is available. It is the responsibility of the student to provide or obtain a reliable Internet connection and computer with which to pursue course activities. In the event of computer failure or Internet connectivity problems, it is the responsibility of the student to make alternate arrangements. It is recommended that course assignments be completed well in advance of their deadlines, to allow time to recover from technical difficulties. In the event of computer / Internet related problems during a timed quiz in Blackboard Vista, you should close the browser and immediately re-launch it. If this does not work, you may need to re-boot your computer. You should be able to resume your timed quiz, provided your time has not expired. It is important to note that your time on the quiz continues to elapse, even while you are not connected to the Internet, or not viewing the quiz page. Therefore, it is extremely important that you re-access your timed assignment as soon as possible after a computer or network failure. Note that exams are now REQUIRED to be taken in the Testing Center. In the event of a computer failure during an exam, consult a Testing Center proctor. He or she will assist you in re-gaining access to your exam. If the proctor on duty is not able to solve the problem, (s)he can attest to the fact that a problem has occurred that has prevented you from completing the exam. In such a case, the instructor will discuss the details of the failure with the proctor and the student, and a grade adjustment or make-up (at the instructor's discretion) will be offered. A student's claim of technical failure during an exam will not be accepted without verification by the proctor on duty. For work done at home: In the event of a failure that will prevent you from completing the assignment, and for which you plan to ask for any kind of allowance to be made, you MUST document the failure by calling the Alamo Colleges Helpdesk at 210- 485-0555. If the issue can not be immediately resolved, get the name of the technician who helped you, and the ticket number assigned to your issue. This information will show that you have made a good faith effort to resolve the problem, and may help your instructor investigate the problem on your behalf. Out of town students can call the Helpdesk toll free at 1-866-493-3947. If the problem occurs at a time that is outside of Helpdesk service hours, then leave a voicemail message at 210486-3375. In your message, briefly describe what is going wrong, and leave a callback number where you can be contacted. The instructor will reutrn your call during normal business hours. You should also follow up with a call to the Helpdesk as soon as possible after their service hours resume. If these guidelines are not followed, no allowance can be made for the failure. Expectation of Active Participation: Since all assignments are made available at the beginning of the course, students may work at their own pace, and may work well ahead of due dates. "Active Participation" shall be defined as keeping current on all assignments, and responding to any email or bulletin board communications that require the student's attention. Students who have more than 6 past due assignments in either the quiz or homework categories, or who have missed two major exams, may be dropped from the course by the instructor. Even if you have worked well ahead of the posted due dates, you should still log in regularly to check email and bulletin board messages. Adhering to Deadlines: Students are expected to comply with the assignment completion deadlines posted in this course. These deadlines are found on the Blackboard calendar, and in the course calendar at the end of this syllabus. Since all graded assignments (except for the final exam) are made available at the beginning of the course, make-ups for missed assignments will be rare. When students miss an assignment, the two most common excuses are the following: 1. The student was mistaken about the due date. They thought it was later than it really was. 2. The student planned to do the assignment on the last day, but "something came up" that kept them from getting it done. Since the due dates are clearly posted -- in TWO places -- not being aware when something is due is not a valid excuse. And, although you can wait until the last day (or even the final hour) to complete an assignment, you do so at your own risk. For example, the fact that you got called in to work on the last night you could complete an assignment is not grounds for a make-up. You are strongly encouraged to complete work well in advance of posted deadlines. This gives you time to recover when the unexpected happens. On-Campus Monitored Testing: Although most assignments in this course can be accessed 24 / 7 anywhere you have Internet access, the exams are an exception. There are 4 exams and a final exam that MUST be completed at the Palo Alto College Testing Center, located in Brazos Hall, Room 100. All the other assignments can be completed without supervision, so this course will only require 5 trips to campus over the entire semester. Your instructor regrets any inconvenience this requirement may cause, but no exceptions can be made to this policy. Our exams are closed book and closed notes. These rules are applied to students taking exams in the on-campus sections of this class, and the only way to ensure that online students are held to the same standards is to monitor the testing process. It is very important for you to be aware that the Testing Center does NOT accept walk-ins. You MUST have an appointment, set up at least one business day in advance. You can reach the Testing Center at (210) 486-3444. You are strongly encouraged to set up your appointments far in advance of the exam due dates. If you wait too late to set up an appointment, there is the risk that the Testing Center will be full during your desired time slot. You have the best chance of getting a seat at your perferred testing time if you make your appointment well in advance of your testing day. PLEASE NOTE: Exams must be completed by the end time of the test session chosen. Students are asked to arrive with enough time to allow for the length of their exam as specified by the instructor. Students will not be allowed to start any test during the last hour of any session. No exceptions will be permitted. Academic Dishonesty (Cheating): Students are expected to pursure their course activities in an honest manner. Academic Dishonesty takes many forms, but some common examples include the following: Plagiarism -- Presenting the work of another person as if it were your own. Using unauthorized materials or assistance when completing a graded assignment. Claiming a computer failure has occurred (to get a make-up or grade adjustment) when no such failure has occurred, and you are aware that everything is working normally. This is the cyber version of "my dog ate my homework". Asking someone to divulge the content of or answers to a graded assignment that you have not yet completed. Assisting another student in carrying out any act of acdemic dishonesty. The penalty for academic dishonesty on a graded assignment will be a grade of zero for the affected assignment. A zero assigned as a penalty for academic dishonesty can not be dropped as the "lowest grade". Such zeros must ALWAYS be used in calculating the student's grade in the course. An assignment that is "zeroed out" for dishonesty can not be made up. For particularly serious cases, or repeat offenders, the instructor may also report the dishonesty to the Dean of Students, for any possible disciplinary action by the College. Schedule Change Policy: The instructor has made every effort to set up an accurate and workable schedule of events for this course. While there are currently no plans to make any changes to this schedule, the instructor reserves the right to modifiy the schedule if unforessen circumstances warrant any changes. In the event of any changes, students will be notified via Blackboard email and/or a bulletin board posting. Resolution of Disputes: Your instructor strives to treat all students with fairness and respect, and hopes your journey through this course will be a pleasant one. However, in our complex, modern world, misunderstandings and disputes sometimes arise. In most cases, when a student feels they have been slighted, the best course of action is a polite discussion with the instructor. The instructor will listen to the student's concern or complaint, and investigate the facts pertainent to the concern or complaint. After careful consideration, the instructor will inform the student of his decision and how that decision was reached. If the student is not satisfied with the instructor's decision, the student may appeal, using the formal student grievance procedure as set forth by the Alamo Colleges. The student should by-pass the instructor in the grievance process only if they feel they have been treated capriciously or arbitrarily by the instructor, and do not feel comfortable discussing the problem with him. It should be noted that this syllabus is a contract between the student and the instructor, and in the event of any dispute, an arbitrator's first action would most likely be to determine whether or not the issue in question (and its resolution) is already covered by this syllabus. If any part of this syllabus is found to be in conflict with a higher authority (such as an official Alamo Colleges policy), it shall be modified to the extent necessary to bring it into compliance with the higher authority. The parts of the syllabus that are not in conflict will remain valid and enforceable. Communication Tools: Each time you log in to your chemistry course in Blackboard Vista, you should check the bulletin board, your Blackboard Vista email, and the course calendar. These are the places where your instructor will post important messages involving the course. The email and bulletin board facilities are also available for student-to-student communication. The bulletin board is organized into 4 special topic boards. The board entitled "Messages from the Instructor" is especially important reading. This is where you will find important updates, news, instructions and announcements. On the board entitled "New Student Introductions", you should introduce yourself to your classmates. This is the online equivalent of the on-campus ice-breaker in which each student introduces himself or herself, and shares some noteworthy details, such as hobbies, interests, career plans, etc. Posting an introductory message on this board is a required part of orientation. The board entitled "The Student Lounge" is a place for on-going student interaction. Here, you may share study tips, make friends, form study groups, and so on. The board entitled "The Sandbox" is an experimental board. This is useful if you want to confirm how Blackboard will display messages containing HTML coding. It allows you to experiment all you want without cluttering up the production boards with your experimental postings. You should not post "real" messages here, since most people will probably never read them. On all bulletin boards, the messages you post are visible to everyone in the course. If you want to communicate privately with your instructor, or with another student, you should use the Blackboard email facility instead. Messages you post in an email can only be read by the recipient(s) you designate. The instructor generally uses the bulletin board for messages of interest to all students, and email for messages directed to specific students. Students can use the calendar to post reminder messages for themselves. Items posted by a student are only visible on that student's calendar. Items posted by the instructor are visible to all students. You can feel free to mark up your Blackboard calendar all you want, since no one else will see those entries. For example, if you want to set personal deadlines in advance of those established by the instructor (highly recommended), you can include your personal deadlines on your calendar. Rest assured that setting your own "deadline" will not shorten your assignment availability. You will still have until the date and time set by your instructor to complete your assignment. Adhering to a "soft" deadline that you set for yourself just ensures that you will not run up against the "hard" deadline established by your instructor. Tracking Your Progress: As a security measure, you will not be able to view your results for quizzes and exams in Blackboard Vista until after the availability period has ended. Since some of your coursework (quizzes and exams) will be completed in Blackboard Vista, and some of your coursework (homework assignments) will be completed in Mastering Chemistry, your instructor will provide password protected access to a Website where you can view all of your grades in one place. This site will also include your overall score in the course, so you can keep track of your academic standing throughout the semester. Your instructor strongly recommends that you get help early if you see that your grades are slipping. It is much more difficult to recover after several low grades have been earned. Getting Help: Although this is an online course, you are by no means all alone and on your own. Your instructor is committed to getting you the help you need to be successful in this course. You are welcome to email the instructor at any time, and you should receive a reply within 24 hours. Even better, you can hold a live conversation with the instructor through the Elluminate Chat Room. The URL is http://elluminatelive.accd.edu. This is much better than a standard textbased chat room. Text chat is there, of course, but this room also provides a shared white board, and supports voice chat. The instructor uses the shared white board to provide chemistry tutoring, just as a chalk board or white board would be used in a traditional classroom. While tutoring, the instructor has his microphone turned on, so if you have a working sound card and speakers, you can hear the spoken explanations of what is being written on the white board. If you have a microphone on your computer, you can speak to the instructor and others in the room. Having a microphone is not a requirement, however. You can still use text-based chat to ask questions and make comments. To log in to the chat room, use your first and last name (spaces are allowed) for your user ID. If I were logging in as a student, I would type Dale Robinson for my user ID. You can also get help at the Science Learning Center. The Science Learning Center has 2 locations: Location Phone Hours Frio Hall, Room 111 (210) 486-3281 Monday - Thursday: 8:00 a.m. - 6:00 p.m. Friday: 8:00 a.m. - 2:00 p.m. Brazos Hall, Room 126 (210) 486-3232 Monday - Thursday 8:00 a.m. - 4:00 pm Friday: 8:00 a.m. - 12:00 p.m. COURSE COMPETENCIES Upon completion of the course, the successful student will be able to: Explain why there is no general mathematical equation to relate pressure, temperature, and volume for solids and liquids, as there is for gases. Identify the characteristics of solids, liquids, and gases, both macroscopically and at the molecular level. Understand the kinds of attractive forces that can exist between the molecules (or atoms) of a substance and predict in specific cases which kinds of attractive forces should be important. Use intermolecular attractive forces as a basis to predict or explain physical properties such as melting point, boiling point, vapor pressure, heat of vaporization, viscosity, and surface tension. Apply elementary thermodynamics to phase changes, to calculate, for example, the amount of heat needed to melt 50 grams of ice at its melting point. Understand and explain, the relationship between the vapor pressure of a solid or liquid and the strength of the intermolecular attractive forces between its molecules. Understand and explain, the relationship between the vapor pressure of a solid or liquid and its temperature. Use the Clausius-Clapeyron equation to relate the vapor pressures of a substance at two different temperatures to the heat of vaporization. Use a phase diagram to determine which state (or states) of a substance will be stable under specified conditions of temperature and pressure. Use a phase diagram to identify which phase changes would be expected to occur for a specified change of pressure and/or temperaure. Understand the basics of crystal structure, and do simple geometric calculations involving cubic crystal lattices, to calculate such properties as density, unit cell edge length, type of crystal lattice, and atomic weight. Understand the energetics of solution formation, and identify which factors favor solution formation and which factors disfavor solution formation. In simple cases, predict or explain the solubility (or insolubility) of one substance in another. Understand and convert between commonly used solution concentration units, such as molarity, molality, mole fraction, and mass percent of solute. Explain commonly observed colligative properties, such as freezing point depression, boiling point elevation, vapor pressure lowering, and osmotic pressure. Given a solution concentration, calculate an estimated freezing point, boiling point, vapor pressure, or osmotic pressure. Use a colligative property to calculate solution concentration and molecular weight of the solute. Understand the dependence of reaction rate on temperature, concentration, surface area, and presence of a catalyst. Use kinetic data to work out the rate law for a chemical reaction. Relate reactant concentrations and reaction times for zero, first, and second order reactions. Predict the rate law for a chemical reaction from a proposed mechanism; discard a mechanism as not correct, when appropriate, based on a comparison of the experimental and predicted rate laws. Use the Arrhenius equation to relate the reaction rate constants at two different temperatures to the activation energy. Explain in terms of reversible reactions, what happens as a chemical system approaches equilibrium, and why an equilibrium system appears to be static, even though the chemical reactions in the system continue to occur at equilibrium. Understand what an equilibrium constant is, and how it can be calculated from a set of equilibrium concentrations. Make the appropriate changes in the equilibrium constant when the chemical reaction it describes is written in a different form, such as being reversed, or being doubled. When combining two or more chemical reactions to get a new reaction, obtain the equilibrium for the new reaction from the equilibrium constants of the starting reactions. Use an equilibrium constant to tell whether reactants or products will be favored in the equilibrium, to calculate a "missing" equilibrium concentration given all the others, and to calculate the final equilibrium composition, given the initial composition. Use an equilibrium constant, in conjunction with an initial composition, to predict the direction of approach to equilibrium. Apply the concepts of equilibrium to acids and bases, and calculate ion concentrations, pH and pOH of acidic and basic solutions. Predict the pH of a buffer, given the concentration of the acid or base and its salt, along with the relevant equilibrium constant value. Calculate equilibrium constants for hydrolysis of conjugate acids and bases, given the equilibrium constants for the parent acids and bases. Apply the concept of equilibrium to slightly soluble salts, and calculate the solubility in distilled water, in a solution containing an ion common to the salt, and in a solution containing a ligand that complexes one of the ions of the salt. Predict, on the basis of ion concentrations, whether or not a slightly soluble salt will precipitate when two solutions are mixed. Understand the significance of the thermodynamic functions enthalpy (H), entropy (S), and Gibbs free energy (G). Use these thermodynamic functions to determine whether a chemical reaction is endothermic or exothermic, whether it increases or decreases the order of the chemical system, and whether it is spontaneous or non-spontaneous. Use thermodynamic functions to calculate equilibrium constants for chemical reactions. Explain the function of voltaic cells in terms of oxidation and reduction reactions occurring in the cell. For a given voltaic cell, predict, on the basis of standard reduction potentials, which electrode will be the cathode and which will be the anode. Calculate cell voltages from the standard reduction potentials of the half reactions. Calculate cell voltages for non-standard conditions using the Nernst equation. Balance redox equations. Understand and describe the 5 modes of radioactive decay. Write balanced equations to describe radioactive decay. Understand factors that contribute to nuclear instability. Date Sunday, August 28 Class Activities Schedule Event Orientation exercises due. Sunday, Chapter 11 assignments due. September 11 Sunday, Chapter 12 assignments due. September 18 Last day to take EXAM 1, covering chapters 11 & 12. This exam must be taken at the Testing Friday, Center, located in Brazos Hall, room 100. Call the Testing Center at September 23 (210) 486-3444 at least 1 business day in advance of when you want to take your exam. The Testing Center does not accept walk-ins or same day appointments. Sunday, October 2 Chapter 13 assignments due. Sunday, October 9 Chapter 14 assignments due. Friday, October 14 Last day to take EXAM 2, covering chapters 13 & 14. This exam must be taken at the Testing Center, located in Brazos Hall, room 100. Call the Testing Center at (210) 486-3444 at least 1 business day in advance of when you want to take your exam. The Testing Center does not accept walk-ins or same day appointments. Sunday, October 23 Chapter 15 assignments due. Sunday, October 30 Chapter 16 assignments due. Sunday, November 6 Chapter 17 assignments due. Last day to take EXAM 3, covering chapters 15, 16, & 17. This exam must be taken at the Friday, Testing Center, located in Brazos Hall, room 100. Call the Testing Center at November 11 (210) 486-3444 at least 1 business day in advance of when you want to take your exam. The Testing Center does not accept walk-ins or same day appointments. Sunday, Chapter 18 assignments due. November 13 Sunday, Chapter 19 assignments due. November 20 Monday, Chapter 20 assignments due. Due date falls on Monday instead of Sunday due to the November 28 Thanksgiving holidays. Friday, December 2 Last day to take EXAM 4, covering chapters 18, 19, & 20. This exam must be taken at the Testing Center, located in Brazos Hall, room 100. Call the Testing Center at (210) 486-3444 at least 1 business day in advance of when you want to take your exam. The Testing Center does not accept walk-ins or same day appointments. Friday, December 9 Last day to take FINAL EXAM, covering chapters 11-20 (comprehensive). This exam must be taken at the Testing Center, located in Brazos Hall, room 100. Call the Testing Center at (210) 486-3444 at least 1 business day in advance of when you want to take your exam. The Testing Center does not accept walk-ins or same day appointments.