Name: ______________________________________________ Per. _________ Date Due: _______________________ The Energy Question The Carbon Question The Movement Question Ethanol Burning Lab Part 1: What do you predict you will observe when ethanol burns? Macroscopic scale: Make predictions about what you will observe. Atomic-molecular scale: Explain your predictions using the Three Questions. Predictions about mass What do you think will gain mass? Draw labeled arrows to show how atoms or molecules might be moving into and out of the flame. Where do you think matter is moving Where do you think matter is going? from? Reactants Products What do you think will lose mass? Predictions about changes in BTB Do you think that BTB will change color if it’s in a closed container with the flame? If YES, what color change do you predict? What molecules do you think carbon atoms are a part of before the ethanol burns? What molecules do you think carbon atoms are a part of after the ethanol burns? Chemical Change What other reactants do you think are needed in order for ethanol to burn? Predictions about energy What forms of energy do you think you will observe? What forms of energy do you think are in the reactants? Energy Transformation Stamp for Part 1: What forms of energy do you think are in the products? Ethanol Burning Lab Part 2: Lab Procedure Use this worksheet to complete the ethanol burning investigation and to record your observations, measurements, and class results. Steps in the investigation: Check the box as you complete each step. 1. ☐ Add 1 dropper-full of ethanol to a watch glass or glass Petri dish. 2. ☐ Turn on a digital scale so that it reads “0.00” g. Place the dish with ethanol on the scale. Record the mass of the ethanol and dish in the data table. 3. □ Place a piece of Cobalt Blue Paper next to the dish and record the initial color. 4. ☐ Place 5 drops of BTB on another watch glass. Record the time and color of the BTB the data table. 5. ☐ Place the dish with BTB next to the dish with ethanol so that the large plastic container lined with aluminum will be able to fit on top of the two dishes. 6. ☐ Light the ethanol with the lighter. Then, immediately put the large container on top of both the dish with burning ethanol and the dish of BTB. Observe: the flame will go out quickly inside the container 7. ☐ Wait 5 minutes before taking the lid off the container. Observe the color of the BTB. Record this in your data table. 8. ☐ Place the dish with ethanol on the digital scale and record the mass. 9. □ Record the color of the BTB and Cobalt Blue Paper after the experiment. 10. □ Calculate the change in mass for ethanol and record on the data table. 11. □ Record your results on the class data table. Observations during the investigation: Record your macroscopic-scale observations below. Use drawings and/or words. Measurements Before Burning Mass of Watch glass with ethanol Measurements After Burning Mass of Watch glass with ethanol Mass: _______________ grams Mass: _______________ grams Color of BTB Change in mass: ____________ grams Changes in color of BTB Color of BTB: ________________________ Color: _______________________ Change in color? Yes / No Color of Cobalt Chloride Paper Changes in color of Cobalt Chloride Paper Color of paper: ________________________ Color: _______________________ Change in color? Yes / No Results for the whole class: Make notes about how the observations and measurements of other groups compared to yours. Describe patterns in your class data. 1. Changes in mass of the Petri dish with ethanol: 2. Changes in color of BTB: Summary of Class Data Change in Mass (g) Final Color BTB Final Cobalt Chloride Control (no burning) Class Data Average Ethanol Burning Lab Part 3: Constructing an Evidence-based Conclusion Constructing Your Conclusion: For each of the Three Questions, consider the evidence you have from your class investigation, the conclusion(s) you can draw based on your evidence, and what questions you are still unable to answer. Check Yourself: Be sure that you follow the rules of matter and energy conservation. Evidence: What patterns in your observations or measurements help you answer the Three Questions? Conclusion: Based on your evidence, what can you conclude about the answers to the Three Questions? Unanswered Questions: What questions can you NOT answer without more evidence? The Movement Question: Where are atoms moving? Evidence Conclusion Unanswered Questions Check Yourself Atoms last forever in combustion and living systems. All materials (solids, liquids, and gases) are made of atoms. When materials change mass, atoms are moving. When materials move, atoms are moving. The Carbon Question: What is happening to carbon atoms? Evidence Conclusion Unanswered Questions Check Yourself Carbon atoms are bound to other atoms in molecules. Atoms can be rearranged to make new molecules. The air has carbon atoms in CO2. Organic materials are made of molecules with carbon atoms: food, fuels, living and dead plants and animals. The Energy Question: What is happening to chemical energy? Evidence Conclusion Unanswered Questions Check Yourself Energy lasts forever in combustion and living systems. C-C and C-H bonds have more stored chemical energy than C-O and H-O bonds. We can observe indicators of different forms of energy: organic materials with chemical energy, light, heat energy, and motion. Burning Ethanol Lab Part 4: Molecular Models You will use models to learn about ethanol burning at the atomic-molecular scale, as you continue to look for answers to “unanswered questions” from your investigation. Introduction There are many different kinds of alcohol. The most common is ethanol, which is the kind of alcohol in alcoholic drinks and in biofuels. (The next time you get gasoline, check the pump to see if it says “10% ethanol.”) Ethanol is a good fuel because it has chemical energy stored in its high-energy bonds: C-C and C-H bonds. When ethanol burns, it reacts with oxygen (O2) in the air to produce carbon dioxide (CO2) and water (H2O). When high energy bonds are broken and low energy bonds (C-O and O-H) are formed, chemical energy is transformed into heat and light energy. Use the molecular models to show how this happens. Using molecular models to show the chemical change 1. Work with your partner to make models of the reactant molecules: ethanol and oxygen. Using the models, show how chemical energy is stored in the high-energy bonds of ethanol. a. ☐ Make models of an ethanol molecule (C2H5OH) and oxygen molecules (O2, with a double bond). The air has lots of oxygen; make three O2 molecules. Put these molecules on the reactant side of the Molecular Models Placemat. b. ☐ When you are finished creating the reactant molecules (O2 and ethanol), put away all extra pieces that you didn’t use from the molecule kit. This is an important step! c. ☐ Use twist ties to represent chemical energy. Put a twist tie around each highenergy bond (C-C and C-H bonds) in the ethanol molecule. d. ☐ Complete the reactants section of the table (on the back of this paper) to keep track of atoms and energy. STOP. Get a teacher or another group that has already completed this step to check your set-up. Make sure you and your partner understand what is represented at this point. If you are not sure, ask for help. 2. Show how the atoms of the reactant molecules can recombine into product molecules— carbon dioxide and water—and show how chemical energy is released when this happens. a. ☐ Take the ethanol and oxygen molecules apart and recombine them into carbon dioxide (CO2) and water (H2O) molecules. Put these molecules on the product side of the Molecular Models Placemat. Answer these questions: i. How many oxygen molecules reacted with 1 ethanol molecule? ____ ii. How many carbon dioxide molecules were produced? _____ iii. How many water molecules were produced? _____ b. ☐ Energy lasts forever, so move the twist ties to the product side of the Molecular Models Placemat. Carbon dioxide and water have only low-energy bonds (C-O and H-O), so what forms does the chemical energy change into? (Re-read the introduction if you aren’t sure.) c. ☐ Complete the products section of the table (on the back of this paper) to keep track of atoms and energy. STOP. With your partner, practice explaining out loud what happens at the atomicmolecular scale when ethanol burns. Get a teacher or another group that has already completed this step to check your explanation. If you are not sure, ask for help. Atoms last forever! Energy lasts forever! Review the table below to account for all the atoms and types of energy in your models. Then answer the “Check Yourself” questions below the table. MATTER ENERGY How many How many How many How many twist What forms of ties? energy? carbon oxygen hydrogen atoms? atoms? atoms? Reactants Ethanol Oxygen REACTANTS TOTALS Products Carbon Dioxide Water PRODUCTS TOTALS Check Yourself! 1. Did the number and type of atoms stay the same at the beginning and end of the chemical change? ____ 2. Did the number of twist ties (representing energy) stay the same at the beginning and end of the chemical change? ____ 3. Why do the numbers of atoms and twist ties have to stay the same? Write a balanced chemical equation using the molecular formulas and the yield sign ():