Reactivity of Metals Research Name: Go to Google and type in reactivity of Metals and choose the following site from the list: http://group.chem.iastate.edu/Greenbowe/sections/projectfolder/flashfiles/redox/home.html 1. What are you going to do in the exercises? __________________________________________ 2. (click start) List the solutions below each beaker and click on each to write in what 2 ions appear in each solution: (Some of them may not show in the beaker with the magnifying glass – it just depends on how cooperative the simulation is being. If one or more don’t work – use the BALANCED formula of the compound to determine what 2 ions are in there. You can have your answer checked for those if you are unsure!) _____________ _____________ _____________ _____________ _____________ _____________ _____________ _____________ *Also INDICATE THE COLOR of each solution!!! You could actually color them if you have the untensils! *Why are they not showing the water molecules if this is an “aqueous” solution? _________________________ 3. (Click Activity 1) Choose a metal and then click the button to test them with the solutions. Click again when it says they are ready to remove. Record your observations on the chart, and then repeat the procedure with the other solutions: Metals Mg Cu Zn Ag Magnesium nitrate Zinc II nitrate Copper II nitrate Silver nitrate *Which metal reacted with the MOST solutions? ____________ Which is the LEAST reactive? ________________ Now Click the MOLECULAR SCALE REACTIONS button. Then try the simulation with the combinations on the back and record what you observe. BE SPECIFIC! What ions are present and what do they do when they contact each other? Quick tips: solution is abbreviated soln and reaction is abbreviated rxn! Save yourself writing time and use these! Try this! WHAT HAPPENS – Don’t forget to be specific!!! Give details about what the ion charge is as well as what exchange of e-s occur… Now click on the “STEP by STEP button. Write BOTH equations that show what chemical reaction occurs – unless the button doesn’t appear- in which case, you just say NO REACTION WHAT HAPPENS – Don’t forget to be specific!!! Give details about what the ion charge is as well as what exchange of e-s occur… Now click on the “STEP by STEP button. Write BOTH equations that show what chemical reaction occurs – unless the button doesn’t appear- in which case, you just say NO REACTION WHAT HAPPENS – Don’t forget to be specific!!! Give details about what the ion charge is as well as what exchange of e-s occur… Now click on the “STEP by STEP button. Write BOTH equations that show what chemical reaction occurs – unless the button doesn’t appear- in which case, you just say NO REACTION WHAT HAPPENS – Don’t forget to be specific!!! Give details about what the ion charge is as well as what exchange of e-s occur… Now click on the “STEP by STEP button. Write BOTH equations that show what chemical reaction occurs – unless the button doesn’t appear- in which case, you just say NO REACTION Mg in Mg soln Mg in Cu soln Mg in Zn soln Mg in Ag soln Try this! Cu in Mg soln Cu in Cu soln Cu in Zn soln Cu in Ag soln Try this! Zn in Mg soln Zn in Cu soln Zn in Zn soln Zn in Ag soln Try this! Ag in Mg soln Ag in Cu soln Ag in Zn soln Ag in Ag soln Were you able to predict what you would write in the last column for silver EVERY time????________ Now experiment with Activities 2 and 3 and record the reactivity results for the additional metals: Reactivity of Metals Research (continued) Name: Activity 2 – Fe Cu Zn Pb - If you are unsure if there has been no rxn, you may click on the molecular level button for a closer look: Metals Fe Cu Zn Pb Iron II nitrate Zinc II nitrate Copper II nitrate Lead II nitrate *Which metal reacted with the MOST solutions? ____________ Which is the LEAST reactive? ________________ Activity 3 - Fe Pb Ni Sn Metals Fe Pb Ni Sn Iron II nitrate lead II nitrate nickel II nitrate tin II nitrate *Which metal reacted with the MOST solutions? ____________ Which is the LEAST reactive? ________________ Activity 4: REACTION with HCl: Click on each of the metals to drop in the acid. Be sure to wait until they are “done” before you remove them. Record the observations you can observe with the naked eye and then check things out on the molecular level to see if the electrons are being transferred. Remember these simplifications represent a SINGLE REPLACEMENT reaction IF a reaction occurs…. Metal with HCl Observations with naked eye Molecular level activity Ag Cu Fe Mg Ni Pb Sn Zn Predict what Au would do: What is the product that provides the bubbles when the metal does react with HCl? ____________ Reaction or NOT???? Now that you know what reacts and what isn’t likely to, predict the products for the following reactions or say NO REACTION if there is not going to be a replacement because you have a less active metal trying to replace a more reactive one! To the right is the complete reactivity series, so now you can plug in others that you have not played with before. Also use it to answer the questions before you try the reactions: A. What group/family is the most active of all? ________________ B. Where on the table are the LEAST active metals?______________ C. List any metals that WILL NOT reactive if placed in HCl: ___________ D. What elements would “replace” Mg due to their high level of reactivity? __________________________________________ Reactions: Remember write the products or no reaction if it will not take place. 1. Sodium nitrate reacts with tin 2. Calcium reacts with aluminum nitrate 3. Potassium reacts with copper II sulfate 4. Silver nitrate reacts with sodium hydroxide 5. Write JUST the half-reaction of the follow single replacement (remember from the simulation, this only includes the positive ions and metals – no negative ions! Calcium chlorate reacts with sodium