Fourth-fifth Grade Mixtures and Solutions -Lesson 4 INTENDED CURRICULUM BIG IDEA: (display in class during the lesson) Elements and their combinations account for all the varied types of matter around us. Idaho Standard(s) addressed: 4.S.2.1.2 Describe the physical properties of solids, liquids, and gases. (590.01.b) 4.S.2.1.3 Explain the changes caused by heating and cooling materials. (590.01.c) 5.S.2.1.2 Compare the physical differences among solids, liquids and gases. CL: D Content Limit: Students will be able to recognize the differences in molecular distance between a solid, a liquid, and a gas, as well as differences in basic molecular motion. 5.S.2.1.3 Explain the nature of physical change and how it relates to physical properties. CL: D Content Limit: Students will be able to recognize the change(s) in physical properties that take place when physical changes occur including ice melting into water and water being heated into steam and the reverse processes . LESSON CONTENT GOALS GUIDING QUESTIONS 1) The speed and movement of atoms increases from solids to liquids to gases. 1) How does the speed and movement of atom change during physical changes? 2) A saturated solution is one in which no more solid can be dissolved into the solution. 2) What is a saturated solution? 3) A solute such as salt lowers the freezing point of a solvent such as water. 3) How does adding a solute affect the freezing point of a solvent? 4) The mass of a mixture is the same as the combined masses of its components. 4) How is the mass of a mixture related to the mass of its components? Teacher’s notes TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 1 IMPLEMENTED CURRICULUM Teacher’s Notes: This lesson will review and build on the basic properties of solids, liquids and gases learned in the third grade Water unit. Advanced Preparation and useful science concepts: (1) Recall that the big idea of this unit is that all of the variety of materials around us comes from just a few elements. In other words, all matter, from my pillow to the river to people, is composed of elements like carbon, hydrogen, oxygen and nitrogen. The elements combine to form molecules that are specific to each thing, and most of the matter that we encounter on a daily basis is actually a mixture of many different types of molecules. Another important way that matter varies is in its physical state. Common physical states are solids liquids and gases. The main thing to know about these states is that molecules do not change from one state to the next. In other words, a water molecule is H2O (two hydrogen atoms bonded to one oxygen atom) whether it is ice, water or steam. The only difference from one state to the next is how the H2O molecules are stuck together. Physical states can be converted back and forth, which is called physical change. Boiling, melting, condensing and vaporizing are common physical changes. (2) If you would like, a computer simulation of solids, liquids and gases can be used as a demonstration during the making meaning conference to review the difference between solids, liquids and gases at the molecular level. I really like the phet simulation on changes of state: http://phet.colorado.edu/en/simulation/states-of-matter-basics. Quick directions: - Run the simulation - Click on the water on the right hand side of the window, and then you can select solid, liquid or gas also on the right menu. - The simulation displays the speed and connectivity of the molecules in each state. - Note that, when a compound is a solid, it is held together by forces (hydrogen bonds) locking the molecules in place. When you heat and melt the solid, the forces are broken and the molecules are freer to move and flow as a liquid. Even more energy added breaks all of the forces and also speeds up the molecules so they fly all over the place as a gas. TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 2 Instead of, or in addition to, the computer demonstration, you can do an interpretive dance: the solid, liquid and gas dance (SLAG dance): -Solids: students stand at arms length in place and bounce around but don’t move. This mimics the forces (the hydrogen bonds in water) holding together molecules in a solid and also that solids are a fixed shape. -Liquids: students stay together as a group but slowly mill around close to one another. This mimics the few forces holding together molecules in a liquid and also that liquids are a fixed volume, but not a fixed shape. -Gas: students can bounce around the classroom. Gases have no forces holding them together and thus their molecules fill all available space. Note that, in all states, the molecules are the same (H2O is always H2O, whether it is a solid, liquid or gas) it is just the forces, the hydrogen bonds, holding together the molecules that differ. Also note that the salt lowers the temperature at which water freezes because it blocks the water from forming hydrogen bonds. You can include this in your SLAG dance by first having students for hydrogen bonds in an open space (modeling pure water) and then doing it in a classroom with lots of tables or desks, which are the sodiums and chlorides. . (3) In this lesson, students will prepare three different concentrations of solutions of salt and water: pure water, a ½ spoonful of salt in 25 mL water and 1 spoonful of salt in 25 mL of water. The highest concentration solution is a saturated salt solution, meaning that it is not possible to dissolve more salt in the water. You will need to put the solutions in the freezer for a night. The pure water and the solution with a ½ spoonful of salt in it should freeze while the saturated solution does not. Do test the saltwater concentrations in your freezer before doing the experiment with your students to make sure that only the saturated solution does not freeze. If the ½ spoonful concentration also does not freeze, then use less salt. (4) If you are feeling excited about changes of state, this is a good time to make slime or jello (making a semi-solid from a semi-liquid). TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 3 Materials for a group of 4 students: 3 small paper cups that can be put in the freezer A 25 mL syringe or graduated cylinder A plastic spoon About 100 mL water Stirring sticks Kosher salt (at least 4 spoonfuls per table) A tray to put the cups on Tape for labeling the cups A balance from the measurement kit (optional) Also need a freezer with enough space to hold three cups per group. Brief Lesson Review Read engaging scenario Review solids, liquids and gases and then talk about how salt might prevent water from freezing. Discuss the problem based on the given scenario and write a focus questions from that discussion. Write a prediction. Students make salt solutions and they are place in the freezer overnight. Making Meaning Conference: guided discussion on writing claims based on evidence obtained + SLAG dance or computer demonstation Claims and Evidence: write claims and evidence focusing on guiding questions Conclusion: writing a report of findings. Reflection: writing about types of matter: mixtures, solutions, pure compounds. TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 4 DAY ONE ENGAGING SCENARIO Teacher says: “Clearwater Construction is very pleased with your help in identifying their unknown compound. Now they have another mystery that they would like you to solve: although it is winter and the temperature is below freezing, the water on the ground at their construction site remains a liquid. They are very curious to understand why this is happening and think that it might have something to do with the salt that is on their construction site. What is the problem here?” Teacher’s Notes: Word Wall- Freeze: to change from a liquid to a solid (opposite of melting) Word Wall- Freezing point: the temperature at which a liquid freezes. Students are to think what problem(s) they need to solve for this next investigation. Solicit ideas for the focus questions from the class and display on the board. Make a selection of the one that will best solve the problems in the scenario. Students write CLASS FOCUS QUESTION in their notebooks, if it is different from theirs. Check notebooks and provide feedback when necessary. FOCUS QUESTION (discuss by groups, display, record in notebooks) SUGGESTED CLASS FOCUS QUESTIONS How can we find out if table salt stops water from freezing? Or How does the concentration of table salt affect the freezing of a salt solution? TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 5 PREDICTION (discuss by groups, record in notebooks) Teacher’s Notes Example of a Prediction: I think table salt [stops or does not stop] water from freezing because__________________. For example: I think table salt stops water from freezing because my parents put salt on the steps when it is icy out. DAY TWO: PLANNING Teacher’s Notes and Instructions: Planning how to determine if table salt stops water from freezing. Teacher says, “Let’s discuss in our groups to come up with a way of finding out if table salt stops water from freezing. ” Allow them time to discuss. Listen in to see if the idea of dissolving salt in water and putting it in the freezer comes up. Help if needed. Teacher says, “We need to test pure water and several Word Wall- Concentration: the amount of one compound in a mixture. concentrations of salt in water to see how the concentration affects whether the solution freezes or not. We will need to record our data in a chart. We are going to test three different Word Wall- Saturated: a solution with the maximum amount of a solute dissolved in it. concentrations of salt in water: pure water, a ½ spoonful in 25 mL water and a saturated solution.” Lead students on a discussion about saturation. After the discussion, have them copy the chart into their notebooks. Here Word Wall- Solubility: the amount of a solute in a saturated solution. TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 6 are a few talking points in the discussion: - You might have seen a saturated solution when you have made kool-aid. Some of the sugar doesn’t dissolve and stays at the bottom of the pitcher. - You have to stir a mixture for a few minutes to see if it is really saturated. If after a few minutes of stirring, there is still solid on the bottom of your cup, then the solution is saturated. - Temperature matters to some solutions. For example, a lot of sugar can be added to hot water but not to cold water. In contrast, the amount of table salt in a saturated solution doesn’t depend on temperature; it dissolves readily no matter if the water is cold or hot. - Different compounds have differing amounts that can be added to a solution before the solution becomes saturated, called the compound’s solubility. [note: This is something that students can test if you have time and inclination: see how much of the Epsom salts can be dissolved in water, or sugar, and compare it to table salt. You can measure spoonfuls or the weight of the solid that can be dissolved. This is also a great opportunity to make rock candy and show students how much sugar dissolves in hot water compared to cold water. Directions for rock candy are found on the web.] Chart 1: Determining if table salt stops water from freezing. Concentration of table salt in 25 mL water 1 spoonful ½ spoonful 0 (pure water) A. Is the solution saturated? B. Does the solution freeze? TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 7 DAY THREE: THE EXPERIMENT Re-read the class FOCUS QUESTION and review the plan. Have the following materials available for each group: 3 small paper cups that can be put in the freezer, a 50 mL syringe or graduated cylinder, a plastic spoon, about 100 mL water, stirring sticks, kosher salt (at least 4 spoonfuls per group), tray to put the cups on, tape for labeling the cups Instruct your students to first label their cups with the amount of salt that they plan to add. Then, have them add 25 mL water to each cup followed by the salt. They should stir their mixtures. The ½ spoonful of salt should dissolve, but a bit of the salt should remain on the bottom of the cup with 1 full spoonful in it. In other words, the 1 spoonful of salt mixture should be saturated. If it is not saturated, then have the students add a bit more salt. It does take a few minutes of stirring to get the salt dissolved. Have students fill in column A in their chart. Extension exercise: Using the balance from the measurement kit, have students compare the mass of the two salt solutions. The one that is more concentrated has a greater mass because the mass of a mixture is equal to the mass of its components. You can also do this as a demonstration. Place the cups in your freezer for the night. TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 8 DAY FOUR: MAKING MEANING CONFERENCE (Teacher directed) Give students an opportunity to observe their cups of pure water and salt water, and to record their observations in their charts. 1) Share and display findings. Remember, this is the conferencing stage. It is preferable that students contribute with their ideas. Ask students to share the information they have written on their chart. Replicate the chart on the board or an overhead to analyze data. If students need to check the information they wrote on their charts, this is the right time to do it. 2) Looking for patterns from the data charts: Guide students to analyze the data by asking the following questions: Did the salt dissolve in water? How can you tell? Were any of the mixtures saturated? Which one? Did the mixtures have the same concentrations? (extension) Which solution had the greater mass? (ans. The more concentrated one) Did the mixtures have the same physical properties such as: o Did they have the same appearance? o Were they solutions? o Did they freeze? 3) Discuss phase changes and do a computer simulation and/or SLAG dance (see page 2 of this lesson) At this point, you will want talk with your students about phase changes so that they can picture how salt is preventing the water by interrupting the hydrogen bonds. Use either the computer simulation or the SLAG dance described on page 2 of this lesson to explain phase changes and the effect of added salt. Also remind them that they have seen vaporization in the last two lessons. Word Wall- Phase change: when a solid, liquid or gas changes to a different state of matter. Freeze: liquid to solid Melt: solid to liquid Vaporize: liquid to gas Condense: gas to liquid Guide students to understand the computer simulation/SLAG dance by asking the following questions: How are solids, liquids and gases different from one another? [ans: they have different amounts of forces holding them together + the speed of the atoms/compound] How are solids, liquids and gases the same? [ans: the identity of the atoms/compounds stays the same. I.e. H2O stays H2O no matter the state of matter it is in] How does salt prevent water from freezing? [ans: it stops the formation of forces holding the water molecules together] TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 9 4) Guide students in writing CLAIMS from the evidence on the data chart as a group. Examples CLAIMS EVIDENCE I claim that ….. I claim this because….. I know that….. I know this because….. 1.Mixtures with different concentrations have different physical properties. 1. The saturated solution did not freeze but the lower concentration solution did freeze. 2. 1 spoonful of salt in 25 mL water is a saturated solution. 2. Not all of the salt dissolved in the cup with1 spoonful of salt in 25 mL water. Some stayed on the bottom of the cup. 3. A high concentration of salt is needed to lower the freezing temperature of water.* 3. Only the saturated solution remained a liquid in the freezer. 4. Solids have many forces between them and liquids do not.* 4. The saturated salt solution did not freeze (note: this one looks like a big jump from the evidence to the claim, but it is actually how chemists think!) * It is unlikely that students will come up with these on their own. Instead, you will have to guide them to it. CLAIMS AND EVIDENCE (record in notebook) Teacher says “You are now going to write 3 claims and evidence statements. I want you to look at the guiding questions and answer them with a claim based on the evidence. Revisit the class data chart in order to write your claims. Record them on your notebook.” Example sentence structures: I claim that ____________________I claim this because __________________. I know that__________________. I know this because _________. Share and discuss claims and evidence with the class Check and provide feedback TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 10 DAY FIVE: conclusion and reflection CONCLUSION (record in notebooks) Ask your students to write a 1-2 paragraph report or business letter to the Clearwater Construction Company telling them how to solve the problem presented in the engaging scenario. Check and provide feedback REFLECTION (record in notebooks) Students will revisit the “Big Idea” and their results. They write a new investigable question I wonder if……. What about if………What would happen if……….. that is related to the topic covered and “big idea”. Check and provide feedback TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 11 ACHIEVED PROFICENCY FEEDBACK: CURRICULUM This guide is: to be posted on the board/butcher paper so students know what is expected in their notebooks to be an evaluation tool for teachers as students work in their notebooks to be converted into questions as a student self assessment piece Suggested PROFICIENCY FEEDBACK GUIDE MIXTURES AND SOLUTONS LE 4 S T Focus Question Question written clearly Related to the scenario Prediction Two Related to freezing and salt uses “because” Us Data 1 chart complete and accurate labeled with titles Claims & Evidence 3 complete sentences showing understanding of guided questions Conclusion Grammatically correct Describes results Reflection writes one question for further investigation TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 12 ENGAGING SCENARIO LESSON 4 “Clearwater Construction is very pleased with your help in identifying their unknown compound. Now they have another mystery that they would like you to solve: although it is winter and the temperature is below freezing, the water on the ground at their construction site remains a liquid. They are very curious to understand why this is happening and think that it might have something to do with the salt that is on their construction site. What is the problem here?” TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 13 Chart 1: Use the first one if you did not measure mass and the second one if you did. Chart 1: Determining if table salt stops water from freezing. Concentration of table salt in 25 mL water 0 (pure water) Is the solution saturated? Does the solution freeze? ½ spoonful 1 spoonful TESLA Scaffolding Guided Inquiry Mixtures and Solutions Draft 072613 Lesson 4 – Characteristic Properties of Some Solids, Liquids and Gases 14