0PHY455 Spring, 2014 Exam #2 1. Calculate for potassium, K, a. the Fermi wavevector in Å-1 b. the Fermi energy in eV c. the Fermi temperature in K. 2. For an electron gas in two dimensions: a. Derive the relationship between the electron concentration and the Fermi wavevector. Assume a valency of 3 free electrons per atom. b. Derive an expression for the density of levels, D(). 3. For a 2D gas at T=0, a valency of 3, N atoms and area A, find the total energy of the system in terms of A,N,m,and h. 4. Sketch the f(), D( a. T=0 n(), vs. for a 3D electron gas at b. T~1000K 5. Referring to the results of #4, briefly explain the origin of the linear term in the heat capacity for metals. 6. For the SCC of side a, give the G vector and resultant necessary to reduce the following k vectors into the 1st Brillouin Zone: a. 3/a[110] b. 11/a[111] c. 9/2a[231] d. 3/2a[010] e. /2a[001] 7. a. For an electron gas, find the occupation probability for a state 0.250 eV above the chemical potential for these temperatures: 100K and 10,000K. b. Repeat for a state 0.250 eV below the chemical potential. c. Comment on/briefly discuss the results (do they make sense...?) 8. For a 1D crystal with valency 1 and lattice of spacing 2.0 Å, a. Plot the real lattice, the reciprocal lattice and the 1st and 2nd Brillouin Zones. b. Find the "radius" of the Fermi surface in Å-1 and sketch the Fermi surface in a reduced zone scheme. c. Find the "radius" of the Fermi surface and sketch the Fermi surface in a reduced zone scheme assuming a valency of 3. 9. For a 2D rectangular lattice with dimensions of 2Å and 5Å a. plot the real space lattice. b. Plot the reciprocal lattice; give dimensions. c. Plot the 1st and 2nd Brillouin Zones on the plot above. 10. Given the electrical conductivity of K at 295K, find a. the lifetime in s and b. the mean free path of an electron in Å. Hint: ohm is in SI units; you just need to covert cm-1. S13 1. Sketch the temperature dependence of the heat capacity for a free electron gas and for a metal. Explain what contribution is due to electrons. 2. For an electron gas in one dimension: a. Derive the relationship between the electron concentration and the Fermi wavevector. Assume a valency of 1 free electron per atom. b. Derive an expression for the density of levels, D(). 3. Sketch the occupation probability, f() vs. for an electron gas at a. T=0, b. T~50K and c. T~2000K. 4. a. For an electron gas, find the occupation probability for a state 0.200 eV above the chemical potential for these temperatures: 50K and 2000K. b. Repeat for a state 0.200 eV below the chemical potential. 5. For the SCC of side a, give the G vector and resultant necessary to reduce the following k vectors into the 1st Brillouin Zone: a. 7/a[100] b. 9/a[111] c. 3/2a[231] 6. Calculate for Cs, a. the Fermi energy in eV b. the Fermi wavevector in cm-1 c. the Fermi temperature in K. 7. For a 2D crystal with valency 1 and square lattice of side 3.0 Å, a. Plot the reciprocal lattice and the 1st and 2nd Brillouin zones. b. Find the radius of the Fermi circle in Å-1. Use kF2 = 2p N A from a previous homework assignment. c. Sketch the Fermi circle in a reduced zone scheme on the plot above. d. Find the radius of the Fermi circle and sketch the Fermi circle in a reduced zone scheme assuming a valency of 2. 8. Consider the free electron energy bands of an SCC crystal in the reduced zone scheme. Find the energy of the first 7 bands at the center of the zone and at the zone boundaries in the (100) direction in terms of the lowest band energy at the zone boundary (call it Eo); and sketch the bands in the reduced zone scheme. 9. At 295 K, the conductivity of Na is 2.11x105 (ohm.cm)-1. Use that to estimate the average collision time.