Lesson Title: Plants versus Pollutants Model Eliciting Activity Resource ID: 37190 Description: The Plants versus Pollutants MEA provides students with an openended problem in which they must work as a team to design a procedure toselect the best plants to clea n up certain toxins. This MEA requires students to formulate a phytoremediationbased solution to a probleminvolving cleaning of a contaminated land site. Students are provided the co ntext of the problem, a request letter from a client asking them toprovide a recommendation, and data re levant to the situation. Students utilize the data to create a defensible model solution to present to the client. Document Note This file contains the student handouts for the MEA; you can access and download all of the teacher instructional materials at: http://www.cpalms.org/Public/PreviewResourceLesson/Preview/37190 Subject(s): NGSSS: Science,CCSS: Mathematics,CCSS: English Language Arts Grade Level(s): 9,10,11,12 Intended Audience: Educators Instructional Time: 3 Hour(s) Resource supports reading Yes in content area: Keywords: Instructional Component Type(s): MEA, model eliciting activity, model-eliciting activity, modeling, phytoremediation, toxins, pollution, problem-solving, plants Lesson Plan (Primary Type), Problem-Solving Task, Model Eliciting Activity (MEA) STEM Lesson Center for Opportunities in Environmental Research 1414 Copper Road, Dirty Dirt, GA 30000 ________________________________________________ Dear Research Advisors, I am the Senior Vice President of Toxins Research at the Center for Opportunities in Environmental Research (COPPER). We are interested in learning more about how plants can be used to clean up land areas contaminated by industrial chemical waste. This process is known as phytoremediation. Briefly, phytoremediation is a plant-based method for extracting toxic material from contaminated areas. This method is less invasive than methods that involve digging and physical removal of material for cleaning. To carry out this method, plants are selected for their ability to remove certain contaminants, planted, and cultivated on a contaminated site. After harvest, toxins that have been taken up by the plants may possibly be recovered. More research must be done, however, to understand which plants are good at accumulating which contaminants. We are writing to you to request a research plan for conducting phytoremediation studies at four new research laboratories. These labs are located in the immediate vicinity of abandoned industrial manufacturing sites. In the past, the industrial operations produced waste byproducts that have, over time, contaminated the surrounding soil with compounds containing arsenic, cadmium, copper, lead, and zinc. Residents at new home developments in the area are potentially at risk because these toxins remain in the soil for long periods of time. Children and pets frequently play outdoors near these sites and may possibly ingest dust or otherwise be exposed to the contaminated soils. Each site has a unique soil contamination profile. Ideally, the research conducted at each lab will address the contamination in that area. You will be provided with basic information to help in decision making and in planning how research efforts should be distributed at each laboratory. Your formal response must contain the following: • A list of plant species you think would be most useful to our research at each of the sites • A step-wise description of the procedure you used to select these plants • Evidence of quantitatively-supported reasoning To support your choice of plants to be studied at each test site, please provide mathematical and/or graphical evidence demonstrating each plant's effectiveness at phytoremediation after 1 growing/harvest cycle, 1 year, 5 years, and 10 years for a contaminated plot of approximately 7 hectares. Please also be sure that your response letter is written in a formal style, with cohesive structure, transitions, precise language, concrete details and information, a formal style and tone, and a concluding statement so that we can share your letter with our funding agency to request more funding in the future. Thank you for your cooperation in this important endeavor. We look forward to conducting this research aided by your recommendations. Sincerely, Selene Argentum, PhD SVP Toxins Research COPPER Provided Materials Project Notes Research Advisors may suggest up to three plants to be studied at each laboratory Any plant may be studied at any site Deliverables Research Advisors are responsible for the following deliverables: A list of plant(s) and associated metal(s) to be studied at each laboratory (fill out the Research Advisor Reporting Guide) A formal response letter (use the Letter Template if needed) that must contain the following: o A list of plant species you think would be most useful to our research at each of the sites o A step-wise description of the procedure you used to select these plants o Please be sure that your response letter is written in a formal style, with cohesive structure, transitions, precise language, concrete details and information, a formal style and tone, and a concluding statement Mathematical and/or graphical evidence demonstrating each plant's effectiveness at phytoremediation after 1 growing/harvest cycle, 1 year, 5 years, and 10 years for a contaminated plot of approximately 7 hectares. This can be included in your letter or as a separate attachment. Data Provided for you are data related to what we know already about certain plant species and their ability to accumulate particular metals from contaminated soil (Dataset: Metal Concentrations in Herbaceous Crops). You will need to use these data to inform your decisions. You may wish to consult additional sources as this may improve your ability to make informed decisions. Industrial Site Contamination Profiles Table 1. Contamination by Industrial Site Site Associated Laboratory Contaminant(s) and Percentage of Contamination 1 A 1 Arsenic (60%), Cadmium (73%), Copper (100%) B 2 Cadmium (30%), Lead (90%), Zinc (50%) C 3 Cadmium (40%), Copper (100%) D 4 Arsenic (50%), Lead (80%), Zinc (60%) 1 Soil at each site was tested with random selection of multiple samples across the suspected contaminated area. Percentage values represent the fraction of samples that tested positive for toxic levels of that particular contaminant. Material Safety Data Sheet (MSDS) Information: Health Hazard Ratings Health Hazard Data includes information on acute (short-term) and chronic (long-term) health effects, signs and symptoms. This section may be less relevant for residential settings where long-term exposures to low doses and complex chemical mixes are more common. Also, since most of the information was developed in relation to adult male exposures, it may be less relevant in residential settings where at-risk populations such as children, the infirm and the elderly live. *Retrieved online from: www.cmhc-schl.gc.ca/en/co/maho/gemare/gemare_012.cfm Table 2. MSDS Health Hazard Codes and Meanings Rating Code Meaning 0 No unusual hazard 1 May be irritating 2 May be harmful if inhaled or absorbed 3 Corrosive or toxic. Avoid skin contact or inhalation 4 May be fatal on short exposure. Specialized protective equipment required * MSDS information retrieved online from: www.ehs.neu.edu/laboratory_safety/general_information/nfpa_hazard_rating/ Table 3. Health Hazard Ratings Contaminant Rating Arsenic 3 Cadmium 3 Copper 2 Lead 1 Zinc 1 * MSDS information retrieved online from: www.sciencelab.com Material Safety Data Sheet: Exposure Effects Arsenic (As) Short term/acute exposure: Very hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant). Long term/chronic exposure: The substance is toxic to kidneys, lungs, the nervous system, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Cadmium (Cd) Short term/acute exposure: Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant, sensitizer), of eye contact (irritant). Severe over-exposure can result in death. Long term/chronic exposure: The substance is toxic to kidneys, lungs, liver. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Copper (Cu) Short term/acute exposure: Very hazardous in case of ingestion. Hazardous in case of eye contact (irritant), of inhalation. Slightly hazardous in case of skin contact (irritant). Long term/chronic exposure: The substance is toxic to lungs, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Lead (Pb) Short term/acute exposure: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Long term/chronic exposure: The substance may be toxic to blood, kidneys, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage. Zinc (Zn) Short term/acute exposure: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Long term/chronic exposure: Repeated or prolonged exposure is not known to aggravate medical condition. * MSDS information retrieved online from: www.sciencelab.co Dataset: Metal Concentrations in Herbaceous Crops* Latin Name Common Name As Cd Cu Pb Zn Plants/ hectare (ha) Metric tons /ha (Dry) Root Depth (m) Root Type Days or Years to maturity Notes Brassica carinata A. Braun1 Ethiopian mustard 12 12 37 50 1650 1250000 5.50 <1 Fibrous 160d Brassica juncea (L.) Czern.1 Mustard greens 30 10 71 55 2029 200000 9.53 <1 Fibrous 60d Hordeum vulgare L. 1 Barley 20 0.4 4 16 27 334 3000000 2.24 <1 Fibrous 90d Oryza sativa L. 1 Rice ND ND 34 6 90 220000 20.18 <1 Fibrous 150d Raphanus sativus L. 1 Radish ND 9.4 34 28 1450 300000 13.45 <1 Taproot 28d Triticosecale, cv. ‘Trujillo’1 Triticale 21 1.9 27. 5 37 588 4000000 7.85 <2 Fibrous 110d extensive roots Salix viminalis 'Orm'2 Osier (tree), leaves only ND 4.3 7.6 2.9 362.5 14000 13.61 <2 Fibrous 4y extensive roots cultivated under flooded conditions *metal concentrations are expressed as mg of metal per kg of plant material Note. All data values are to be considered reasonable and approximate. ND=no data available 1 Vamerali, T., Bandiera, M., & Mosca, G. (2010). Field crops for phytoremediation of metal-contaminated land. A review. Environmental Chemistry Letters, 8, 1-17. 2 Vervaeke, P., Luyssaert, S., Mertens, J., Meers, E., Tack, F.M.G., & Lust, N. (2003). Phytoremediation prospects of willow stands on contaminated sediment: a field trial. Environmental Pollution, 126, 275-282. 5 Research Advisor Reporting Guide Laboratory 1 (Industrial Site A) Plant(s) Associated Metal(s) Laboratory 2 (Industrial Site B) Plant(s) Associated Metal(s) Laboratory 3 (Industrial Site C) Plant(s) Associated Metal(s) Laboratory 4 (Industrial Site D) Plant(s) Associated Metal(s) Center for Opportunities in Environmental Research 1414 Copper Road, Dirty Dirt, GA 30000 ________________________________________________ Dear Research Advisors, Thank you for your earlier efforts to help us choose plants for our phytoremediation research. We sincerely appreciate that effort and would like to invite you to provide an additional analysis with new information we received just this week. Based on your earlier performance, we are confident you can utilize your methods from before to carry out this new analysis swiftly. Recent efforts in our program have identified a new set of plants that may be of use in our phytoremediation program (see Dataset 2; new plants are shaded) and we would like for your group to evaluate these plants against the earlier set of plants. The new plant information should be considered with the earlier information as we do not know how the entire group of plants compares. Please send a formal response in the same style as before, including all required material, but be sure to consider the new plants as part of your evaluation. If any new plants are determined to be superior in any way versus the plants considered earlier, please highlight this change in your response. Public outreach is an important component of scientific research. To help explain to a public audience how this research is important, please also include a statement of how your site-specific phytoremediation research decisions might impact the global discussion on remediation of industrial waste sites. Following this round of analysis, we will be able to make a final decision to guide our research program efforts. Thank you very much. Regards, Selene Argentum, PhD SVP Toxins Research COPPER Dataset 2: Metal Concentrations in Herbaceous Crops* Latin Name Common Name As Cd Cu Pb Zn Brassica carinata A. Braun1 Ethiopian mustard 12 12 37 50 1650 Brassica juncea (L.) Czern.1 Brassica napus L. 1 Mustard greens Canola 30 10 71 55 2029 5.8 11 40 39 1400 Festuca spp. 1 Fescue ND ND 106 ND 90 Glycine max (L.) Merr. 1 Plants/ hectare (ha) Metric tons /ha (Dry) Root Depth (m) Root Type Days or Years to maturity 1250000 5.50 <1 Fibrous 160d 200000 9.53 <1 Fibrous 60d 500000 6.73 <1 Taproot 90d 500000 15.69 <0.2 Fibrous 180d Soybean 230 2.4 440 72 430 250000 2.76 <2 Fibrous 90d Hordeum vulgare L. 1 Barley 20 0.44 16 27 334 3000000 2.24 <1 Fibrous 90d Oryza sativa L. 1 Rice ND ND 34 6 90 220000 20.18 <1 Fibrous 150d 300000 13.45 <1 Taproot 28d 4000000 7.85 <2 Fibrous 110d 14000 13.61 <2 Fibrous 4y 100000 2.74 <1 Fibrous 1y Raphanus sativus L. 1 Radish ND 9.4 34 28 1450 Triticosecale, cv. ‘Trujillo’1 Triticale 21 1.9 27.5 37 588 Salix viminalis 'Orm'2 Pteris vittata L.3 Osier (tree), leaves only Brake fern ND 4.3 7.6 2.9 362.5 2000 ND ND ND ND Notes Requires flooding extensive roots extensive roots extensive roots *metal concentrations are expressed as mg of metal per kg of plant material Note. Plants new to the table are highlighted. ND=no data available 1 Vamerali, T., Bandiera, M., & Mosca, G. (2010). Field crops for phytoremediation of metal-contaminated land. A review. Environmental Chemistry Letters, 8, 1-17. 2 Vervaeke, P., Luyssaert, S., Mertens, J., Meers, E., Tack, F.M.G., & Lust, N. (2003). Phytoremediation prospects of willow stands on contaminated sediment: a field trial. Environmental Pollution, 126, 275-282. 3 Koller, C.E., Patrick, J.W., Rose, R.J., Offler, C.E., & MacFarlane, G.R. (2008). Arsenic and Heavy Metal Accumulation by Pteris vittata L. and P. umbrosa R. Br. Bulletin of Environmental Contamination and Toxicology, 80, 128-133. Research Advisor Reporting Guide Laboratory 1 (Industrial Site A) Plant(s) Associated Metal(s) Laboratory 2 (Industrial Site B) Plant(s) Associated Metal(s) Laboratory 3 (Industrial Site C) Plant(s) Associated Metal(s) Laboratory 4 (Industrial Site D) Plant(s) Associated Metal(s) Dear __________________________, Our team, ___________________________________, has determined that the following plants should be studied at each of the following sites: Site 1: Site 2: Site 3: Site 4: Our team has determined that you should use the following procedure for selecting plants: Sincerely, ______________________________ Dear __________________________, Our team, ___________________________________, has determined that the following plants should be studied at each of the following sites: Site 1: Site 2: Site 3: Site 4: Our procedure (did/did not) _____________ change. The changes we made to our procedure are: How our site-specific phytoremediation research decisions might impact the global discussion on remediation of industrial waste sites: Sincerely, ______________________________ PRESENTATION REVIEW FORM Your name/reviewer: ___________________________________________________________ Name of presenting team: _______________________________________________________ Rate the team’s presentation for the following: Presentation Components Delivery (speech, mannerisms) 1 Needs improvement Poor volume, eye contact, or pace of speech (too fast/slow) Visuals (graphs, charts, diagrams, powerpoints) Visually unattractive, confusing Persuasiveness (information, argument) Information is not convincing; little or no evidence is presented for arguments The focus of the presentation was mainly on the types of plants; little or no information was presented about the procedure to select the plants Most of the scientific and/or mathematical content was inaccurate Procedure (model solution) Scientific/mathematical information 2 Satisfactory For the most part has overall satisfactory volume, eye contact, and pace of speech Shows some clutter or lack of structure but overall understandable Includes persuasive information; some evidence is presented for arguments The focus of the presentation was partially on the procedure to select the plants with more focus on the plant descriptions Most of the scientific and/or mathematical content was accurate 3 Excellent Excellent volume, eye contact, and pace of speech Your rating Visually pleasing, enhances understanding Main idea is communicated convincingly; clear evidence is presented for arguments The focus of the presentation was on the procedure to select the plants types of plants; information about plant descriptions was also included All scientific and/or mathematical content presented was accurate Total Score Articulate why you provided the rating for “Persuasiveness,” making sure to identify how the evidence was used, any incorrect reasoning, or exaggerated evidence. What are the strengths of this team’s procedure? Do you have any suggestions for improving this team’s procedure?