Systemic Assessment [SA] as a Tool To Assess Student Achievements in Inorganic Chemistry [Part-I]: Sodium Chemistry: Fahmy, A.F.M.*& Lagowski, J.J *Department of Chemistry, Faculty of Science, Ain Shams University, Cairo, Egypt. E-mail: afmfahmy42@gmail.com ; www.satlcentral.com Department of Chemistry, University of Texas at Austin, Austin, Texas USA E-mail: jjl@mail.utexas.edu ABSTRACT: Systemic Assessment aiming to a more effective evaluation of the systemic oriented objectives articulated by SATL model. Systemic Assessment [SA] raising the level of students academic achievements, increasing students learning outcomes, develop the ability to think systemically, assess students higher-order thinking skills in which students are required to analyze, synthesize, and evaluate, measures the students' ability to correlate between concepts. Systemic Assessment Questions [SAQ, s] are the building unites of the systemic assessment. In this issue we use SA as a tool to assess the student achievement in inorganic chemistry by taking sodium chemistry as a module. We use four types of Systemic assessment Questions, namely Systemic Synthesis Questions [SSynQ, s], Systemic Analysis Questions [SAnQ, s], Systemic SyntheticAnalytic Questions [SSyn-A Q, s], and complete Systemics [SComp Qs]. -----------------------------------------------------------------------------------------------------------*Author for correspondence e-mail: afmfahmy42@gmail.com 1 INTRODUCTION: Systemic approach to Teaching and Learning Chemistry (SATLC) is a method of arranging concepts in such a way that the relationships between various concepts and issues are made clear. SATL methods have been shown, empirically, to be successful in helping students learn in a variety of settings-pre-college, college, and graduate systems of formal education as well as adult education—in a variety of disciplines; the sciences (chemistry, biology, physics) (1-4). A number of statistical studies involving student achievement indicate that students involved with SATL methods taught by teachers trained in those methods achieve at a significantly higher level than those taught by standard linear methods of instruction. However, our studies on Systemic Assessment [SA] (5-7) is an ongoing process of identifying the student learning outcomes, assess the student performance to these outcomes. SA showed that is highly effective in raising the level of students academic achievements, develop the ability to think systemically, assess students higher-order thinking skills in which students are required to analyze, synthesize, and evaluate, measures the students' ability to correlate between concepts, enables the students to discover new relation between concepts. It is more effective evaluation of the systemic oriented objectives in the SATL model .Systemic Assessment Questions [SAQ,s]are the building unites of the systemic assessment (7,8). In inorganic chemistry the usual descriptions of inorganic reactions by chemical equations, represents linear separated correlations between reactants, resultants and 2 reaction conditions. The student taught the six general types of chemical reactions, namely, Combustion, single displacement, double displacement, Synthesis, decomposition, and Acid-Base reactions. Although the students know the six types of chemical reactions they find difficulties in representing chemical changes by correct chemical equations, and in correlation between reactants and resultants. The student while being taught through a linear approach is asked to present the chemical changes by correct chemical equations , without any comprehension or appreciating significance of these relationships representing the chemical reactions. This leads to memorization of the chemical equations and finally to surface and rote learning. -Ausubel distinguishes “rote learning” or memorization from meaningful learning (9). The process called “assimilation” creates personal meaningful knowledge by restructuring the already existing conceptual frameworks that the learner possesses to accommodate to the new concepts being learned. Our goal of this issue is to develop systemic assessment [SA] strategies and materials can be used by students to assess their learning of chemical changes of elements .Also it might lead to a better understanding of the systemic relations between elements and their related compounds, between compounds of the same element, and most importantly between types of the chemical changes under consideration. Proposed learning Module: Domain of learning material. As a material for the study, we take Sodium metal, as an example of metals in this issue. Sodium metal is the first member of alkali metals [Group-1.A] of the periodic table .The study includes the extraction of the sodium metal 3 and its chemical properties. Also industrial preparations and chemical properties of some sodium compounds are included. This module is considered as a part of general chemistry for secondary school students and presented by systemic methodology. Table 1. Domain of teaching material Teaching unit Alkali Metals [Sodium] Teaching themes Preparation of Sodium Chemical properties of Sodium Sodium hydroxide [Caustic soda] Chemical properties of Sodium hydroxide Sodium Chloride Sodium carbonate and Bicarbonte Selected contents of defined theme -Extraction from sodium hydroxide by Electrolysis. - Extraction from sodium chloride by Electrolysis -Reactions with oxygen,chlorine,water,acids. -Manufacturing of Caustic soda -Rections with acids, acidic oxides,amphoteric oxides ,halogens, some salts. -Preparations of pure sodium chloride. - Reactions of sodium chloride. -Manufacturing of Sodium carbonte,and bicarbonate -Chemical reactions. CORE IDEA: Linear Assessment vs Systemic Assessment: In the linear (Traditional )Assessment[LA] we ask our students to represent the different types of inorganic reactions by chemical equations. Example from Sodium chemistry: Write equations for the following reactions: 1-Reaction of sodium with water.[Displacement reaction]. 2-Reaction of sodium hydroxide with hydrochloric acid.[Acid-Base reaction]. 3-Electrolysis of molten sodium chloride.[Electrolytic-Decomposition reaction]. Answer: 1- 2Na + 2 HOH 2 NaOH 2- NaOH + dil. HCl 3- NaCl [Molten] NaCl Electrolysis 2Na [Cathode] 4 + H2 + + HOH Cl2 [Anode] The student can write the symbolic chemical equations as above,but,however,he couldn,t correlate between either sodium metal and its related compounds(NaOH,NaCl) or the three chemical processes [Displacement, Acid-Base,and electrolysis] of the above reactions.So, he just write the three separate equations without any comprehension or appreciating significance of these relationships representing the chemical reactions. This leads to a rote learning and consequently assess our students at lower learning level [Memorization]. In the Systemic Assessment [SA]: We can ask our students about the same chemical reactions by using four types of systemic assessment questions [SAQ, S]: Type (I): Systemic Synthesis Questions [SSynQ, s]: In which we ask students to synthesize trigonal systemic represents the chemical relations between [Na- NaOH - NaCl]. In this type of questions we assess our student’s knowledge about relations between (sodium, sodium hydroxide, and sodium chloride) beside the relations between the three chemical processes [Displacement, Acid-Base, and Electrolysis].Assess student learning outcomes at synthesis level. Type (2): Systemic Analysis Questions[SAn Q,s]: In which we give our students the above trigonal systemic and ask them to analyze to the corresponding chemical reactions.Assess student learning outcomes at synthesis level. 1- 2Na + 2 HOH 2 NaOH + H2 2- NaOH + HCl NaCl + HOH 2Na + Cl2 3- NaCl [Molten] 5 Electrolysis Type-3: [SSynQ,s-SAn Q,s] by asking our student to; 1-Synthesize trigonal sytemic shows the chemical relations between [Na-NaOH-NaCl]. 2- Analyze the resulted systemic into the corresponding chemical reactions. Assess student learning outcomes at synthesis followed by analysis level. Type-4: Complete the given ststemics by adding the missing chemicals [ScompQ,s] Assess student learning outcomes at synthesis level. By using SA we expect to convert our students from surface learning to deep learning of chemical processes in sodium chemistry. Design of learning material: Learning sheets were prepared in the form of; (1) A diagram of proposed liable bottles of the given element [Sodium] and some of its related compounds, (2) Systemic diagrams representing different types of systemic assessment questions [SAQs] in which the selected chemicals of any reaction were located in the given systemics. [SAQs] have been designed in accordance with the guidelines sated by: Fahmy & Lagowski (2006, 2008, and 2012) (5-7), and Tzougraki (2011) (8) (3) Then we ask students to choose between sodium and the given compounds to answer the given systemic assessment questions. You have the following bottles of chemicals: 6 Answer the following questions: Type-I: Systemic Synthesis Questions [SSynQ, s] [Synthesize systemics from the given chemicals & assess the student learning outcomes at synthesis level] Type-I-A: Synthesize clockwise or anticlockwise systemic from the given chemicals to give the correct possible chemical relations]: Q1) Use the following triangular diagrams to construct the clockwise Systemic chemical relations between the (forgoing) chemicals. 7 Q2) Use the following quadrilateral diagrams to construct the clockwise Systemic chemical relations between the (forgoing) chemicals. 8 Q3) Use the following pentagonal diagrams to construct the possible clockwise systemic chemical relations between the (forgoing) chemicals. 9 10 Q4) Use the following hexagonal diagram to construct the possible Clockwise chemical relations between the (forgoing) chemicals. A4) 11 Q5) Draw one possible anticlockwise triangular systemic chemical relations between three of (forgoing) chemicals. A5) Type-I-B: Synthesize systemic from the given chemicals to give Maximum possible chemical relations: Q6) Draw the maximum possible chemical relations between some of the (forgoing) chemicals in quadrilateral systemic diagrams. A6-A: Note: There are five possible chemical relations instead of four in the clockwise quadrilateral chemical relations (Q2). 12 A6-B: Note: There are six possible chemical relations instead of four in clockwise quadrilateral chemical relations (Q2). Q7) Draw the maximum possible chemical relations between the (forgoing) chemicals in a pentagonal systemic diagram. A7-A: Note: There are eight possible chemical relations instead of five in the clockwise pentagonal chemical relations (Q3). 13 A7-B: Note: There are eight possible chemical relations instead of five in the clockwise pentagonal chemical relations (Q3). Q8) Draw the maximum possible chemical relations between the (forgoing) chemicals in hexagonal systemic diagrams. A8: Note: There are eleven possible chemical relations instead of five in the clockwise hexagonal chemical relations (Q4). 14 Type-II: Systemic Analysis Questions [SAnQ,s] Assess the student learning outcomes at Analysis level. Type-II-A: [Analyze systemics into another systemic] Q1) Analyze the given systemic diagram from the (forgoing) chemicals to the maximum possible clockwise systemic chemical relations. A1) 1-Clockwise quadrilateral systemic chemical relations. 2-Clockwise triangular chemical relations. 15 Q2) Analyze the given systemic diagram from the (forgoing) chemicals to the maximum possible clockwise systemic chemical relations. A2 1-Clockwise quadrilateral systemic chemical relations. 2-Clockwise triangular systemic chemical relations. 16 Q3) Analyze the given systemic diagram from the (forgoing) chemicals to the maximum possible clockwise systemic chemical relations. 1-Clockwise pentagonal systemic chemical relations. 2-Clockwise quadrilateral systemic c chemical relations. 2-Clockwise triangular systemic chemical relations. 17 Type-II-B: Analyze systemics into The Corresponding Chemical Equations: Analyze the following systemic diagrams illustrating the systemic chemical relations between Sodium and its related compounds into Chemical equations: Q1) A1) 2Na 2NaOH + + Na2CO3 + 2 NaCl 2H2O 2 NaOH+H2 CO2 Na2CO3 + H2O Dil.2HCl 2NaCl +CO2+ H2O [Molten] 2Na + Cl2 Q2: NaCl Electro./ Molten Na Air/heat HCl 18 Na2CO3 Na2O CO2 H2 O NaOH Q3) Type-III: Complete Systemics Questions [SComp Q,s] [Complete the given unfilled or partially filled systemic diagrams & assess the student learning outcomes at synthesis level] Q1) From (forgoing) chemicals complete the following clockwise systemic trigonal chemical relations. 19 A1) Q2) From (forgoing) chemicals complete the following quadrilateral clockwise systemic chemical relations. A2: …… …… electrolysis (molten) …… CO2 …… …… Na H2 O …… …… ……… …… …… NaOH Na CO2 electrolysis (molten) Na2CO3 NaCl …… …… …… …… heat excess (O2) Na2O2 A2) electrolysis (molten) NaCl 20 HCl H2 O HCl NaOH Q3) From (forgoing) chemicals complete the following clockwise Systemic pentagonal chemical relations. A3) 21 Q4) From (forgoing) chemicals complete the following hexagonal chemical relations. A4) 22 Type-IV: Systemic Synthetic- Analytic Questions [SSyn -An Q,s] It is integration between systemic Synthesis and systemic Analysis questions. So, we assess the student achievements learning outcomes at the synthesis & analysis levels. We ask our students to synthesize systemic from the given chemicals then ask them to analyze the resulted systemic to the corresponding chemical reactions. Q1) Use the following triangular systemic diagram to construct the clockwise systemic chemical relations between the (forgoing) chemicals. Then analyze to the corresponding chemical equations A1-1: Synthesis: 23 A1-2: Analysis: To three equations. 2 Na + O2 Na2O2 + HCl 2 NaCl [Molten] heat/excess [O] Na2O2 2NaCl + H2O2 Electrolysis 2Na + Cl2 Q2) Use the following the quadrilateral systemic diagram to construct the clockwise systemic chemical relations between the (forgoing) chemicals. Then analyze to the corresponding chemical equations A2-1:Synthesis:. A2-2:Analysis: To four equations. 1) 2 Na + 2) Na2O2 + 3) NaOH + O2 2 HOH 4) 2NaCl [Molten] 24 heat/excess [O] Na2O2 2 NaOH + 2 H2O2 HCl NaCl Electrolysis 2 Na + HOH + Cl2 Q3)Use the following the pentagonal systemic diagram to construct the clockwise systemic chemical relations between the (forgoing ) chemicals. Then analyze to the corresponding chemical equations . A3-1: Synthesis: A3-2: Analysis: To five equations. 1) 4 Na + O2 2) Na2O + HOH heat/ Air [O] 2 Na2O 2 NaOH 3) 2 NaOH + CO2 Na2CO3 + HOH 4) Na2CO3 + 2 HCl 2 NaCl + CO2 + HOH 5) 2NaCl [Molten] Electrolysis 2 Na + Cl2 [Cathode] [Anode] 25 References: 1-Lagowski, J.J. and Fahmy, A.F.M. (2011);The systemic approach to teaching and learning, [SATL]: A 10- year’s review, AJCE,1(1) 29-47. 2-Fahmy, A.F.M. and Lagowski,J.J.(1999); The uses of systemic approach to teaching and learning in 21st century,Pure PureAppl. Chem., 1999, 71(5) 859 – 863.[15th ICCE, Cairo, Egypt, August, 1998]. 3-Fahmy, A.F.M.andLagowski, J.J. (2003); Systemic Approach to teaching and learning chemistry [SATLC] in Egypt [1998-2011], AJCE,2(2)92-97. 4- Nazir, M. , Naqvi,I.(2012); Designing Of Lectures through Systemic Approach to Teaching and Learning, a Model for (SATL) Methodology, Pak. J. Chem. 2(1):46-57 5-Fahmy, A.F.M.andLagowski, J.J. (2006); Systemic Multiple Choice Questions (SMCQ)in Chemistry.19th International Conference on Chemical Education, (19th ICCE),Seoul, Korea, August 12-17. 6-Fahmy, A.F.M.andLagowski, J.J. (2006/2008); Systemic Multiple Choice Questions in Chemistry, Chemical Education International Vol. 3 (2006/2008)http://www.iupac.org/publications/cei 7-Fahmy, A.F.M., and .Lagowski, J.J. (2012):Systemic assessment as a new tool for assessing students learning in Chemistry using SATL methods: Systemic true false [STFQs] and systemic sequencing [SSQs] question types, AJCE. 2(2)66-78. 8-Vachliotis,T, Salta,K., Vasiliou, P., Tzougraki, C (2011): Exploring novel tools for assessing high School students' meaningful understanding of organic reactions, J. Chem. Educ. 88 [3] , 337-345. 9-Ausubel, D. P.; Novak, J. D.; and Hariesian H.(1968) “Educational Psychology: A Cognitive View” Reinhart and Winston, New York, 26