Study program: Condensed Matter Physics Theme: Investigation of properties of superconductor-semiconductor heterostructures. Supervisor: Prof. RNDr. Alexander Feher, DrSc. Consulant: Mgr. Vladimír Komanický, PhD. Annotation: Superconductor-semiconductor devices have become a topic of intensive research in recent years. They provide excellent systems to study transport phenomena in superconductor -normal conductor structures. Due to the superconducting energy gap, nonlinear effects in the conductance are already present at very low voltages. One of the most interesting phenomena that may occur at the interface between a superconductor and a normal metal is Andreev reflection. Also when the light is shined on the semiconductor with the wavelength corresponding to band gap, carriers in the semiconductor can be excited which can potentially lead to rising of interesting new phenomena in these structures. The topic of this PhD dissertation is preparation of superconductor-semiconductor heterostructures and study of their physical properties. The literature overview will be done first. Then various types of the superconductor-semiconductor heterostructures will be prepared by magnetron sputtering and their electrical transport properties and optical properties will be studied at low temperatures. Literature: 1. Konrad W. Lehnert, Nonequilibrium dynamics in mesoscopic superconductorsemiconductor-superconductor junctions, Dissertation, UC Santa Barbara, 1999. Theme: Nanostructured materials for applied catalysis. Supervisor: Prof. RNDr. Alexander Feher, DrSc. Consulant: Mgr. Vladimír Komanický, PhD. Annotation: Sustainability of energy resources is one of the major hurdles each developed country is facing today. To render production of fuels sustainable, one must either close the carbon cycle that is to use CO2 and water to make "synfuels" through different catalytic processes or to use some alternative cycle. One of the alternatives to the carbon cycle, which is technologically most developed is a hydrogen (water) cycle through photovoltaics, electrolysis (photoelectrocatalysis) and fuel cells. Fuel cells and electrolyzers are energy conversion systems that are currently available for use in the hydrogen cycle. However, they are all plagued by one major problem, i.e. the involvement of precious metal catalysts, which are very expensive and thus represent a large portion of the total price of these systems In order to reduce the amount of precious metal in the relevant energy conversion devices, one has to improve the activity, stability and selectivity of precious metal based catalysts. The topic of this PhD dissertation is preparation of nanostructured catalytic materials using sputtering and nanofabrication methods to prepare novel nanomaterials with higher activity, stability and selectivity. The literature overview will be done first. Prepared catalytic materials will be studied by atomic force microscopy, electron microscopy and their catalytic activity will be determined. Literature: 1. Heiz, Ulrich; Landman, Uzi (Eds.), Nanocatalysis, Springer, 2007. Theme: Experimental study of selected low-dimensional magnets with an energy gap in the excitation spectrum Supervisor: RNDr. Erik Čižmár, PhD. Annotation: Thesis will be devoted to the study of low-dimensional magnets with an energy gap in the excitation spectrum with aim to observe novel quantum phase transitions. Experimental work will include the automation a tuning of the measurement techniques for specific heat and electron spin resonance at low temperature. The theoretical knowledge of the low-dimensional magnets theory and quantum phase transition will be acquired by the student. Student will perform magneto-structural analysis, ESR, magnetic and thermodynamic measurements of selected low-dimensional magnets. The results will be published at international conferences and published in CC journals. Literature: 1. Schollwöck, U.; Richter, J.; Farnell, D.J.J.; Bishop, R.F. (Editors), Quantum Magnetism, Springer, World Scientific, London, 2004. 2. Parkinson, J.B., Farnell, D.J.J., An Introduction to Quantum Spin Systems, Springer, 2010. Theme: Heusler alloys prepared by rapid quenching method Supervisor: doc. RNDr. Rastislav Varga, PhD. Consultant: doc. RNDr. Zuzana Vargová, PhD. Annotation: The aim of the thesis is to study the preparation of Heusler alloys by rapid quenching method in the shape of bulk or ribbon. Consequently, magnetic, structural and electrical characterization of such alloys will be performed. Literature: 1. T. Krenke, E. Duman, M. Acet, E. F. Wassermann, X. Moya, L. Mañosa, A. Planes, Nat. Mater. 4 (2005) 450. 2. B. Hernando, J.L. Sánchez Llamazares, J.D. Santos, Ll. Escoda, J.J. Suñol, R. Varga, D. Baldomir, D. Serantes, Appl. Phys. Lett. 92 (2008) 042504. Theme: The influence of thermal treatment on structural and magnetic properties of rapidly quenched soft magnetic materials. Supervisor: doc. RNDr. Rastislav Varga, PhD. Consultant: prof. RNDr. Pavol Vojtanik, DrSc. Annotation: The aim of the thesis is to study the influence of thermally induced anisotropy (under mechanical stress, magnetic field, etc…) on magnetic properties of rapidly quenched soft magnetic materials in the shape of ribbon and glass-coated microwires. Literature: 1. K. Richter, R. Varga, G. A. Badini-Confalonieri and M. Vázquez, Appl. Phys. Lett. 96 (2010) 182507. 2. J. Olivera, R. Varga, V. M. Prida, M. L. Sanchez, B. Hernando, and A. Zhukov Phys. Rev. B 82 (2010) 094414. Theme: Study of structure and physical properties of amorphous and nanocrystalline alloys. Supervisor: Prof. RNDr. Pavol Sovák, CSc. Annotation: Main purpose of the project is to handle technology of production amorphous and nanocrystalline alloys by rapid quenching. Due to chemical composition or annealing treatment to optimize physical properties of produced alloys. For structural characterization to use mainly electron microscopy techniques. Literature: 1. P. Sovák, A Zorkovská, Structure and magnetic properties of Finemet basd alloys, P.J. Šafárik University in Košice, 2008, ISBN:978-80-7097-719-4. 2. Carl C. Koch, Nanostructured materials, WA Publishing, 2007, ISBN: 0-81551534-0. 3. M.A White, Physical properties of materials, CRC Press 2012, ISBN: 978-1-43986651-1. Theme: Magnetism and magnetostructural correlations in genuine organic and organometalic TCNQ-based materials. Supervisor: RNDr. Marcela Kajňaková, PhD. Consulant: RNDr. Erik Čižmár, PhD. Anotation: The Ph.D work is aimed at the magnetism and magnetostructural correlations of new genuine organic and organo-metalic materials based on the anionradical TCNQ (7, 7, 8, 8 – tetrakyanochinodimethane), i.e. materials with a chargetransfer. The literature information overview about this theme is assumed at the first. The experimental study of the thermodynamic, magnetic and transport properties will be done. The experimental data will be analyzed by theoretical models and by the study of crystal structure. The main goal of the work is to define magnetic properties and the magnetic system of studied material. Literature: K. Ariga, T. Kunitake: Supramolecular chemistry - Fundamentals and Applications. Springer, Berlin 2006. J. Fraxedas: Molecular Organics Materials: From Molecules to Crystalline Solids. Cambridge University Press 2006.