Supporting Information Highly Enhanced UV Photosensitivity and Recovery Speed in Electrospun Ni-doped SnO2 Nanobelts Siya Huang,1 Kohei Matsubara,1,2 Jing Cheng,1 Heping Li,1 and Wei Pan1,a) 1 State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, People’s Republic of China 2 Department of Physical Electronics, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan a) Author to whom correspondence should be addressed. Electronic mail: panw@tsinghua.edu.cn. Figure S1. Time-dependent photoresponse of pristine SnO2 measured at a bias voltage of 1.0 −𝑡 V, where τd is estimated to be 13 s according to the exponential law: 𝐼 = 𝐼0 e ⁄𝜏𝑑 . 1 Figure S2. SEM images of Ni-doped SnO2 samples with different Ni-doping concentrations: (a) 0 at. %, (b) 3.0 at. %, (c) 5.0 at. %, (d) 7.0 at. %, (e) 10.0 at. %, and (f) 15.0 at. %. Table S1. SnO2-based photodetectors.* Nanostructures Devices Light of detection Dark current Or resistance Photocurrent Or resistance Sensitivity Response time Ref NW FET 254 nm 0.66 nS 760 nS 103 ( Vg:-10 V) <0.1 s [1] NW Resistor 325 nm ~ 2 µA NW NB NW Resistor Resistor Resistor 370 nm 254 nm 325 nm ~ 37.5 kΩ 0.4 nA 30 nA NW ZnO-functional NW NW NW NN NB Ni-doped NB ~ 14 µA (air) ~ 12.5 kΩ 80 µA (air) 210 nA (air) ~3 105 (air) 7 235 nA 1.18 300 nA 1.50 1.69 107-104 (Vg:-40-0 V) 4.1 102 Resistor 365 nm 200 nA Resistor 365 nm 77 µA 130 µA FET 254 nm 0.12 µA ( Vg = 0 V) 83.9 µA ( Vg = 0 V) ~ 7 (air) 100300 s (air) — — — 320 nm 89.9 µA 40 nA 375.2 µA 4.0 µA 2 [3] [4] [5] — [6] — [7] Tens of seconds [8] — 13 s 0.5-5 s Resistor 254 nm 0.5 nA 0.65 µA 103 (15.0-3.0 (3.0 at.%) (3.0 at.%) at.%) *NW-nanowire; NB-nanobelt; NN-nanonet; FET-field effect transistor Resistor [2] [9] Present work References 1 Z. Q. Liu, D. H. Zhang, S. Han, C. Li, T. Tang, W. Jin, X. L. Liu, B. Lei, and C. W. Zhou, Adv. Mater. 15, 1754 (2003). 2 J. S. Lee, S. K. Sim, B. Min, K. Cho, S. W. Kim, and S. Kim, J. Cryst. Growth 267, 145 (2004). 3 S. Mathur, S. Barth, H. Shen, J. C. Pyun, and U. Werner, Small 1, 713 (2005). 4 Y. J. Chen, C. L. Zhu, M. S. Cao, and T. H. Wang, Nanotechnology 18 (2007). 5 C. H. Lin, R. S. Chen, T. T. Chen, H. Y. Chen, Y. F. Chen, K. H. Chen, and L. C. Chen, Appl. Phys. Lett. 93 (2008). 6 Q. Kuang, C. S. Lao, Z. Li, Y. Z. Liu, Z. X. Xie, L. S. Zheng, and Z. L. Wang, Journal of Physical Chemistry C 112, 11539 (2008). 7 J. M. Wu, and C. H. Kuo, Thin Solid Films 517, 3870 (2009). 8 D. Kim, Y. K. Kim, S. C. Park, J. S. Ha, J. Huh, J. Na, and G. T. Kim, Appl. Phys. Lett. 95 (2009). 9 H. Chen, L. F. Hu, X. S. Fang, and L. M. Wu, Adv. Funct. Mater. 22, 1229 (2012). 3