https://www.youtube.com/watch?v=VgVQKCcfwnU 8.1 Compounds and Chemical Bonds Compounds: a substance whose smallest particles include more than one element chemically bonded together. Example: H2O is a compound of hydrogen and oxygen atoms bonded together. Mixture: a substance that includes more than one type of element and/or compound NOT bonded together. Most matter is in the form of compounds. Our atmosphere is a mixture of nitrogen and oxygen molecules. Nitrous Oxide (N2O) is a compound because oxygen and nitrogen atoms are bonded together into one molecule. Virtually everything you eat is a compound: Salt is a compound of sodium and chlorine: NaCl Sugar is a compound of carbon, hydrogen, and oxygen. Glucose: C6H12O6 Body turns carbohydrates into glucose, the preferred energy sugar of the body. Stored in muscles and liver until needed. Fructose: C6H12O6 Found in fruits and sugar cane; body turns excess in to fat Most matter is in the form of blends of compounds. All sugars taste sweet, but fructose tastes much sweeter than glucose. There are thousands of different compounds in a single sample of animal or vegetable tissue. p. 159 Molecules and covalent bonds Chemical bond: a bond formed between atoms through sharing or transferring of electrons Almost all elements form chemical bonds easily. Covalent bond: a type of chemical bond formed by shared electrons Example: There are two covalent bonds in a water molecule, between the oxygen and each of the hydrogen atoms. Each bond represents one electron. The electrons are SHARED not TRANSFERRED. 4 Examples of molecules held together by covalent bonds: Double bond: (2 electrons) Triple bond: Ammonia (NH3): Methane (CH4): (3 electrons) Molecule: a group of atoms held together by covalent bonds in a specific ratio and shape P160: Chemical formulas and diagrams Chemical formula: identifies the number and element of each type of atom in a compound For example: Fe2O3 is for a compound with iron (Fe) and oxygen (O) in a ratio of 2 iron atoms for every 3 oxygen atoms. H2O: The subscript 2 indicates that there are 2 hydrogen atoms in the molecule. No subscript means there is one molecule. The formula also tells you that water always contains twice as many hydrogen atoms as oxygen atoms. The shape of a molecule is also important to its function and properties, so they are represented by structural diagrams which show the shape and arrangement. Methane: 3D: Of course, real molecules are threedimensional, not flat as shown in the structural diagram. Methane is really a 4-sided pyramid called a tetrahedron. P161 Structure and Function Properties come from the molecule: properties of a compound depend MUCH more on the exact composition and shape than on the elements of which it is made. Aspirin (acetylsalicylic acid) is made from carbon, hydrogen, and oxygen (H8C9O4) which reduces pain and fever in humans. By themselves, H, C, and O do NOT reduce pain and fever. Polyethylene plastic wrap and formaldehyde (a toxic preservative) are also made from carbon, oxygen, and hydrogen. If the ratio of elements change, the resulting molecule would NOT be aspirin. Aspirin (C9H8O4) Acetyl Benzoyl Peroxide (C9H8O4) Benzodioxole-5 carboxylic acid methyl ester (C9H8O4) P162 Ionic Compounds Ion: an atom that has an electric charge different from zero. Ions are created when atoms gain or lose electrons. Ionic Bond: a bond that transfers an electron from one atom to another resulting in attraction between oppositely charged ions. Not all compounds are made of molecules. Sodium Chloride (NaCl) is a compound of Na and Cl in a ratio of one sodium per chlorine atom. In Sodium Chloride, the electron is transferred from the sodium atom to the chlorine atom. When atoms gain or lose an electron, they become ions. An ion is a charged atom. By losing an electron, sodium becomes a sodium ion with a charge of +1. Chlorine gains an electron, and becomes a chloride ion with a charge of -1 (when chlorine becomes an ion, the name changes to chloride) Ionic bond: Sodium and chlorine form an ionic bond because the positive sodium ion is attracted to the negative chloride ion. Ionic bonds are bonds in which electrons are transferred from one atom to another. Ionic compounds do NOT form molecules. The atoms bond through attraction between positive and negative charge. Ionic compounds also have ratios of elements – like one sodium per chloride ion in sodium chloride. Sodium involves the transfer of ONE electron; however, ionic compounds may also be formed by transferring two or more electrons. Example: magnesium chloride (MgCl2). The magnesium gives up two electrons to become a magnesium ion with a charge of +2. (Mg²+). Each chlorine atom gains one electron to become a chloride ion with a charge of -1 (Cl-). The ion charge is written as a superscript. P163 Why Chemical Bonds form Atoms form bonds to reach a lower energy state. Energy is released when chemical bonds form because chemically bonded atoms have less total energy than free atoms. All elements except noble gases form chemical bonds. However, some elements are more reactive than others. “Reactive” means an element readily forms chemical bonds with other elements. Example: Sodium is a highly reactive metal. Chlorine is a highly reactive gas. If pure sodium and pure chlorine are placed together, a violent explosion occurs as the sodium and chlorine combine and form ionic bonds. The explosion is the energy given off by the formation of the chemical bonds. Grease fire in kitchen: https://www.youtube.com/watch?v=T77rYn-yAe0 sodium/chloride: https://www.youtube.com/watch?v=oZdQJi-UwYs https://www.youtube.com/watch?v=ji_25I_q4LQ The closer an element is to a noble gas, the more reactive it is. The alkali metals are very reactive because they are just one electron away from the noble gases. The halogens are also very reactive because they are also one element away from the noble gases. The beryllium group and the oxygen group are less reactive because each element in these groups is two electrons away from a noble gas.