BAHRA UNIVERSITY, WAKNAGHAT, SOLAN, HIMACHAL PRADESH Ist YEAR, Ist SEMESTER CHEM-107T CHEMISTRY-I THEORY L T P C 3 1 - 3 Course Objective: This course deals with the basic concepts of engineering chemistry which are essential for engineering students of all branches. At the end of this course, a student will be familiar with the basic principles involved in treatment of water, corrosion and its control, lubricants and cementing materials. In Addition, the students will also learn the concept of chemical bonding, analytical chemistry and chemistry of compounds resulting from environmental pollution. Unit-1 Water and its treatment Introduction, hardness of water, units of hardness, disadvantages of hard water, problems associated with boiler feed water: scale and sludge formation and its prevention, caustic embrittlement, softening of water (lime-soda process, Zeolite process, ion exchange process), desalination of water (electro dialysis, reverse osmosis). Unit -2 Chemical bonding Chemical bonding, ionic bond, covalent bond, coordinate bond, vanderwaals forces, hydrogen bond, valence bond theory and molecular orbital theory, energy level diagrams for some homo nuclear diatomic molecules. Unit -3 Corrosion and its control General introduction, types of corrosion, dry or chemical corrosion, wet or electrochemical corrosion, corrosion by gases, mechanism of corrosion, factors influencing corrosion, protection against corrosion. Unit -4 Inorganic Cementing material Gypsum, Plaster of Paris, cement, manufacture of Portland cement, chemical composition of cement, mechanism of hardening of cement, function of gypsum in cement Unit -5 Lubricants Introduction, functions of lubricants, mechanism of lubrication (thick film, thin film, extreme pressure lubrication), liquid lubricants, solid lubricants, semisolid lubricants, synthetic lubricants, properties of lubricants (viscosity , flash and fire point, cloud and pour point, aniline point). Unit -6 Analytical methods and applications Titrimetric analysis with reference to acid base, redox precipitation and complexometric titrations, gravimetric analysis. Unit -7 Chemistry in environment Pollution, Earths radiation balance, Air pollutants, Acid rain: its cause and effect, Greenhouse effect, ozone depletion (causes and effects of ozone depletion ), Photochemical smog , water pollution (sources and control methods) sewage, Biological and Chemical oxygen demand, soil pollution, Radioactive pollution. Books recommended: Text Books: Engineering Chemistry by P.C. Jain and Monica Jain, Dhanpat Rai Publishing Co. Ltd. New Delhi. Reference books: 1.Engineering Chemistry by Shashi Chawla, Dhanpat Rai Publications Co. Ltd. New Delhi. 2. Engineering Chemistry by S.S. Dara, S. Chand and Co. Ltd. New Delhi. 3. Environmental Chemistry by A.K. De, New Age International. 4. Engineering Chemistry by B Sivasankar, Tata McGraw Hill Publishing Co. Ltd. CHEM 107P- CHEMISTRY-I PRACTICAL L T P C As per BU Chemistry Lab Manual - - 2 1 BAHRA UNIVERSITY, WAKNAGHAT, SOLAN, HIMACHAL PRADESH Ist YEAR, IInd SEMESTER CHEM-108T CHEMISTRY-II THEORY L T P C 3 1 - 3 Course Objective: This course is designed to introduce the students with the basic concepts of chemistry. At the end of this course, a student will be familiar with the basic principles involved in general organic chemistry, polymerization, surface chemistry and catalysis. In Addition, the students will also learn practical importance & applications of phase rule and different spectroscopic techniques in different areas. Unit- 1 General concepts in organic chemistry Introduction, bond fission, classification of reactions, types of attacking reagents, inductive effect, electrometric effect, resonance effect, hyper conjugation, mechanism of nucleophilic substitution reactions ( SN1 and SN2), mechanism of elimination reactions (E1 and E2). Unit- 2 Polymers Introduction, types of polymerization (addition, condensation and copolymerization), free radical mechanism of addition polymerization (ethane), thermo plastic resins (PVC, Polystyrene, PAN, Nylon 6, Nylon 66), thermo setting resins (Bakelite, polyesters) and their uses, Engineering plastics. Unit- 3 Phase Rule Introduction of phase rule, explanation of the terms: phase, component, degree of freedom, one component system (water system), Phase rule for two components system, eutectic system, simple eutectic system ( Lead – Silver system). Unit- 4 Surface Chemistry General introduction about absorption and adsorption, classification of adsorption, applications of adsorption, Langmuir’s theory of adsorption, colloidal state, types of colloidal state, preparation of colloidal solutions (by chemical methods and dispersion methods), characteristics of colloidal solutions (mechanical and optical properties), emulsions, gels, micelles, applications of colloids. Unit- 5 Fuels and Non-conventional energy sources Classification of fuels, calorific value of fuel, determination of calorific value by using Bomb Calorimeter, coal, analysis of coal, non-conventional sources of energy, solar energy, solar cell, biomass. Unit- 6 Spectroscopic Techniques General introduction, electromagnetic spectrum, emission and absorption spectrum, representation of absorption spectrum, IR spectroscopy (principle and theory), Infra-red spectrum of polyatomic molecules, examples of IR spectra (ethanol, benzaldehyde, acetic acid, diethyl amine). NMR-spectroscopy- principle, shielding and deshielding of protons, chemical shift, how to interpret NMR spectrum, NMR-spectrum of methanol and ethanol, applications of NMR-spectroscopy. Unit- 7 Catalysis Introduction of catalysis, characteristics of catalysts, types of catalysis (Homogeneous and Heterogeneous Catalysis), mechanism of catalytic action (unstable intermediate compound formation theory and adsorption theory), Introduction of enzymes or biological catalysts, mechanism of enzyme action, brief idea about acid-base catalysis. Text Book: Engineering Chemistry by P.C. Jain and Monica Jain, Dhanpat Rai Publishing Co. Ltd. New Delhi. Reference Books: 1. Engineering Chemistry by Shashi Chawla, Dhanpat Rai Publications Co. Ltd New Delhi. 2. Engineering Chemistry by S.S. Dara, S. Chand and Co. Ltd. New Delhi. 3. Engineering Chemistry by B Sivasankar, Tata McGraw Hill Publishing Co. Ltd. CHEM 107P- CHEMISTRY-II PRACTICAL L T P C As per BU Chemistry Lab Manual - - 2 1