CORE CONCEPTS OF PROPERTIES OF GASES Core Concepts 1 1) What do you intend the students to learn about this topic? 2) Why is it important for students to know this? Core Concepts 2 Core Concepts 3 Core Concepts 4 Core Concepts 5 Core Concepts 6 Core Concepts 7 Core Concepts 8 Core Concepts 9 Core Concepts 10 Gases are composed of particles that move randomly and collide with each other. Gases have weight. There are more spaces between particles of gases compared to solid and liquid form of matter. Gases diffuse to fill their container. Gases can mix in any portion homogeneously. Gases are compressible. Under constant Pressure and Number of particles(mole) the Volume is directly proportional to the Temperature. Under constant pressure and temperature the volume is directly proportional to no of particles. Under constant volume the kinetic energy of particles is directly proportional to temperature. An ideal gas is a theoretical gas and differs from real gases. The laws of gases apply to ideal gases more than real gases. In order to visualize movement of gas particles (in a container) in a proper way. To understand pressure and kinetic theory of gases. They should not think of gases as composed of static particles. They can travel and mix. Later weight will be built on the particulate nature of gases. In daily lives, they should be aware of the fact that gases like all matters are composed of particles and so they weigh. Pressure is due to the weight of these particles. In order to understand differences between solid, liquid and gases form in microscopic level, to figure out why gases mix easily, why they are compressible and they have greater kinetic energy to go far apart. They may be able to compare the strength of interactions between particles comparing to solid and liquid forms of matter. The need to understand why gases show the same characteristics allover the container. How gases behave when there is density difference in a container or when a parfüme is sprayed from a corner of the room. For example, why air has the same percentages (almost) of its components in every field. To make calculations regarding gas mixtures, they should consider homogeneous mixing. In order to differentiate gases from solid and liquid form of matter. Making connections to everyday life such that how so much gas can be filled in a small container like bottle, how some pistons work in relation to pressure, why a bottle of cola makes some noise when you open the cap etc. To understand the idea of gas expansion. Making connections to everyday life such that why a ball gets smaller in cold days and visa versa. The piston mechanism should be understood basically. Students need to understand what the constant pressure, constant no of particles and how these variables fixed. How related experiments should be done etc. How the related gas law is used and what the results mean. To relate number of particles to volume of a gas under constant pressure and temperature. How balloons get bigger when you blow in it. In a closed container the behavior of gas molecules should be examined. They need to figure out what happens if someone heats up a closed container and relate to pressure phenomenon. In daily life they can find many examples to this situation such that every spray has warning about being careful about the temperature, even if the bottle is empty, so they can explain why it is dangerous. They should not expect real gases to obey the gas laws. Why ideal gases are mentioned always in gas law equations. Real gases have differences comparing to ideal gases but ideal gases give some well approximated idea about gases’ behavior and in experiments with real gases would need corrections. They should understand under which conditions a real gas resembles most to an ideal gas in order to make mental connections to each other. 3) What else do you know about this topic (that you do not intend students to know yet)? 4) What are the difficulties/limitatio ns associated with teaching this topic? There are complex calculations to measure the average velocity of particles’ collisions. Not all particles have the same energy, how they collide, and their interaction. Each gas molecule has a molecular weight but we do not explain them in detail in this topic. Under typical conditions,the average distance between gas particles is about ten times their diameter. We do not explain phase transitions in microscopic level and how much the distance effects the interaction between particles. We do not explain diffusion rate calculations. In gas mixtures if there are big differences between molecular weight of the components there may occur gas phases such that the gas which has bigger molecular weight may accumulate in lower parts of the container. We can not mention about the thermodynamic properties of ideal gases which include the compressibility factor. We do not explain the definition of absolute zero Charles Law.We also do not mention the Boltzman constant. Approximations for real gases. In experiments it would not be yielded like it is expected. We do not need to explain avagadros number in calculations of number of particles.Appro ximations for real gases. It may differ in reality and in theory. Even they are weak, attractions still occur among the particles. There may be differences related to piston mechanism, such that fixing temperature and pressure, frictionless piston are the ones which difficult to have. The evarage kinetic energy and momentum of molecules calculations will not be included. We do not explain Van der Waals forces and also London forces between isomers.Critical pressure and phase diagrams can not be mentioned. Because the representation of the nature of matter is difficult and it leads visualization problems. Most of the gases are colorless so their weights can be ignored because atoms and molecules are invisible to eye. The concept of space is difficult to explain and it is confused with air. Because of the nature of gases most of them are colorless so it is difficult to explain that invisible gases move and diffuse. If students’ conceptual understanding of ‘space’ is not sufficient it is difficult to explain the mixing process. Because of the nature of gases most of them are colorless so it is difficult to explain that gases are compressible. Approximations made in order to express the equations well may lead some limitations through experiments. Same difficulties with core concept 7 still hold. Also fixing some variables may be a problem for the experiments. And it is not possible to have frictionless, weightless piston to conduct related experiments. Same difficulties with core concept 7 still hold. Also expressing kinetic energy in terms of heat, pressure and speed may be a source of confusion. Ideal gas particles having no volume because of particle size may not seem relevant.So it leads some limitations about this topic. 5) What do you know about students’ thinking which might influence your teaching of this idea? They do not see gas particles and thinking about something that they cannot observe in daily life (or they are not aware) may seem irrelevant. They may think for some triggering factors refusing their internal energy in order to explain motion of particles (giving initial pulse, wind etc.) They may think gas particles as weightless because especially air is given as an example of gases and they do not feel the weight or mass of the air. If they do not know the arrangements of of particles in liquids and solids,students can not image. They may think the space as if there is air between particles They may be confused with the idea of ‘nothing’ and ‘air’ because we call a bottle of air as ‘empty’. Students may confuse about the concept of homogeneity. When big volumes mentioned as the container student may think the gas particles to be disappeared such that when you spray some odor from one corner of the room because the number of particles is very small students at first could smell the odor but after a while the odor would not be effective and they think of disappearing after some time rather than diffusing into the room. They may have difficulty with having the idea that if a container is filled with a substance how another substance can be put in. They may think compression as squeezing particles such that making molecules smaller may be an idea of compression. They may confuse when they think of macroscopic and microscopic scales such that they may consider a sponge to be compressible. The space concept may still be confusing because when they think the space is full of air they can think the air is compressed not the gas inside or the space between gas particles gets smaller. They may not easily get used to the Kelvin scale to express temperature. The relation between temperature and heat concepts, it may be difficult to separate from each other. When it is said to double the temperature they may insist on thinking just Celsius scale and use in the law equation. Just dealing with equations may not make sense in terms of what they mean in real. When they add some gas into the container they may expect the pressure to increase because what they put should force them to squeeze. In real, most of the time we have closed container examples or the ones which in somewhere it has limits to expand. So the student may not be used to these ideas including idealized cases (piston, interactions etc.). They may think about just the temperature raising not the kinetic energy. Speed and heat may not seem related at first. In a closed container, relation between pressure, heat, speed of molecules and kinetic energy may confuse students in a way that they may have difficulties in making double connections (relation between heat and pressure, relation between speed and pressure etc.). They cannot observe the kinetic energy in daily examples and it may seem abstract to them. Heat loses may attract their attention and they cannot hold the idea of isolated system. They may have difficulties for visualization of ideal gases (having no size particles) and real gases separately. It may seem meaningless to study with real gases if we do not observe them in real life. They may refuse using real gases in ideal gas format while making calculations with gas laws. If they know what they do has mistakes in it they may detach from the topic. 6) What are some of the other factors that you need to consider that might influence your teaching of this topic? If students do not know the relationship between temperature and kinetic energy it will be difficult to explain how it effects the movement of particles and collision of particles.So we should consider whether students have clear knowledge about these concepts or not. We should explain conservation of mass in phase changes superficially. They may not know this concept before this concept. It is difficult to fixed the students’ misconceptions about the space concept and the arrengements of the particles for teachers. They may not know the term ‘diffusion’ and how it occurs. We should not ignore that the ‘homogenity’co ncept may not be understood by students due to the inability of keeping trackof particles. (also in macro level). They may not be familiar with the idea of piston mechanism, how to fix a variable. In that case constant pressure idea is difficult to visualize. And doubling temperature is sometimes confusing because of Kelvin-Celcius scale usage. In that case, they may not be familiar with the piston mechanism and while waiting for a system to reach an equilibrium (also in simulations) they may think of pressure to change. Because the kinetic energy is not observable in daily life examples, students may refuse to accept this idea even they see in simulations. I should be sure that they are aware of kinetic theory assumptions such as the size of molecules can be ignored when contrasted to the large distances between molecules, the interactions between gas molecules can be ignored and at the same temperature the average kinetic energy of different gases are equivalent. They may think that real gases are always very different from ideal gases but I should mention that at standard temperature and pressure, most real gases behave qualitatively like an ideal gas. 7) What kind of methods or strategies you may use to teach this topic? Explain the reasons for using these methods or strategies. Asking some questions about daily life examples to think more internalized way the groups which we combined before like “how can we hear voices how can it be possible.” ,”how can they smell something pleasant or not so nice then particles are getting up your nose. “ And enable them to discuss their ideas about the concept. We can ask some questions to the groups which we combined before like “where does the weight of tree come from” or “what happens in condensation ,where does liquid comes from and how can it be weightable after condensation.”We may ensure group discussion to share their ideas with their friends and it makes them to think more different point of views.After a group discussion we may ensure another discussion between groups to think more deeply. We may want the students to draw or tell how the space between particles of solid, liquid and gas form of matter differ from each other. If they have misconceptions about the spaces between particles Ballons and Buoyancy simulations explaining solid, liquid and gas phase differences may be demonstrated. And the idea of ‘flying’ particles may be used to explain how much spaces can form between the particles and they are still in gaseous phase. Some discussion should be conducted in order them convince about the spaces that are not air particles. I will start with leading them to critical thinking by focusing on previous core concepts 3&4 and apply them to the structure of ‘air’. I will want them to say what they know about the air and write them on the chalkboard. Then I will mention again that ‘ Because most of the volume occupied by a gas consists of empty space and there is nothing to prevent two or more kinds of gases from occupying the same volume’. Then I will remind Avogadro’s Law and explain that ‘equal volumes contain equal numbers of molecules, so when we say that air is 21 percent oxygen and 78 percent nitrogen by volume, this is the same as saying that these same percentages of the molecules in air consist of O2 and N2. Similarly, in 1.0 mole of air, there is 0.21 mol of O2 and 0.78 mol of N2. Then I will ask them to explain how we smell parfume odor and let them to discuss. I will apply an activity which is spraying on parfume to the classroom from the door. I will say them to wait for five minutes and then walk around the classroom. I will ask them if they observe the ‘mixing homogenously’ phenomenon. Also I will use the simulation that I got from http://phet.colorado.edu/si mulations/sims.php?sim= Gas_Properties to help them visualize the process. Fistly we may accomodate them to re-think that there are spaces between particles of gases.And we can show the Ballons and Buoyancy simoulation to help them to visualize that gases are compressible. Asking questions should be the first step of this concept teaching. These questions may be ‘What happens when we heat a gas?’, ‘What may effect behavior of gases?’, ‘What should be the conditions to see only the relationship between volume and temperature?’. With such questions, group discussions should be promoted and their ideas should be shared and expressed. With using simulation they should control the variables and discuss what will happen before playing simulation. After playing it, their questions may arise and these questions should be answered in a way that students’ confusion around this concept should disperse. What resembles to this conditions in daily lives may be asked and it is another way to make the theory of temperature-volume relation permanent. Relating with previous core concept, students should be asked this time to think of making pressure and temperature constant, and changing volume with respect to number of particles. The question to make them critically think, may be ‘why a balloon expands and gets bigger when you blow in it?’. According to their response, group discussions should be promoted in a way that they must realize their way of thinking is true or not. Then the simulation Balloons and Buoyancy may be used to make clear their ideas. Relating with core concepts 7-8, this time students should be asked to discuss about how temperature effects the speed of the particles of gases. They actually familiar with the Constant volume issue but they may not be aware of it. By group discussions their ideas should be cleared and then by the simulation Balloons and Buoyancy they can observe the changes. In addition their attention should be drawn to the pressure at the same time, because heating a closed container leads pressure increase beside the kinetic energy. Constant pressure case should be compared to constant volume case, differences and reasons should be discussed through the lesson. I will start with asking them what ‘real gas’ and ’ideal gas’ concepts mean to them. I slice the chalkboard into two parts and write their answers to identify the two terms. Then I will remind them about the kinetic theory assumptions and apply them wile defining ideal gas behaviours. I will explain them the terms ‘non-interacting point particles’ and ‘random motion’. Give examples such as comparing He-Kr, CH4-C3H8, H2- N2 while explaining how gases tend to be ideality. I will mention that in real life in experiments we use real gases but in laws and calculations we assume gases as ideal. I will show them the simulation of ‘ideal gas’ that I got from http://www.phy.ntnu.ed u.tw. in order to see ideal gases at microscopic level. I want them to change the variables and see the outcomes in their own computers. I will guide them about changing variables and discuss at each process. 8) What are the specific ways of ascertaining students’ understanding or confusion around this topic (include likely range of responses). We can use the Ballons and Buoyancy simulation to make meaningful understanding of the concept.Also we can spray a parfume to the media and it enables to student to smell it. After that we can apply a post test to make a decision that students really get rid of their misconceptions. We will make an experiment in this concept.Our materials are a pair of scale and a coke.We divided experiment into two parts.In the first part we want from student to weight the coke and then we want from the student to think the weight of coke after s/he opens it.In the second part,one week later we want from student to weight opened coke again.Than s/he can see the weight difference which derives from weight of CO2 after two weighing. We may use a simple experiment which needs only three injectors which contain three phases of same matter.First one is full of a solid one second one is full of liquid one the last one is full of gase one. We want from the students to try squeeze all the injectors when they are closing the hole of injector.Then they can see that to squeeze first one is the hardest one ,the second one is more easier than the first one ,in the last one which contains gase phase is the easiest one to squeeze they can get that there are more spaces between in gase phases . During lecture we will draw them to think deeply about the space concept of gases, homogenity concept and the mixing process by asking them questions such as ‘Can you explain the arrangement of gas molecules at molecular level?’ ‘What is there between gas molecules?’ ‘How does parfume odor spread in a room (by concerning air molecules)?’ They may have general difficulties in understanding the space concept and visualizing the molecular dimension. After discussions, explanations, activity and simulation I want them to write what they have learned about the issue with their own words on a piece of paper in order to learn their way of thinking. If there are still misconceptions or lack of knowledge I will inform them again. I will give them homework about writing three daily-life exa.mples of homogenous gas mixtures on their notebooks We may use a simple experiment which needs only an injector.We want from the students to squeeze the injector when they are closing the hole of injector.Then they can see that it can be squeezable. Before the lesson a quiz may be given asking about comparing temperature and volume, or what happens to a filled balloon a day later on a cold day and why?. Looking to their answers, if there is problem with the idea of constant pressure, constant number of particles or temparature-volume relations, these should be predetermined. And through the lesson, students’ attention should be drawn according to their responses. Group discussions are also conducted in a way that their ideas are shared and if there is a contradict students try to express their ideas to convince others mostly. Here s/he can have problems with explaining all the cases according to her/his theory and s/he may be suspicious about own theory if there is another which explains more cases logically. The students who are still refusing to accept the ‘right theories’ should be determined and with simulation and other materials, their attention should be drawn to their theories which cannot explain in a logical way. After the lesson a post test may be given to the students and a homework may be given to the students who are still confused about the concept and their additional works must be controlled and feedback should be given. The strategy is the same with the core concept 7. Additionally the relating quiz question may be ‘What happens when you blow a balloon and why this is so?’ The strategy is the same with the core concepts 7 and 8. Also, in the quiz to relate constant volume issue to previous concepts, the question may be ‘what happens if to blow a plastic freezer bag for example and what is the the difference to that of balloon and why?’, ‘What happens to the gas particles when you heat a closed container, what you expect in terms of kinetic energy and pressure of the gas?’. And post test should include all of the 7., 8. and 9. concepts and the similarities, differences should be asked. Some cases should be given where the students are wanted to select the right answer which explains the given case in a proper way etc. At each stage of giving a new information I want them to explore their ideas such as why do we need to use ideal gas assumption, why we cannot use real gases in rules and calculations, if we ignore interactions or molecular sizes how does it affect other variables etc. At the end of the lecture I want them to write categorize again the properties of real gases and ideal gases. I will ask them why we need to use ideal gas concepts with their explanations. I will use generally the inqury-based method verbally in order to understand how they think.