Performance Chemical Company Product: Pro-Flow-503 Current Issue Date: December 29, 2013 Pro-Flow 503 From: GHS Page 1 of 6 Safety Data Sheet 24 Hour Emergency Telephone CHEM-TEL, INC. 1-800-255-3924 Performance Chemical Company 9105 W Interstate 20 Midland, TX 79706 Phone: (432) 332-3059 Fax: (432) 332-3097 All non-emergency questions should be directed to (432) 332-3059 for assistance. NOTE: CHEM-TEL emergency number to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure, or accident involving chemicals. 1. Product Identification Trade Name Pro-Flow 503 Clay Stabilizer CAS Number: Mixture – See Section 2 Product Family: Complex Mixture Synonyms: N/AP 2. Hazards Identification Hazard Classification: Flammable Liquid-Category 4 Skin Irritation-Category 3 Eye Irritation-Category 2B WARNING Hazard Statement: Combustible liquid. Moderate fire hazard. Precautionary Statement: Keep away from heat, sparks, open flame, and other ignition sources. Contact with eyes may cause irritation. Contact with skin may cause irritation. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. 3. Composition/Information on Ingredients Component Name Proprietary blend Water Methanol CAS Registry No. 7732-18-5 67-56-1 Concentration % (Wt.) < 50% <70% <20% Performance Chemical Company Product: Pro-Flow-503 Current Issue Date: December 29, 2013 Page 2 of 6 4. First Aid Measures Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS. Inhalation Eye Contact Skin Contact Ingestion General Advice If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Get medical attention immediately. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. Wash off with soap and water. Get medical attention if irritation develops or persists. It swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting without medical advice. If you feel unwell, seek medical advice (show label when possible). 5. Fire Fighting Measures Extinguishing Media Suitable extinguishing Media Protection of firefighters Water, Alcohol foam, polymer foam, dry chemical powder, carbon dioxide Wear full protective clothing, including helmet, SCBA. If tank, rail car, or tank truck is involved in a fire. Isolate for 800 meters (1/2 mile) in all directions. Always stay away from tanks engulfed in flame. Withdraw immediately in case of rising sound from venting safety devices or any discoloration of tanks due to fire. Move containers from fire area if you can do it without risk. Do not scatter spilled material with high pressure water streams. Use water spray to cool unopened containers. Cool containers with flooding quantities of water until well after fire is out. 6. Accidental Release Measures Personal precautions Environmental precautions Keep people away from upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep unnecessary personnel away. Stay upwind, keep out of low areas. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area.) Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways, sewers, basements or confined areas. Methods for cleaning up Should not be released into the environment. Large Spills: Dike far ahead of liquid spill for later disposal. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. After removal flush contaminated area thoroughly with water. Small Spills: Wipe up with absorbent material (cloth, fleece). Clean contaminated surface thoroughly. Never return spills in original containers 7. Handling and Storage Handling Do not breathe dust/fumes/gas/mist/vapors/spray. Use only with adequate ventilation. Avoid release to the environment. Wash thoroughly after handling. Performance Chemical Company Product: Pro-Flow-503 Current Issue Date: December 29, 2013 Storage Page 3 of 6 Store in a closed container away from incompatible materials. Store in accordance with local/regional/national/international regulation. 8. Exposure Controls and Personal Protection Engineering Controls Ensure adequate ventilation, especially in confined areas Personal Protective Equipment (PPE) Wear appropriate chemical resistant clothing. Wear appropriate chemical resistant gloves. General Hygiene considerations When using do not smoke. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Physical State Liquid Color Colorless Odor Not Available pH 7.0 Specific Gravity 0.988 Flash Point 150 ˚F Vapor Pressure Not available Vapor Density Not available Boiling Point / Range Not Available Freezing Point Not available Evaporation Rate Not Available 10.Stability and Reactivity Chemical Stability Stable Hazardous Polymerization Not expected to occur. 11.Toxicological Information Sensitization Not expected to be hazardous by OSHA criteria. Chronic Effects Not expected to be hazardous by OSHA criteria. Carcinogenicity Not expected to be hazardous by OSHA criteria. Neurological Not expected to be hazardous by OSHA criteria. Further information Not expected to be hazardous by OSHA criteria. 12.Ecological Information Not Not Established. CLEAN WATER ACT: ............... Established. 13.Disposal Considerations Disposal Instructions Do not allow this material to drain into sewers/water supplies. This product, in its present state, when discarded or disposed of, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b) (4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Dispose in accordance with all applicable regulations Performance Chemical Company Product: Pro-Flow-503 Current Issue Date: December 29, 2013 Page 4 of 6 14.Transport Information DOT Information - Non regulated as hazardous goods DOT Requirements Bulk- Not regulated as hazardous goods 15. Regulatory information US FEDERAL TSCA CAS# 67-56-1 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA Section 302 (RQ) CAS# 67-56-1: final RQ = 5000 pounds (2270 kg) Section 302 (TPQ) None of the chemicals in this product have a TPQ. SARA Codes CAS # 67-56-1: acute, flammable. Section 313 This material contains Methyl alcohol (CAS# 67-56-1, 99%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Clean Air Act: CAS# 67-56-1 is listed as a hazardous air pollutant (HAP). This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 67-56-1 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: TF Risk Phrases: R 11 Highly flammable. R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R 39/23/24/25 Toxic : danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. Performance Chemical Company Product: Pro-Flow-503 Current Issue Date: December 29, 2013 Page 5 of 6 S 36/37 Wear suitable protective clothing and gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 7 Keep container tightly closed. WGK (Water Danger/Protection) CAS# 67-56-1: 1 Canada CAS# 67-56-1 is listed on Canada's DSL List. CAS# 67-56-1 is listed on Canada's DSL List. This product has a WHMIS classification of B2, D1A, D2B. CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List. Exposure Limits CAS# 67-56-1: OEL-ARAB Republic of Egypt:TWA 200 ppm (260 mg/m3);Ski n OEL-AUSTRALIA:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin OEL-BELGIU M:TWA 200 ppm (262 mg/m3);STEL 250 ppm;Skin OEL-CZECHOSLOVAKIA:TWA 10 0 mg/m3;STEL 500 mg/m3 OEL-DENMARK:TWA 200 ppm (260 mg/m3);Skin OELFINLAND:TWA 200 ppm (260 mg/m3);STEL 250 ppm;Skin OEL-FRANCE:TWA 200 ppm (260 mg/m3);STEL 1000 ppm (1300 mg/m3) OEL-GERMANY:TWA 200 ppm (2 60 mg/m3);Skin OEL-HUNGARY:TWA 50 mg/m3;STEL 100 mg/m3;Skin JAN9 OEL -JAPAN:TWA 200 ppm (260 mg/m3);Skin OEL-THE NETHERLANDS:TWA 200 ppm ( 260 mg/m3);Skin OEL-THE PHILIPPINES:TWA 200 ppm (260 mg/m3) OEL-POLA ND:TWA 100 mg/m3 OEL-RUSSIA:TWA 200 ppm;STEL 5 mg/m3;Skin OEL-SWEDEN :TWA 200 ppm (250 mg/m3);STEL 250 ppm (350 mg/m3);Skin OEL-SWITZERLAN D:TWA 200 ppm (260 mg/m3);STEL 400 ppm;Skin OEL-THAILAND:TWA 200 ppm (260 mg/m3) OEL-TURKEY:TWA 200 ppm (260 mg/m3) OEL-UNITED KINGDOM:TW A 200 ppm (260 mg/m3);STEL 250 ppm;Skin OEL IN BULGARIA, COLOMBIA, JO RDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM ch eck ACGI TLV 16.Other Information Disclaimer of Liability: The information in this msds was obtained from sources which we believe are reliable. However, the information is provided without any warranty, expressed or implied regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the substance itself. This msds was prepared and is to be used only for this product. The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with handling, storage, use or disposal of the product. Abbreviations: App. = Approximately NE = Not Established EQ = Equal > = Greater Than < = Less Than ACGIH = American Conference of Governmental Industrial Hygienists IARC = International Agency for Research on Cancer NIOSH = National Institute of Occupational Safety and Health NPCA = National Paint and Coating Manufacturers Association NFPA = National Fire Protection Association HMIS® N/AP = Not Applicable ND = No Data AIHA = American Industrial Hygiene Association NTP = National Toxicology Program OSHA = Occupational Safety and Health Administration HMIS = Hazardous Materials Information System EPA = Environmental Protection Agency Explanation of the HMIS® Ratings III - HEALTH HAZARD RATINGS * Chronic Hazard Chronic (long-term) health effects may result from repeated overexposure 0 Minimal Hazard No significant risk to health 1 Slight Hazard Irritation or minor reversible injury possible 2 Moderate Hazard Temporary or minor injury may occur Performance Chemical Company Product: Pro-Flow-503 Current Issue Date: December 29, 2013 Page 6 of 6 3 Serious Hazard Major injury likely unless prompt action is taken and medical treatment is given 4 Severe Hazard Life-threatening, major or permanent damage may result from single or repeated overexposures HMIS® III - FLAMMABILITY RATINGS 0 Minimal Hazard Materials that will not burn 1 Slight Hazard Materials that must be preheated before ignition will occur. Includes liquids, solids and semi solids having a flash point above 200 F. (Class IIIB) 2 Moderate Hazard Materials which must be moderately heated or exposed to high ambient temperatures before ignition will occur. Includes liquids having a flash point at or above 100 F but below 200 F. (Classes II & IIIA) 3 Serious Hazard Materials capable of ignition under almost all normal temperature conditions. Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC) 4 Severe Hazard Flammable gases, or very volatile flammable liquids with flash points below 73 F, and boiling points below 100 F. Materials may ignite spontaneously with air. (Class IA) HMIS® III - PHYSICAL HAZARD RATINGS 0 Minimal Hazard Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. 1 Slight Hazard Materials that are normally stable but can become unstable (self-react) at high temperatures and pressures. Materials may react non-violently with water or undergo hazardous polymerization in the absence of inhibitors. 2 Moderate Hazard Materials that are unstable and may undergo violent chemical changes at normal temperature and pressure with low risk for explosion. Materials may react violently with water or form peroxides upon exposure to air. 3 Serious Hazard Materials that may form explosive mixtures with water and are capable of detonation or explosive reaction in the presence of a strong initiating source. Materials may polymerize, decompose, self-react, or undergo other chemical change at normal temperature and pressure with moderate risk of explosion. 4 Severe Hazard Materials that are readily capable of explosive water reaction, detonation or explosive decomposition, polymerization, or self-reaction at normal temperature and pressure.