記錄
編號
13570
狀態
G0400176192
助教
查核
建檔完成
索書
號
查核完成
學校
名稱
輔仁大學
系所
名稱
化學系
舊系
所名
稱
學號
400176192
研究
林彥妤
生(中)
研究
Yan-Yu Lin
生(英)
論文
名稱
(中)
論文
名稱
(英)
原位乳化聚合法製備聚苯乙烯/官能基化石墨烯氧化物奈米複合材料及其
性質研究
Preparation and Property Studies of Polystyrene/Functional Graphene Oxide
Nanocomposites by In-situ Emulsion Polymerization
其他
題名
指導
教授
(中)
游源祥
指導
教授
(英)
Yuan-Hsiang Yu
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封面(書名頁) 謝辭 摘要 目次 第一章 第二章 第三章 第四章 參考書目
電子
全文
01 02 03 04 05 06 07 08 09
學位
類別
碩士
畢業
學年
度
101
出版
年
102
語文
別
中文
關鍵
奈米複合材料 石墨烯 聚苯乙烯 防腐蝕 氣體分離
字(中)
關鍵
Nanocomposite Graphene Polystyrene Anticorrosive Property Gas Separation
字(英)
摘要
(中)
本論文將無機材料石墨，藉由硫酸、磷酸和過錳酸鉀進行氧化改質，再
利用對苯二胺( p-Phenylendiamin, PPD) 和 4-苯乙烯烴基酸(4-vinylbenzoic
acid, PVBA) 使之還原，進一步將填充材料苯乙烯分散於其中，進行原位
乳化聚合反應，製備一系列不同比例聚苯乙烯/官能基化石墨烯氧化物奈
米複合材料。 所得的產物以 FTIR、XRD、XPS、SEM 和 TEM 進行分析
鑑定；並探討化學官能基改質之石墨烯對材料在熱性質、機械性質、光
學性質之基本特性變化；進一步利用 GPA 和電化學防腐蝕量測來探討石
墨烯(Graphene)的導入增加氣體的穿透路徑，避免及延緩鐵片的腐蝕，有
效提升塗層材料抗腐蝕性能；最後研究自由體積之變化，首次提出高分
子/石墨烯奈米複合材料於氣體分離特性之研究。
摘要
(英)
論文
目次
Graphene has attracted many research and application areas of interest due to its
excellent properties in recent years. Graphene-based nanocomposites exhibiting
excellent electrical conductivity, mechanical properties, thermal conductivity,
thermal stability, gas barrier properties, etc., could be synthesized by using
graphene-based derivatives through their functional groups modification and
reacted with various polymers. Due to the possibility for mass production by
chemical methods, there are great potentials to prepare graphene-based
nanocomposites with low cost and excellent performance for commercial
applications. In this research, A series of polymer-graphene nanocomposite
materials consisting of organic polystyrene (PS) and organo functionalized
graphene oxide were prepared successfully by the effective dispersion of the
graphene nanolayers in the PS matrix through in-situ emulsion polymerization.
The as-prepared organo functionalized graphene oxide (FGO) and PS/FGO
nanocomposites were characterized by Fourier-Transformation infrared (FTIR)
spectroscopy, X-ray Photoelectron Spectroscope (XPS), X-ray diffraction (XRD),
scanning electron microscopy (SEM) and transmission electron microscopy
(TEM). In addition, the properties of as-prepared nanocomposites were studied by
thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), etc.
Anticorrosive and gas separation properties of as-prepared PS/pv-GO
nanocomposites, in form of coating and membrance, were also systematically
investigated and compared based on electrochemical impedance spectroscopy
(EIS) and gas permeability analysis (GPA).
摘要 I Abtract II 目錄 IV 圖目錄 VIII 表目錄 XVI 第一章 緒論 1 1-1 前言 1
1-2 石墨烯簡介 4 1-2-1 碳奈米材料發展之歷史 5 1-2-2 石墨烯之特性 6 12-3 石墨烯的製備方法 8 1-3 石墨烯/高分子奈米複合材料 18 1-3-1 高分子/
石墨烯奈米複合材料之分類 18 1-3-2 高分子/石墨烯奈米複合材料的合成
方法 20 1-3-3 高分子/石墨烯奈米複合材料之特性 23 1-4 聚苯乙烯/石墨烯
奈米複合材料之特性 36 1-4-1 優異的導電性質 36 1-4-2 優異的機械性質
41 1-4-3 優異的熱穩定性 43 1-4-4 優異的熱導性 44 1-4-5 優異的阻氣性質
45 1-5 防腐蝕 47 1-5-1 腐蝕之定義 48 1-5-2 石墨烯之防腐蝕應用 51 1-6 氣
體分離 57 1-6-1 薄膜分離過程概述 58 1-6-2 聚苯乙烯應用於氣體分離膜
61 1-7 研究動機與目的 65 第二章 實驗部分 68 2-1 實驗藥品 68 2-2 鑑定及
分析儀器 70 2-3 實驗構想示意圖 76 2-4 實驗步驟 77 2-4-1 石墨烯氧化物
(GO) 的製備 77 2-4-2 p-GO 的製備 77 2-4-3 pv-GO 的製備 78 2-4-4 聚苯乙
烯的製備 78 2-4-5 聚苯乙烯/官能基化石墨烯氧化物(PS/pv-GO) 奈米複 合
材料的製備 79 2-5 自由立膜(Free Standing File)之製備 82 2-6 氣體穿透分
析之製備及裝置 83 2-7 防腐蝕測試試片之製備及裝置 84 第三章 結果與
討論 86 3-1 結構形貌鑑定 86 3-1-1 紅外光吸收光譜 (FT-IR) 分析 86 3-1-2
化學分析電子光譜(XPS) 91 3-1-3 X 射線粉末繞射儀(XRD)分析 97 3-1-4 場
發射掃描式電子顯微鏡(FE-SEM)分析 102 3-1-5 高解析穿透式電子顯微鏡
(HR-TEM)分析 105 3-1-6 拉曼光譜(Raman Spectrometer)鑑定分析 108 3-1-7
凝膠滲透層析(GPC)之分子量檢測 110 3-2 熱性質分析 112 3-2-1 熱重力分
析(TGA) 113 3-3 動態機械分析(DMA) 119 3-4 阻氣特性 122 3-5 塗層材料
之電化學性質分析 125 3-5-1 防腐蝕測試 125 3-5-2 交流阻抗圖譜(EIS)分析
128 3-6 薄膜材料之氣體分離性質分析 137 3-6-1 pv-GO 對 PS/pv-GO 奈米
複合材料薄膜分子堆疊程度之影響 137 3-6-2 氣體分離測試 138 第四章 結
論 147 第五章 參考文獻 149
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