Radar Absorbing Materials: Furthering the Advancement of Stealth Technology Francesco D. Marino, ME Student Northeastern University Abstract: This paper will discuss the different types of cutting edge materials being designed as radar absorbing materials (RAM). It will define the type of RAM and its general performance. I will discuss the plausible use of each material and provide details on what aspects must be improved or further researched. Overall a general path for future RAM will be proposed and discussed. Keywords: Radar absorbing material (RAM), Radar absorbing structure (RAS), Reflection Loss (RL) Introduction: Aircraft today are becoming faster and more agile each and every year. Nations however are designing methods to counter these newer, better aircraft at the same rate. The way the military is trying to beat out the counter measures built by the enemies, such as surface to air missiles sites, anti-air guns and air-to-air missiles, are by not letting them see the aircraft at all. In today’s fast paced modern world by the time you see an aircraft approaching it is most likely too late to implement a defense or escape; so aircraft defense systems rely of extremely sensitive radar systems. Scientists today are trying to develop ways to let aircraft slip through the radar net undetected. The way radar works is a source emits a wave at a known frequency as it travels out it reflects off of things and bounces back to the receiver. By knowing the frequency and velocity of the wave you can locate the position and speed of the object reflecting the wave. By designing a material that will absorb those waves it will not be recognized by the receiver, therefore giving the appearance that there is nothing there. The image shows how when a radar ream hits a RAM it reflects the wave internally and does not let the wave escape. How a RAM works There are many different types of materials that absorb wide ranges of frequencies however some are not practical to use such as lead. The design of a versatile, durable, high absorption material is greatly needed to advance todays aircraft past the treats of anti-aircraft systems. The standardized measuring technique is by reflection loss. 10 dB absorbing bandwidth means that the frequency bandwidth can achieve 90% of reflection loss, whereas a 20 dB absorbing bandwidth means that the frequency bandwidth can achieve 99% of reflection loss. RAM Types: 1 Polymer RAM 1.1 Carbonyl Iron/Rubber Carbonyl iron can be used as microwave absorption filler in the frequency range of 2.6–18 GHz and even at higher frequencies because it has good temperature stabilization and high value of microwave permeability and dielectric constant which makes it a very good RAM. EthylenePropylene-Diene Monomer (EPDM) has excellent durability, chemical resistance and, makes a good insulator. It also is soluble with many types of fillers.[1] This makes the two materials a good pair. By doping the EPDM with carbonyl iron a strong RAM is created. Fig. 1) Effects of carbonyl iron volume fraction on the reflection loss of the RAM (d = 3:0 mm). [1] 1.2 Polyaniline/rubber The goal of RAM materials is to create a substance that yields minimal scattering of waves when irradiated by a power source. Acceptable results were attained using the conducting polymer polyaniline (PAni). The polymer compound was produced using blends of EPDM (ethylenepropylenediene rubber) and the PAni. They were prepared in an internal mixer for different processing time. Flat sheets of 3mm thick and 15cm x 15cm dimension were obtained by compression molding at 100°C.[2] Four different samples were produced shown in Table 1. Out of the four RAMs produced only #2 and #3 had a RL less then -10dB. They both provide a sufficient RL across an equal frequency range. However the performance of RAM #2 slightly surpasses that of RAM #3. The use of this material would not be too bad as a coating for the leading edge of wing tips or even the entire wing and/or fuselage. Table 1) Parameters used in the RAM preparation[2] Fig. 2) Affects of thickness of the RAM on the microwave absorption properties. (a) Vf = 0.3 (b) Vf = 0.45. [1] The reflection loss by the material is measured. The volume fraction of the iron is varied along with the thickness of the test sample. In figure 1 the sample thickness is held constant at 3mm and the volume fraction is varied from 0 to .45. In figure 2 the volume fraction is held constant and the thickness of the sample is varied. From these graphs you can see that its effectiveness greatly depends on its composition and the thickness of the sample. Only a few of the tests resulted in a RL of 10dB over the Xband frequencies. Fig. 3) RAM #1 reflectivity on X-Band [2] 2 Carbon Fiber RAM Carbon fiber is one of the most widely used materials in aviation due to its light weight and high strength however, it happens to be a fantastic radar reflector which is bad for its stealth capabilities. [3] In order to masks the signature of the carbon fiber components a few methods are being developed. 2.1 Nickel coated CF Fig. 4) RAM #2 reflectivity on X-Band [2] Fan et al.’s approach to this problem is to coat the carbon fibers in a thin nickel film. They used electroless plating in order to adhere the nickel to the carbon fibers (CF). The nickel carbon fibers (NCF) have a uniform and continuous coating with a thickness of ca. 1.2 μm (Figure 7b). The nickel carbon fibers are then tested for their reduction loss across a range of frequencies by mixing the NCF into cement with a 15% and 30% weight ratio. [4] Fig. 5) RAM #3 reflectivity on X-Band [2] Fig. 7) The surface morphology of (a) CF; (b) NCF [4] The results of this test show the reflection loss is good with a 30% weight ratio to the phenol– formaldehyde cement above 13 GHz (Figure 8). This material would perform well in aircraft if the NCF could be integrated into other materials of the aircraft. Phenol-formaldehyde cement would not be on any use in an aircraft so the NCF should be tested in other substrates to validate its plausible use. Fig. 6) RAM #4 reflectivity on X-Band [2] After dried in air, they were annealed at 350 and 400°C for 4 h in air to achieve the CNWCFs. 350°C produced very few nanowires however 400°C produced very abundant long nanowires as shown in figure 9. The RL was tested for samples of varying thickness across a range of frequencies. (Figure 10) Fig. 8) Reflection loss of the NCF *Disregard FG and NFG*[4] 2.2 Cupric oxide-nanowire (CNW) coated CF In previous reports, cupric oxide nanowires (CNWs) showed remarkable optical, electrical, magnetic, and mechanical properties [5]. Jun et al. synthesized the CNWCF by annealing copper coated CFs in air. The Cu/CFs were created by electroless plating. Fig. 9) The low and high magnification FESEM images of CNWCFs synthesized at different temperatures: (a) and (b) at 350 °C; (c) and (d) at 400°C. [5] Table 2) [5] The carbon fibers were cut to 2–3 mm in length before the surface treatment. The treatment involves three steps: (1) The carbon fibers were immersed in nitric acid for 5 h and then washed with distilled water. (2) The carbon fibers were treated with stannous chloride and ammoniacal silver solution. (3) They were coated by electroless plating at room temperature for 3 h. Table 1 lists the electroless copper bath conditions. SEM images show that the CFs were completely coated with a thin copper film of 2μm. [5] Fig. 10) Reflectivity curves of different thickness of CNWCFs. [5] The microwave absorption mechanism of CNWCFs has rarely been reported in the previous literature. The results from this experiment offer a promising future for CNWCF use as RAM. Since the thinner samples induced reduction in the X-band and higher it will prove useful for thin film coatings of aircraft and wind turbines. Further advancements must be done in order to achieve a higher reflectivity of the thinner samples on the same scope as the think samples. 3 Composite RAM The use of ferrite materials for RAM applications is the standard approach. However the weakness of ferrite materials is that they lose their effectiveness over large frequency ranges. [6] Also the addition of ferrites increases the weight drastically; composite RAMs can be engineered to cover large frequency ranges and are exponentially lighter. 3.1 Composite Carbon nanotube RAS Zhang et al. integrated carbon nanotubes into the composite carbon fiber structure so it would be able to absorb radar while still maintaining its structural integrity and not sacrificing its light- weight [7]. The CNTs were dispersed in acetone solution in an ultrasonic installation for 2h. After, the epoxy resin had been compounded with the CNT in a self-made die. Then, the glass/carbon fibers/epoxy composites were prepared in a planar rectangular mold. Curing at room temperature for 2h, RAS specimens which composed with glass fibers, carbon fibers, epoxy resin and CNT, were produced, while the pressure was stabilized at 6atm. [7] Four different test samples were created each with a different weight percentage of CNT and one control sample (Table 3). Table 3) Weight percentages of CNT to epoxy Composite denotations Fig. 11) Reflection loss of four kinds of double-layer RAS: A curve, CNT1.2, 5.0mm,CNT0,4.0mm; B curve,CNT1.2,4mm,CNT0,3mm; C curve, CNT1.6,5mm,CNT0,3mm; D curve, CNT1.6,4 mm, CNT 0, 2mm Different double layer configurations were produced and tested shown in the above figure 11. The materials produced excellent RL across a broad range of frequencies; however these test samples were all at least 6mm in thickness which is way too thick to use as a practical coating a 6mm coating over the entire aircraft would add hundreds of pounds. The beauty about CF composites is that they are extremely strong and can be used for structural support. So these materials could be integrated into parts of the aircraft that are already made from epoxy composites and even perhaps make the skin of the aircraft out of these composites. The only thing needed to be done is to figure out how to synthesize components with this material while not jeopardizing structural integrity. A stealth plane doesn’t do any good if its wings fall off when it takes flight. 3.2 Carbon Black composite With weight being a huge concern Oh et al. strived to create a RAS using a blend of lightweight carbon black and a binder matrix of fiber reinforced composite. The goal of their research was to minimize thickness of the material while maximizing the absorption throughout the X-band frequency. The specimens were created by mixing the epoxy matrix with carbon black and then uniformly applying it to the glass fabric. To cure the specimen it is baked in a autoclave for 30 min at 80° and then for 90 min at 130° while maintaining the pressure at 3 atm. [8] Multiple samples were created using different weight percentages of carbon black. The following table shows the denotations. The test is conducted three times. Once without the DZR to provide a control; the second test with nondispersive DZR, and the third with dispersive DZR. Table 4) Specimen denotations of glass fabric/epoxy composites [8] Due to the high viscosity of the CB15 and CB20 samples the epoxy matrix was able to be uniformly applied to the glass fabric; so the test results were inconclusive. The CB10 sample reflected more than 45% of the incident waves at the surface so this material would not serve as a suitable RAS. The absorbing bandwidths of the CB5-CB8 change with respect to the thickness. According to Oh et al. the CB5 exhibits excellent characteristics of reflection loss near 12GHz; however it has the weakness of having a large total matching thickness of 8mm. CB6 shows excellent characteristics at 8GHz and a matching thickness of 2.7mm. CB7 and CB8 exhibited low reflection loss across all frequencies. [8] As seen from the results, it is very important to manufacture the RAS materials with the right amount of additive along with a precise uniform thickness. Fig. 12) Reflected power from a PEC plane versus frequency (a) without coating (b) with two layers of non-dispersive DZR metamaterial coatings (c) with two layers of dispersive DZR metamaterials. [10] From figure 12 you can see that both the DZR coatings produced a huge loss of reflected power with the non-dispersive DZR coating having a reflective power of 0 across the entire X-band. Oraizi et al. also wanted to see the performance of the metamaterial with a varying incidence angle. The sample material had the following parameters coating a PEC plate. 4 Double Zero (DZR) Metamaterials A double zero Metamaterial is an artificially created material engineered to have properties not found in nature. A DZR metamaterial have the real parts of both the permittivity and permeability equal to zero; Re(ε)=0 and Re(μ)=0.[9] Oraizi at el. realized that this material could be used for a number of different applications, one of them being the use as a RAM. They fabricated a two layer DZR to coat a perfectly electric conductor (PEC) plate with and test at an incident angle of 45° through the X-band range of frequencies.[10] The sample plate was rotated through incidence angles from 0 to 45°. Figure 13 shows the test results in comparison to a non-coated PEC plate. It is observed that both the non-dispersive DZR coating and dispersive coating have a good performance throughout the frequency bandwidth and the changing angle of incidence. If you look at the parameters notice that the thickness of the material is less than 2 mm. This is very good performance for the thickness of the material. performance throughout varying angles of incidence enables it to works on all the surfaces of the aircraft. Secondly the use of RAS in aircraft is an important option to work towards for the future. By making the internal components of the plane radar absorbent it will further the stealth capabilities of the plane as a whole. The important aspect to work on would be the manufacturing process with these RAS materials and increasing the strength of the RAS. If all the major components of the aircraft could be replaced with equally strong and light RAS materials then there would be no negatives to adding stealth capabilities to the aircraft. Fig. 13) 3-D diagram of reflected power from a PEC plane versus frequency and angle of incidence under oblique incidence for three cases: (a) without coating. (b) With two layers of nondispersive DZR metamaterial coatings (c) With two layers of dispersive DZR metamaterial coatings. [10] Conclusion: Even with all this data it is tough to say that an of the materials discussed are ready for application. A lot of work must be still done to improve these materials. The goal should be to make the materials thinner and more effective across a wider frequency. Secondly each one of these test were performed in different manners under different test conditions. In order to receive a clearer palate if information each of the materials should be tested in the same machine under the same conditions. This will enable to data not to be skewed by different testing operations. The best solution would be to standardize the test to measure the RAM’s effectiveness. This will enable scientists all over the world to perform their testing on their own and be able to easily compare it to other results worldwide. Judging from these results I feel that the DZR RAM shows the most promising results. With having such a good stable RL across such wide range of frequencies as well across a wide range of incident angles. The test was performed with a sample thickness of only 2mm. This is outstanding performance for such a small thickness. This material seems like it could be used as a suitable coating for the entire aircraft because it performs so well with a thickness of only 2mm. Also its ability to maintain it Overall a lot more work needs to be done to improve thin coating RAM and RAS before they can be applied to aircraft. The use of a standardized test must be implemented and equal testing must be performed in order to decide on the best material and parameters to implement in aircraft for today and the future. References [1] Yong-Bao Feng, Tai Qiu, Chun-Ying Shen, and Xiao-Yun Li. "Electromagnetic and Absorption Properties of Carbonyl Iron/rubber Radar Absorbing Materials." IEEE Transactions on Magnetics 42.3 (2006): 363-68. Print. [2] Franchitto, M., R. Faez, A.J. F. Orlando, M. C. Rezende, and M. Martin. SBMO/IEEE MTi-S IMOC 2001 Proccedings (2001): 13740. Print. [3] Pitkethly, M. J. "Radar Absorbing Materials and Their Potential Use in Aircraft Structures." (n.d.): n. pag. Print. [4] Fan, Y., H. Yang, X. Liu, H. Zhu, and G. Zou. "Preparation and Study on Radar Absorbing Materials of Nickel-coated Carbon Fiber and Flake Graphite." Journal of Alloys and Compounds 461.1-2 (2008): 490-94. Print. [5] Jun, Zeng, Tao Peng, Wang Sen, and Xu Jincheng. "Preparation and Study on Radarabsorbing Materials of Cupric Oxidenanowire-covered Carbon Fibers." Applied Surface Science 255.9 (2009): 4916-920. Print. [6] K.L. Zhang, C. Rossi, C. Tenailleau, P. Alphonse, J.Y.C. Ching, Nanotechnology 18 (2007) 275607. [7] Zhang, Zhengquan, Tiehu Li, Deqi Jing, and Qiang Zhuang. "Fabrication and Optimization of Radar Absorbing Structures Composed of Glass/carbon Fibers/epoxy Laminate Composites Filled with Carbon Nanotubes." COMMAD 2008 (2008): 20912. Print [8] Oh, J., K. Oh, C. Kim, and C. Hong. "Design of Radar Absorbing Structures Using Glass/epoxy Composite Containing Carbon Black in X-band Frequency Ranges."Composites Part B: Engineering 35.1 (2004): 49-56. Print. [9] Oraizi, Homayoon, A. Abdolali, and N. Vaseghi. "Introduction of a New Class of Materials Called Double Zero Media Having the Real Parts of Epsilon and MU Equal to Zero." (n.d.): n. pag. Print [10] Oraizi, H., A. Abdolali, and N. Vaseghi. "APPLICATION OF DOUBLE ZERO METAMATERIALS AS RADAR ABSORBING MATERIALS FOR THE RE- DUCTION OF RADAR CROSS SECTION." Progress in Electromagnetic Research 101 (2010): 323337. Print.