REPORT: GEOCHEMICAL FIELD SAMPLING CAMPAIGN OF THE IGCP/SIDA/UNESCO/MUT PROJECT 606-SIDA EXTRA BUDGETARY ALLOCATION; YAOUNDE CAMEROON, 03 - 09 JULY, 2013 The Geochemical Circulation of Selected Potentially Harmful Elements (PHEs) in Ecosystems Around Mining Centres in East Cameroon: Health implications J. Penaye T.C. Davies S.C. Ngueme Fils E.E. Bate-Tibang M.E. Mimba M. Shapi EXECUTIVE SUMMARY The Swedish International Development Agency (SIDA) Extra-Budgetary Funding for 2013 was an additional grant awarded for the implementation of a proposed extension phase of IGCP/SIDA/UNESCO/MUT Projects 954 and 606, respectively. The geochemical field campaign undertaken in East Cameroon (Kette/Batouri) during the early part of July, 2013, was in fulfilment of the first of four project objectives, specifically for Cameroon, among a number of other Sub-Saharan African countries addressed in the Sub-region. The objective was: ‘to understand how mining and ore processing activities, and particularly abandoned mines, negatively affect the ecosystem (soils, plants, surface- and groundwater) and the health of the neighbouring communities’. A total of 30 soil samples in duplicate and triplicate (respectively), 22 duplicate natural water samples, and duplicate cassava samples were collected from cultivable and uncultivable lands and waterways in and around the alluvial gold mining towns of Kette and Batouri. Thirteen field hydrochemical parameters were measured ‘in situ’ on the water samples. All samples were prepared using standard laboratory procedures, professionally packed and shipped to ACME Laboratories in Vancouver, Canada for analyses of a range of nutritional and potentially harmful elements. Transportation and other logistics for the fieldwork and sample preparation were provided by the Institute of Geology and Mining Research. INTRODUCTION Location of study area The study area is situated in the Kadey Division, Eastern Region of Cameroon along the Equatorial Rainforest Belt. It extends from Kette Sub-Division (4°57'40.04''N and 14°33'45.35"E) in the north to Batouri (4°25'59.84''N and 14°22'00.49"E), the Divisional Headquarters, covering a ground distance of about 85 km (Fig. 1). Fig.1: Location of the study area Climate The study area is influenced by a hot and humid equatorial climate of the classic Guinean type, marked by the alternation of two rainy seasons and two dry seasons. The mean annual rainfall is between 1500 mm and 2000 mm and the average temperature ranges from 22.8 °C to 24.7 °C. During the year, the area experiences the following seasons: the short rainy season from mid-March to June; the short dry season from June to mid-August; the main rainy season, from mid-August to midNovember, and the long dry season from mid-November to mid-March. Vegetation The vegetation in Kette Sub-Division is dominated by a mosaic of shrub and herbaceous savanna bush, with short grasses on the peneplain; this gives way to a gallery forest on the approach to the southern fringes of Batouri. Relief The topography consists of gently rolling hills with an average altitude of between 600 m and 900 m (Fig. 2). The landscape comprises a peneplain, rugged in some places, and supporting a mosaic of lush grass and thicket. A few swampy patches are observed in the shallows. Steep slopes are observed but are very much localised. Fig. 2: Relief and hydrography Hydrography The rugged terrain favours a dendritic drainage system (Fig. 2). The most important river is the Kadey at Batouri, which is fed by the Bombé and Mama streams encountered further north in Kette SubDivision. Geology The Batouri region in East Cameroon is underlain by syn- to late-tectonic granitoids emplaced into medium- to high-grade schists of the Neoproterozoic Yaounde Group. Granitoids include porphyritic biotite-amphibolite granites and granodiorites cross-cut by numerous quartz dykes bearing localised gold mineralization. Schists are generally observed as large xenoliths in the granitoids and include well-deformed gneisses and amphibolites. Soils The study area lies along the Equatorial Rainforest Belt, with warm, wet and humid conditions, combined with a varied topographic profile. There is widespread microbial activity. This combination ensures rapid and prolonged weathering, including biochemical decomposition, resulting in the formation of the typical red or yellow lateritic soils, which are again subjected to leaching. The hydromorphic soils are found mainly in the shallows and are mainly sandy or sandy clay in texture. Despite having soils of apparently high agricultural potential, very little food crops are grown in the Region. Demography and economic activities The population of the Kette municipality is estimated at 31,129 inhabitants in 2010, and that of Batouri, 67,007 in 2010 (3 RGPH, 2010), put together, are relatively young and cosmopolitan. These towns consist of the following dominant ethnic groups: Gbaya Kako, Yanguélé, Bépalo and Mbororro; and minority ethnic groups: Hausa, Mésimé, Maka, Bulu, Bamileke, Fulani, Boussougou, Ewondos, Bamun and Bangantou. Many refugees from the Central Africa Republic are added to this national population, particularly in Kette Sub-Division. The different religious groups existing in the area are the Adventist, Presbyterian, Full Gospel, Muslims, Bahai and Catholics who live together peacefully. Geographic isolation coupled with the existence of an inadequate economic base, does not favour the development of local economic activities such as agriculture, fishing, livestock rearing, crafts and gemstone extraction. Basically, only subsistence agriculture is practiced in this area. The main food and vegetable crops cultivated in this area include Manihot esculenta, Dioscorea rotunda, Arachys hypogaea, Zea mays and Amaranthus esculentus. The hydrological network encourages the development of artisanal fishing. Cattle rearing is widely practiced by the indigenes. This constitutes the main economic resource of the locality. The Kette basement has been unsustainably exploited; notably, through artisanal mining activities (gold and diamond). However, this activity provides these locals with substantial income (Mengue, 2012). METHODOLOGY Soil and water samples were collected in accordance with the project sampling protocol. The GPS coordinates (latitude, longitude and altitude) as well as other geoenvironmental characteristics were recorded at each sampling site. Soil sampling A total of thirty soil samples (Fig. 3) were collected; two composite samples from 2 farms and twenty eight other soil samples at 15 m on either side of the road from Kette to Batouri. On each of the two farms, a composite near-surface (30 cm below A0 ) soil sample was collected. Using a pick, hoe and shovel, four holes were made at the corners of a square. This square had dimensions 20 x 20 m in accordance with IGCP 259 recommendations (Darnley et al., 1995). The sub-samples were homogenised and quartered on a plastic sheet using a trowel; and approximately 250 g of this sample taken and stored in labelled Kraft paper envelopes. Duplicate samples were collected from each site. The different crop types, geology, topography, vegetation and other geoenvironmental variables of the area were noted. The other soil sampling sites are located along the road from Kette to Batouri (Fig. 3). A 1m X 1m pit was dug using the pick and shovel to a depth of 40 cm. About 250 g of the bulk sample was collected at depth of 30 cm using a trowel, followed by description of the soil colour, texture and other pedological characteristics; these samples were then stored in labelled Kraft sample bags. Samples were collected in duplicate or triplicate from each site. The samples were later oven-dried (30˚ C) at the Hydrological Laboratory at the Institute for Geological and Mining Research (IRGM), Nkolbisson, and submitted for geochemical analysis. The geology, topography, vegetation and other geoenvironmental variables of the area were also noted. Fig. 3 : Soil sampling sites Water sampling Twenty-two water samples (Fig. 4) were collected from accessible water points. Ten samples from boreholes (BH), two from open wells (OW), four from springs (SP), five from streams and one from a river, were collected. At each water sampling point, the multiparameter water analyser and new 250 ml HDPE sample bottles were washed three times with distilled water and the water to be sampled before determination of water quality parameters (Table 1). The collected water sample was then stored in the pre-labelled HDPE bottles after thorough rinsing. Collected water samples were properly capped and preserved without cooling. Three samples (A, B, C) were collected from each sampling site. These were later filtered (less than forty-eight hours) at the Hydrological Laboratory at IRGM Nkolbisson. To one 250 ml aliquot of the samples was added two drops of ARISTAR grade concentrated hydrochloric acid (HCl), to another 250 ml aliquot was added two drops of ARISTAR grade concentrated nitric acid (HNO3), and one 250 ml aliquot was preserved without acidification. These were preserved under cooling conditions and shipped to Vancouver for chemical analyses. The geology and land use practices in the area were also noted. Fig. 4 : Water sampling stations Dried cassava chips cultivated in the study area was bought for chemical analysis. Cassava (Manihot esculenta), the staple food of this region, is the main subsistence crop. However, subsistence agriculture is seldom practiced by the indigenes. The enigma of having very large areas of apparently high quality-, very cultivable soils in East Cameroon, accompanied by very little agricultural productivity, is being urgently investigated by the project team. Geochemical analysis All the samples collected have been professionally packed and shipped to ACME Laboratories in Vancouver, Canada, for analyses of 36 trace elements, including PHEs by ICP/MS and ICP/OES techniques. Conclusion The analytical results would be synthesised and interpreted so as to provide tangible scientific support for use in the formulation of environmental norms in individual Sub-Saharan African countries, for improving the efficiency of governments in addressing the challenges related to the adverse effects of abandoned mines; in particular, using the results to provide advice on tangible measures for mitigating the effects of PHEs migrating from mine sites all the way into the food chain, and for obviating accompanying environmental health consequences. Integration of these results with conclusions drawn from the ‘outreach and educational research’ component of these projects, would help strengthen awareness (science-based knowledge and advices) in governments, the private sector and the public on the impact of abandoned and derelict mines on the environment, ecosystem services and health. Recommendation It is noted that the land in this part of the country is very fertile, with very low input of PHEs from mining. On the basis of our field observations and analytical results, we recommend provisionally, the adoption of new land use policies for Eastern Cameroon, that favour the intensification of agricultural activities. References - 3ème Recensement Général de la Population et des Habitats du Cameroun (RGPH), 2010. Bureau Central des Recensements et des Etudes de la Population (BUCREP). http://www.bucrep.cm/ Darnley, A.R., Darnley A. G., Bjorklund A., Bolviken B., Gustavsson N., Koval P. V., Plant J. A., Steenfelt A., Tauchid M. and Xie X., 1995. A Global Geochemical Database for Environmental and Resource Management. Recommendations for International Geochemical Mapping. Final Report of IGCP Project 259. Earth Sciences 19, UNESCO. Fordyce, F.M, Zhang Guangdi, Green, K. and Liu Xinping, 2000. Soil, grain and water chemistry in relation to human selenium-responsive diseases in Enshi District, China. Applied Geochemistry, Vol. 15, p. 117 - 132. - Mengue F. D., 2012. Qualité des eaux de puits et forages du secteur de Ketté. Mémoire présenté et soutenu en vue de l’obtention du Diplôme de Professeur d’Enseignement Secondaire Général deuxième grade (DIPES II) en Sciences Biologique. Ecole Normale Supérieur (ENS). 56P. ***************************************************************************