Chapter 3: Ionic and Covalent Compounds 1. Which is not an ionic compound? A) KCl B) Ca(NO3)2 C) CBr4 Ans: C Difficulty: Easy D) AlBr3 2. Which is not a covalent compound? A) Br2 B) NO2 C) NH3 D) NaNO2 E) More than one of the compounds above is not a covalent compound. Ans: D Difficulty: Easy 3. In bonding, main group elements _____ to attain the electronic configuration of the noble gas closest to them in the periodic table. A) Gain electrons C) Share electrons B) Lose electrons D) Gain, lose, or share electrons Ans: D Difficulty: Easy 4. _____ are negatively charged ions that have _____ electrons than protons. A) Anions, more B) Cations, more C) Anions, less D) Cations, less Ans: A Difficulty: Medium 5. Which statement concerning the ion Li+ is correct? A) Li+ has two total electrons. B) Li+ has an octet of electrons in its valence shell. C) Li+ is formed when a lithium atom gains one electron. D) Li+ is formed when a lithium atom gains one proton. Ans: A Difficulty: Difficult 6. What is the electron configuration of an F– ion? A) 1s22s22p4 B) 1s22s22p5 C) 1s22s22p6 D) 1s22s22p63s1 Ans: C Difficulty: Difficult 7. What is the ion symbol for an atom with twenty (20) protons and eighteen (18) electrons? A) Ca B) Ca2+ C) Ar D) Ar2+ E) Ar2– Ans: B Difficulty: Medium Page 23 Chapter 3: Ionic and Covalent Compounds 8. When forming ions, metals typically do which of the following? A) Lose electrons to form negatively charged ions B) Gain protons to form cations C) Gain electrons to form anions D) Lose electrons to form positively charged ions Ans: D Difficulty: Easy 9. What is the ion symbol for an atom with sixteen (16) protons and eighteen (18) electrons? A) S2– B) S C) Ar D) Ar2+ E) Ar2– Ans: A Difficulty: Medium 10. How many protons and electrons are present in Co2+? A) 27 protons, 27 electrons C) 27 protons, 25 electrons B) 27 protons, 29 electrons D) 29 protons, 27 electrons Ans: C Difficulty: Medium 11. What is the symbol for the ion formed by magnesium? A) Mg2– B) Mg3+ C) Mg2+ D) Mg4– Ans: C Difficulty: Medium 12. What is the charge of the ions formed by group 7A elements? A) +1 B) +7 C) –1 D) –7 Ans: C Difficulty: Easy 13. What is the ion symbol of the oxide ion? A) O2– B) O22– C) O2 D) O2+ Ans: A Difficulty: Medium 14. Which element has a variable charge? A) Na B) Fe C) Al D) C Ans: B Difficulty: Medium 15. Which pair of elements will form an ionic compound? A) Sulfur and oxygen C) Iron and chlorine B) Copper and iron D) Bromine and oxygen Ans: C Difficulty: Easy 16. What is the formula for the ionic compound formed when potassium and bromine combine? A) PBr B) KBr C) KBr2 D) K2Br Ans: B Difficulty: Easy Page 24 Chapter 3: Ionic and Covalent Compounds 17. What is the formula for the ionic compound lithium oxide? A) LiO B) LiO2 C) Li2O D) Li2O2 Ans: C Difficulty: Medium 18. Which statement best explains the basis for the octet rule? A) Atoms are most stable when they have eight bonds. B) Atoms lose, gain, or share electrons to become a stable, noble gas. C) Atoms are most stable with eight protons in their nucleus. D) Atoms are most stable with eight electrons in their valence shell and the electron configuration of a noble gas. Ans: D Difficulty: Difficult 19. What is the formula for the ionic compound formed when magnesium and oxygen combine? A) MgO B) MgO2 C) Mg2O D) Mg2O2 Ans: A Difficulty: Medium 20. What is the formula for the ionic compound formed when aluminum and sulfur combine? A) AlS B) Al2S3 C) AlS3 D) Al2S Ans: B Difficulty: Difficult 21. What is the proper name for CuCl? A) Copper chloride B) Copper (I) chloride Ans: B Difficulty: Difficult C) D) Copper (II) chloride Copper monochloride 22. What is the proper name for MgF2? A) Magnesium fluoride B) Magnesium (I) fluoride Ans: A Difficulty: Easy C) D) Magnesium (II) fluoride Magnesium difluoride 23. What is the name of the SO42– ion? A) Sulfide ion B) Sulfate ion C) Sulfite ion Ans: B Difficulty: Medium D) Bisulfate ion 24. What is the chemical formula for the ionic compound calcium selenide? A) Ca2Se2 B) CaSe C) CaSe2 D) Ca2Se Ans: B Difficulty: Medium 25. What is the chemical formula of tin (IV) cyanide? A) Sn4CN B) SnCN4 C) Sn(CN)4 D) SnC4N4 Ans: C Difficulty: Difficult Page 25 Chapter 3: Ionic and Covalent Compounds 26. The formula for zinc acetate is _____. A) ZnCH3CO2 B) Zn(CH3CO2)2 C) Zn(HCO3)2 Ans: B Difficulty: Difficult 27. Which chemical formula is not correct? A) Na2HCO3 B) NaNO3 C) Na2HPO4 Ans: A Difficulty: Difficult D) Zn(HCl)8 D) Na2SO3 28. Which chemical formula is correct? A) Ag(CH3CO2)2 B) K2CN C) Mg(OH)2 Ans: C Difficulty: Difficult D) MgHCO3 29. An atom has the electron-dot symbol shown below. If this atom is a main group element, what charge will it form in its ionic state? A) –1 B) +3 C) –5 D) –3 Ans: B Difficulty: Easy 30. Which atom fits the electron-dot symbol shown below? A) Li B) B C) N D) Na Ans: B Difficulty: Medium 31. If atoms with the electron-dot symbols shown below are combined, what is the formula of the ionic compound that is formed? A) XY B) X2Y C) XY2 D) X2Y2 Ans: B Difficulty: Difficult E) X3Y2 32. If atoms with the electron-dot symbols shown below are combined, what is the formula of the ionic compound that is formed? A) XY B) X2Y C) XY2 D) X2Y2 Ans: A Difficulty: Difficult E) X3Y2 33. What period 4 element forms an ion with a –1 charge? A) Sulfur B) Bromine C) Iodine D) Rubidium Ans: B Difficulty: Medium Page 26 Chapter 3: Ionic and Covalent Compounds 34. What is the name of the compound (NH4)2SO4? A) Ammonium sulfide C) B) Ammonia sulfate D) Ans: D Difficulty: Difficult Ammonia sulfoxide Ammonium sulfate 35. Which compound has the highest melting point? A) KCl B) CH4 C) C6H12O6 D) H2O Ans: A Difficulty: Medium 36. What is the charge on the chromium ion in the ionic compound CrCl3? A) +6 B) +3 C) –3 D) –6 Ans: B Difficulty: Difficult 37. What is the formula for the ionic compound formed from the lead (II) ion and the carbonate ion? A) Pb(CO3)2 B) PbCO3 C) Pb2CO3 D) PbCO4 Ans: B Difficulty: Difficult 38. The correct name for AuI3 is A) Silver iodide B) Gold iodide Ans: C Difficulty: Medium C) Gold (III) iodide D) Gold iodide (III) 39. What is the formula for chromous cyanide? A) CrCN B) Cr(CN)2 C) Cr(CN)3 D) Cr2CN Ans: B Difficulty: Difficult 40. The diphosphate ion is a biologically important polyatomic ion. If the ionic compound calcium diphosphate has the formula Ca2P2O7, which correctly represents the ion symbol of the diphosphate ion? A) P2O72– B) PO4– C) 2 PO46– D) P2O74– Ans: D Difficulty: Difficult 41. What is another name for an unshared pair of electrons in a covalent compound? A) Lone pair of electrons B) Nonbonded electron pair C) Bonding pair of electrons D) Lone pair of electrons or nonbonded electron pair Ans: D Difficulty: Easy Page 27 Chapter 3: Ionic and Covalent Compounds 42. Which of the statements concerning chemical bonds is false? A) The sharing of electrons between two nonmetal atoms results in a covalent bond. B) The attraction between oppositely charged ions results in an ionic bond. C) The term nonpolar is used to describe a covalent bond in which electrons are not shared equally. D) A bond dipole is the separation of charge that results when atoms sharing electrons have different electronegativities. Ans: C Difficulty: Medium 43. How many covalent bonds are generally formed by atoms with five valence electrons? A) 1 B) 2 C) 3 D) 4 E) 5 Ans: C Difficulty: Medium 44. How many lone pairs of electrons are present in the Lewis structure of ammonia, NH3? A) 0 B) 1 C) 2 D) 3 E) 4 Ans: B Difficulty: Easy 45. How many nonbonded electron pairs are in the Lewis structure below? A) 2 B) 4 C) 6 D) 8 Ans: B Difficulty: Easy E) 16 46. What is the Lewis structure for chloroethylene (C2H3Cl)? A) B) C) D) Ans: C Difficulty: Difficult 47. How many valence electrons are in a molecule of formaldehyde (CH2O)? A) 16 B) 12 C) 10 D) 8 Ans: B Difficulty: Medium Page 28 Chapter 3: Ionic and Covalent Compounds 48. Predict the bond angles around the carbon atom in the structure of carbonic acid shown below. Don't forget to draw in lone pairs where needed to give octets. A) 180° B) 120° C) 109.5° Ans: B Difficulty: Medium D) 90° 49. What is the molecular shape around the phosphorus atom in PH3? A) Linear B) Bent C) Trigonal planar D) Tetrahedral E) Trigonal pyramidal Ans: E Difficulty: Difficult 50. What are the bond angles in a tetrahedral geometry? A) 180° B) 120° C) 109.5° D) 90° Ans: C Difficulty: Easy 51. Aspartic acid is an amino acid used to synthesize proteins. How many lone pairs of electrons need to be added to complete the aspartic acid structure shown below? A) 4 B) 6 C) 8 D) 9 Ans: D Difficulty: Medium 52. Which of the following molecule(s) is(are) polar? A) CO2 B) CH4 C) CBr4 D) CHBr3 Ans: D Difficulty: Difficult 53. Rank the atoms Br, Cl, and K in order of increasing electronegativity. A) K < Br < Cl B) Cl < Br < K C) Br < Cl < K D) K < Cl < Br Ans: A Difficulty: Difficult 54. Rank the atoms Br, Cl, and F in order of increasing electronegativity. A) F < Br < Cl B) Cl < Br < F C) Br < Cl < F D) F < Cl < Br Ans: C Difficulty: Medium Page 29 Chapter 3: Ionic and Covalent Compounds 55. Which atom has the lowest electronegativity? A) Al B) S C) Se D) Rb Ans: D Difficulty: Medium 56. Which bond is the most polar? A) C–N B) C–O C) C–C D) C–Cl Ans: E Difficulty: Difficult E) C–F 57. Which bond is the least polar? A) C–N B) C–O C) C–C D) C–Cl Ans: C Difficulty: Easy E) C–F 58. Aspartic acid is an amino acid used to synthesize proteins. How many polar bonds are in the aspartic acid structure shown below? A) 4 B) 6 C) 9 D) 12 Ans: C Difficulty: Difficult 59. What is the correct chemical formula of selenium dioxide? A) SO2 B) SeO2 C) Se2O D) OS2 Ans: B Difficulty: Easy 60. Which bond has the polarity incorrectly labeled? A) + H–Cl – B) + O–C – C) + Cl–F – D) Ans: B Difficulty: Medium 61. Which is the correct Lewis structure for OBr–? A) D) B) E) C) Ans: B Difficulty: Difficult Page 30 – Cl–Br + Chapter 3: Ionic and Covalent Compounds 62. Estimate the bond angles around the sulfur atom in the structure shown below. A) 90° B) 109.5° C) 120° Ans: B Difficulty: Medium D) 180° 63. What is the molecular shape around the nitrogen atom in the structure shown below? A) Linear B) Bent C) Trigonal planar D) Tetrahedral E) Trigonal pyramidal Ans: B Difficulty: Difficult 64. What is the molecular shape around the oxygen atom in the structure shown below? A) Linear B) Bent C) Trigonal planar D) Tetrahedral E) Trigonal pyramidal Ans: B Difficulty: Difficult 65. Which element may have more than eight valence electrons around it when present in a covalent compound? A) C B) B C) N D) P E) O Ans: D Difficulty: Medium 66. Which molecule or ion has only two resonance structures to describe its bonding? A) CO32– B) NO3– C) HCO31– D) SO3 Ans: C Difficulty: Difficult Page 31 Chapter 3: Ionic and Covalent Compounds 67. Which of the following is classified as a group in the valence shell electron pair repulsion (VSEPR) theory? A) An atom B) A lone pair of electrons C) A valence electron D) Either an atom or a valence electron E) Either an atom or a lone pair of electrons Ans: E Difficulty: Medium 68. Which molecule's Lewis structure contains an atom that violates the octet rule? A) H2O B) BeH2 C) PCl3 D) H2Se Ans: B Difficulty: Difficult 69. Which compound has the greatest number of valence electrons? A) H2S B) CH4 C) NH3 D) H2O E) All of the molecules above have the same number of valence electrons. Ans: E Difficulty: Medium 70. Which atom(s) in the structure below has(have) a partial negative charge (–)? A) Carbon B) Fluorine C) Hydrogen D) Nitrogen E) Nitrogen and fluorine Ans: E Difficulty: Medium 71. How many lone pairs of electrons need to be added to the Lewis structure of carbonic acid shown below? A) 0 B) 3 C) 4 D) 6 Ans: D Difficulty: Medium Page 32 Chapter 3: Ionic and Covalent Compounds 72. What is the total number of bonding electrons in the structure below? A) 5 B) 10 C) 20 D) 30 Ans: C Difficulty: Medium 73. Which Lewis structure is incorrect? A) B) C) D) Ans: B Difficulty: Difficult 74. The Lewis structure shown below is not a valid Lewis structure. What statement best describes the error in the structure? A) B) C) D) Ans: The nitrogen atoms violate the octet rule. The chlorine atoms violate the octet rule. The structure contains an incorrect number of valence electrons. Chlorine atoms and nitrogen atoms do not typically form bonds with each other. C Difficulty: Difficult Page 33 Chapter 3: Ionic and Covalent Compounds 75. Which of the statements concerning compounds is incorrect? A) Compounds are formed when atoms of two or more different elements are chemically bonded. B) Ionic compounds are composed of cations and anions. C) Covalent compounds are composed of metals and nonmetals. D) Covalent compounds are composed of individual molecules. Ans: C Difficulty: Easy 76. Which statement concerning chemical bonds is false? A) A covalent bond involves the sharing of electrons between two nonmetal atoms. B) An ionic bond is the attraction between oppositely charged ions. C) A nonpolar bond is a covalent bond in which electrons are not shared equally between the atoms. D) Electronegativity is a measure of the attraction an atom has for the electrons it shares in a bond. Ans: C Difficulty: Easy 77. Considering the electronegativity values indicated for each element, which covalent bond has the least degree of polarity? C Cl F O N 2.5 3.0 4.0 3.5 3.0 A) C–N B) N–O C) F–F D) H–Cl Ans: C Difficulty: Medium H 2.1 78. The covalent bond between chlorine and iodine is a polar one. Which of the following properly represents the direction of polarity in this bond? A) + Cl–I – B) – Cl–I + C) + Cl–I – D) – Cl–I + Ans: B Difficulty: Medium 79. The Lewis structure of formaldehyde is shown below. Which statement concerning this structure is incorrect? A) B) Two electrons are being shared between the carbon atom and the oxygen atom. The oxygen atom has four valence electrons that are not being shared with another atom. C) The oxygen and carbon atoms each have an octet of electrons in their valence shells. D) The hydrogen atoms have filled valence shells. Ans: A Difficulty: Medium Page 34 Chapter 3: Ionic and Covalent Compounds 80. Anions are formed when a neutral atom gains one or more electrons. A) True B) False Ans: A Difficulty: Easy 81. The (II) in the name of the ionic compound lead (II) acetate specifically indicates that there are two lead ions present in the compound. A) True B) False Ans: B Difficulty: Medium 82. Neutral atoms always contain an equal number of protons, neutrons, and electrons. A) True B) False Ans: B Difficulty: Medium 83. Ionic compounds are composed of individual molecules, discrete groups of atoms that share electrons. A) True B) False Ans: B Difficulty: Easy 84. Ionic compounds are composed of positively and negatively charged ions held together by strong electrostatic forces. A) True B) False Ans: A Difficulty: Easy 85. Bonding is the joining of two atoms in a stable arrangement. A) True B) False Ans: A Difficulty: Easy 86. Ionic bonds result from the sharing of electrons between two atoms. A) True B) False Ans: B Difficulty: Medium 87. A cation is positively charged, and has more electrons than the neutral atom. A) True B) False Ans: B Difficulty: Medium 88. The ionic formula for zinc oxide is ZnO2. A) True B) False Ans: B Difficulty: Medium 89. Ionic compounds have very high melting points compared to covalent compounds. A) True B) False Ans: A Difficulty: Easy Page 35 Chapter 3: Ionic and Covalent Compounds 90. All ionic compounds are soluble in water. A) True B) False Ans: B Difficulty: Easy 91. An ionic compound is a pure substance formed by chemically combining two or more nonmetal atoms together. A) True B) False Ans: B Difficulty: Medium 92. A polyatomic ion is an ion that forms more than one charge. A) True B) False Ans: B Difficulty: Easy 93. The name of an anion usually ends in the -ide if it is derived from a single atom or -ate (or -ite) if it is polyatomic. A) True B) False Ans: A Difficulty: Medium 94. The correct name for CaHPO4 is calcium phosphate. A) True B) False Ans: B Difficulty: Medium 95. The symbol for the nitrite ion is NO2–. A) True B) False Ans: A Difficulty: Medium 96. The noble gas that has the same electronic configuration as the iodide ion is krypton. A) True B) False Ans: B Difficulty: Medium 97. Elements in group 2A form ions with a +2 charge. A) True B) False Ans: A Difficulty: Easy 98. Ionic compounds are usually solids at room temperature. A) True B) False Ans: A Difficulty: Easy 99. The formula for copper (II) hydroxide is Cu(OH)2. A) True B) False Ans: A Difficulty: Medium 100. Sodium nitrate and sodium nitrite are two acceptable names for the same compound. A) True B) False Ans: B Difficulty: Medium Page 36 Chapter 3: Ionic and Covalent Compounds 101. Sodium bicarbonate and sodium hydrogen carbonate are two acceptable names for the same compound. A) True B) False Ans: A Difficulty: Medium 102. The sulfite ion contains more oxygen atoms than the sulfate ion. A) True B) False Ans: B Difficulty: Medium 103. The carbonate ion contains the same number of oxygen atoms as the sulfate ion. A) True B) False Ans: B Difficulty: Medium 104. The electron configuration for the sulfide ion is 1s22s22p63s23p64s2. A) True B) False Ans: B Difficulty: Difficult 105. If the main group element has an electron-dot symbol of ion will be +2. A) True B) False Ans: A Difficulty: Medium 106. If the main group element has an electron-dot symbol of ion will be –2. A) True B) False Ans: A Difficulty: Medium 107. All polyatomic ions are anions. A) True B) False Ans: B Difficulty: Easy 108. All isotopes of an element form the same type of ion. A) True B) False Ans: A Difficulty: Medium 109. All p block elements form ions. A) True B) False Ans: B Difficulty: Difficult 110. The ion symbol for the ferric ion is Fe2+. A) True B) False Ans: B Difficulty: Medium Page 37 , the charge of the resulting , the charge of the resulting Chapter 3: Ionic and Covalent Compounds 111. An iron (III) ion has 29 protons and 26 electrons. A) True B) False Ans: B Difficulty: Medium 112. An iodide ion has 53 protons and 54 electrons. A) True B) False Ans: A Difficulty: Medium 113. Strontium and barium form ions with the same charge. A) True B) False Ans: A Difficulty: Easy 114. Potassium sulfide has the chemical formula K2S. A) True B) False Ans: A Difficulty: Medium 115. In crystal of an ionic compound, the cations are surrounded by anions so that the charges of the ions are balanced. A) True B) False Ans: A Difficulty: Easy 116. The formula for stannic fluoride is SnF4. A) True B) False Ans: A Difficulty: Medium 117. The chemical formulas of ionic compounds are written with the cation first, and then the anion, with subscripts to show how many of each are needed to have zero net charge. A) True B) False Ans: A Difficulty: Easy 118. A main group element is especially stable when it possesses eight total electrons. A) True B) False Ans: B Difficulty: Medium 119. When magnesium forms an ion it gains two electrons. A) True B) False Ans: B Difficulty: Medium 120. When forming an ion, an atom with the electron-dot symbol of a –3 charge by the loss of three electrons. A) True B) False Ans: B Difficulty: Medium Page 38 forms an anion with Chapter 3: Ionic and Covalent Compounds 121. A molecule is a discrete group of atoms held together by covalent bonds. A) True B) False Ans: A Difficulty: Easy 122. A Lewis structure shows the connectivity between atoms in a molecule, as well as where all the bonding and nonbonding valence electrons reside. A) True B) False Ans: A Difficulty: Medium 123. Bonding is the joining of two atoms in a stable arrangement. A) True B) False Ans: A Difficulty: Easy 124. Atoms with three valence electrons generally form five bonds. A) True B) False Ans: B Difficulty: Medium 125. Atoms with seven valence electrons typically form one covalent bond. A) True B) False Ans: A Difficulty: Medium 126. Every atom must have an octet of electrons in order for a Lewis structure to be considered valid. A) True B) False Ans: B Difficulty: Medium 127. Phosphorus usually forms two covalent bonds in a molecule. A) True B) False Ans: B Difficulty: Medium 128. A double bond consists of four electrons shared between two atoms. A) True B) False Ans: A Difficulty: Easy 129. The Lewis structure for BH3 contains an atom that does not follow the octet rule. A) True B) False Ans: A Difficulty: Medium 130. The Lewis structure for PH3 contains an atom that does not follow the octet rule. A) True B) False Ans: B Difficulty: Medium Page 39 Chapter 3: Ionic and Covalent Compounds 131. Resonance structures for a substance differ only in the location of multiple bonds and the position of lone electron pairs. A) True B) False Ans: A Difficulty: Medium 132. There can be no more than two resonance structures for a molecule. A) True B) False Ans: B Difficulty: Medium 133. The correct name for SF6 is sulfur heptafluoride. A) True B) False Ans: B Difficulty: Easy 134. The formula for dinitrogen pentoxide is N5O2. A) True B) False Ans: B Difficulty: Easy 135. A bond formed between the elements hydrogen and bromine would be considered an ionic bond. A) True B) False Ans: B Difficulty: Easy 136. Unequal sharing of electrons in a covalent bond results in a polar bond. A) True B) False Ans: A Difficulty: Easy 137. Nonpolar molecules may contain polar bonds. A) True B) False Ans: A Difficulty: Medium 138. Some covalent compounds are solids, some are liquids, and some are gases at room temperature. A) True B) False Ans: A Difficulty: Easy 139. C–H bonds are considered to be nonpolar, because the electronegativity difference between carbon and hydrogen is small. A) True B) False Ans: A Difficulty: Medium 140. The symbol – is given to the more electronegative atom in a polar bond. A) True B) False Ans: A Difficulty: Medium Page 40 Chapter 3: Ionic and Covalent Compounds 141. The structures shown below are resonance structures of sulfur dioxide. and A) True B) False Ans: A Difficulty: Medium 142. The structures shown below are resonance structures of sulfur dioxide. and A) True B) False Ans: B Difficulty: Medium 143. In the valence shell electron pair repulsion (VSEPR) theory, a group is defined as an atom or a lone pair of electrons. A) True B) False Ans: A Difficulty: Medium 144. A molecule that contains only one polar bond is a polar molecule. A) True B) False Ans: A Difficulty: Easy 145. Ethane (C2H6) is a polar molecule. A) True B) False Ans: B Difficulty: Medium 146. A resonance hybrid is a composite of all resonance structures that spreads out electron pairs in multiple bonds and lone pairs. A) True B) False Ans: A Difficulty: Medium 147. A bond between a carbon atom and a nitrogen atom is a polar covalent bond. A) True B) False Ans: A Difficulty: Medium 148. The molecule below is a polar molecule. A) True B) False Ans: A Difficulty: Medium Page 41 Chapter 3: Ionic and Covalent Compounds 149. Double bonds and triple bonds are never polar bonds. A) True B) False Ans: B Difficulty: Difficult 150. A N–O bond is more polar than a P–O bond. A) True B) False Ans: B Difficulty: Medium 151. The molecule below is a polar molecule. A) True B) False Ans: A Difficulty: Medium 152. The shape around each carbon atom in the molecule below is trigonal planar. A) True B) False Ans: B Difficulty: Medium 153. The Lewis structure for the molecule below is incomplete because it is missing six pairs of nonbonding electrons. A) True B) False Ans: A Difficulty: Medium 154. The shapes around the left and right carbon atoms in the structure below are tetrahedral and linear, respectively. A) True B) False Ans: B Difficulty: Medium 155. A double bond is counted as two groups in the valence shell electron pair repulsion (VSEPR) theory. A) True B) False Ans: B Difficulty: Medium Page 42 Chapter 3: Ionic and Covalent Compounds 156. Dibromomethane (CH2Br2) is a nonpolar molecule. A) True B) False Ans: B Difficulty: Difficult 157. When writing Lewis structures, the symbol below is placed between resonance structures. A) True B) False Ans: B Difficulty: Easy 158. The molecular shape around the boron atom in BCl3 is different than the molecular shape around the nitrogen atom in NCl3. A) True B) False Ans: A Difficulty: Difficult 159. In Lewis structures, fluorine atoms generally do not obey the octet rule. A) True B) False Ans: B Difficulty: Easy 160. The electrons in the outermost occupied shell of an atom are called the _____ electrons. Ans: valence Difficulty: Easy 161. The _____ rule states that a main group element is especially stable when it possesses eight electrons in its outer shell. Ans: octet Difficulty: Easy 162. The chemical formula for iron (III) bicarbonate is _____. Ans: Fe(HCO3)3 Difficulty: Difficult 163. The formula for the ammonium ion is _____. Ans: NH4+ Difficulty: Medium 164. The electron configuration of the oxide ion is _____. Ans: 1s22s22p6 Difficulty: Difficult 165. The Ca2+ ion contains _____ protons. Ans: 20 or twenty Difficulty: Medium Page 43 Chapter 3: Ionic and Covalent Compounds 166. In bonding, main group elements gain, lose, or share electrons to attain the _____ of the nearest noble gas neighbor to them in the periodic table. Ans: electron configuration Difficulty: Medium 167. In general, a _____ bond will be one in which the electronegativity difference between two atoms is 0.5 units or greater. Ans: polar Difficulty: Medium 168. Electronegativity _____ down a column of the periodic table as the atomic radius increases. Ans: decreases Difficulty: Easy 169. In the Lewis structure of a molecule, oxygen atoms typically have _____ lone pair(s) of electrons. Ans: two or 2 Difficulty: Easy 170. Aspartic acid is an amino acid used to synthesize proteins. There are _____ atoms with a trigonal planar geometry in the aspartic acid structure shown here. Ans: two or 2 Difficulty: Difficult 171. The chemical formula for phosphorus pentachloride is _____. Ans: PCl5 Difficulty: Easy 172. Carbon tetrachloride has _____ valence electrons. Ans: thirty-two or 32 Difficulty: Medium 173. To represent the three-dimensional geometry of a tetrahedron on a two-dimensional piece of paper, a solid line is used for the two bonds in the plane of the paper; a _____ is used to show a bond that extends in front of the plane; and a _____ is used to show a bond that extends behind the plane. Ans: wedge, dashed line Difficulty: Easy Page 44