Equilibrium of Fluids A fluid can support no shearing stress when in equilibrium. The stress for compression is simply the pressure. If there are no external forces (such as gravity), the pressure is the same everywhere in the fluid when the fluid is in equilibrium. 1. Gravity on fluids When dealing with a fluid, we no longer have point masses. Forces such as gravity act on fluid elements which are the same as volume elements. This leads to the idea of a body force (force per volume). For gravity, this becomes: f = ρg = -ρg y , where ρ is the mass per volume, dm/dV. Newton’s 2nd law becomes (with P being the pressure): Fx = +Pleft dAleft - Pright dAright = 0 Fz = +Pin dAin – Pout dAout = 0 Fy = +Pbottom dAbottom – Ptop dAtop -ρg dV = 0 . The volume element can be written as: dV = dx dy dz = dAxz dy , so that, with dAtop = dAbottom = dAxz, we have Pbottom – Ptop = ρg Δy . This can be generalized for a body force to be: P2 – P1 = ΔP = r2 r1 f • dr , or f = P . Note that the constant pressure lines (actually surfaces) are perpendicular to the body force, f. Also, since P = 0, we have f = 0, which allows us to have: P(r) – Po = r ro f dr which is similar to a potential energy. 2. Bulk Modulus The Bulk Modulus, B, is defined as: B = stress/ strain, where stress is simply the pressure, P; and strain is ΔV/V : B = PV/ΔV, so we have -dV/V = dP/B. The minus sign comes from converting the ΔV into a dV, but noting that the ΔV is a decrease in the volume, not an increase. Let’s now consider density, ρ = m/V. The quantity dρ is dρ = d(m/V) = m d(1/V) = m d(1/V)/dV dV = m (-1/V2) dV, so that the quantity dρ/ρ becomes: dρ/ρ = m (-1/V2) dV / (m/V) = -dV/V . Note that whenever dV increases, dρ decreases, and when dV decreases, dρ increases. Hence the difference in the sign. Putting -dV/V = dP/B together with dρ/ρ = -dV/V gives: dρ/ρ = dP/B , and integrating both sides gives: ln [ρ/ρo] = PoP (1/B) dP , or ρ = ρo exp [PoP (1/B) dP ] . 3. Three special cases Case 1: incompressible fluid If we have a fluid that is incompressible (B ≈ ∞), then ρ ≈ constant, so using Pbottom – Ptop = ρg Δy we have: Pbottom = Ptop + ρgh , where h = height (or depth) of the fluid. Numerical example If we assume that water is incompressible with a density of 1.0 gr/cc = 1,000 kg/m3, then the pressure at a depth of 100 meters would be ΔP = Pbottom - Ptop = ρgh = (1 x 103 kg/m3) (9.8 m/s2) (100 m) = 9.8 x 105 Nt/m2 . At this depth with this pressure, with the actual finite value of the bulk modulus of water being 2.1 x 109 Nt/m2, water would be compressed by: B = PV/ΔV, or ΔV/V = P/B = 9.8 x 105 Nt/m2 / 2.1 x 109 Nt/m2 = .000467 which says that the water would be compressed to only about 0.05% at that depth. In this case, our approximation of constant density holds up well. If we change the depth to 8 kilometers (about the depth of the deepest ocean trench), then ΔP = (1 x 103 kg/m3) (9.8 m/s2) (8,000 m) = 7.84 x 107 Nt/m2 , and ΔV/V = P/B = 7.84 x 107 Nt/m2 / 2.1 x 109 Nt/m2 = .037 (about 4%). Case 2: Bulk modulus is constant Here we consider the case where the bulk modulus is a constant, independent of pressure and density. In this case, the density equation gives: ρ = ρo exp [PoP 1/B) dP ] = ρo exp [P/B – Po/B] . The pressure equation gives us: Pbottom – Ptop = ρg Δy , or dP = ρg dy = ρo exp{P/B – Po/B} g dy = ρo eP/B e-Po/B g dy. We can separate this equation to get: e-P/B dP = ρo e-Po/B g dy , or P Po e-P/B dP = yo y ρo e-Po/B g dy and with yo = 0 (measured from the surface) and Po = atmospheric pressure (at the surface), we have upon integration: (-B) e-P/B – (-B)e-Po./B = ρo e-Po/B g y , or e-P/B = e-Po./B [1 - ρo g y/B] , or P = -B ln{ e-Po/B [1 - ρogy/B] } . Check: if y = 0, then P = -B ln{ e-Po./B } = Po as required. Check: if P/B is small, then the equation above, e-P/B = e-Po./B [1 - ρo g y/B] simplified using the approximation that e-x ≈ (1 – x) to get: 1 – P/B ≈ (1 - Po/B) [1 - ρo g y/B] can be , or P = Po + ρo g y + terms of order (P/B) . Numerical example Let’s consider the pressure at the deepest part of the ocean, y = 8,000 meters. With Po = Patmospher = 1.01 x 105 Nt/m2 and B = 2.1 x 109 Nt/m2, so that Po/B = 4.81 x 10-5, we get P = -B ln{ e-Po./B [1 - ρogy/B] } = - (2.1 x 109 Nt/m2) ln{ e-4.81 x 10^-5 [1 – (1 x 103 kg)(9.8 m/s2)(8,000 m)/(2.1 x 109) } = 8.00 x 107 Nt./m2 . Note that this is about 2% larger than the value we obtained by considering the water to be incompressible (7.84 x 107 Nt/m2 ). Case 3: Ideal gas at constant Temperature For an ideal gas, we have the ideal gas law: PV = nRT where n is the number of moles, R is the gas constant (R = 8.3 J/mole-K), and T is the temperature (in an absolute scale such as Kelvin). This relates the volume to the pressure, and hence the density to the pressure: ρ = m/V = m / {nRT/P} = Pm/nRT . The m is the mass, and n is the number of moles. We can combine these two to get the mass per mole, M = m/n, so the ρ = PM/RT . We can now use this in the relation for pressure: dP = ρg dy = (PM/RT)g dy . This can be separated and integrated to give: P Po (1/P)dP = yo y (Mg/RT) dy , or ln {P/Po} = Mgy/RT , or P = Po e(Mg/RT)y . The above has y as the “depth” where P increases. To make it into a height (where P decreases), we must put in a negative sign for the y: P = Po e-(Mg/RT)y . Numerical Example Let’s consider the air pressure above the earth’s surface. If we assume that air is incompressible, how high up would the atmosphere extend? From measurements, we have: Pat surface = Patmospheric = 1.01 x 105 Nt/m2, ρo = 1.2 kg/m3, we are assuming Ptop = 0. ΔP = Psurface – Ptop = Patmosphere – 0 = 1.01 x 105 Nt/m2 = ρgh = (1.2 kg/m3)(9.8 m/s2)h , or h = 8,588 meters. Let’s now see what the ideal gas model at constant temperature will predict for the atmosphere: We will start by assuming that air consists of ¾ N2 and ¼ O2 for an average mass per mole, M, of 29 grams/mole, or .029 kg/mole. We will also assume a constant temperature of 32oF (or 273 Kelvin). Since the prediction for an ideal gas is for an exponential decrease in pressure as we increase height, there will be no finite distance at which the pressure will reach zero. Instead, let’s see what the pressure would be when the height is 8,588 meters (the cut-off for the atmosphere in the incompressible prediction): P = Po e-(Mg/RT)y = 1.01 x 105 Nt/m2 * exp{-(.029 kg/mole * 9.8 m/s2 )/(8.3 J/mole-K * 273 K) 8,588 m} = 3.44 x 104 Mt/m2 = .341 Patmosphere .