Biofiltration Technology Overview Biofiltration Systems Overview Biofiltration is a low-cost and highly effective air pollution control (APC) technology that can significantly decrease capital and long-term operating costs compared to conventional competitive technologies such as carbon filtration or oxidation. Proven commercially in Europe since the early 1990’s, biofiltration has been used successfully to control a number of air contaminants such as noxious odors, Volatile Organic Compounds (VOCs), and Hazardous Air Pollutants (HAPs) stemming from a wide range of industrial and public sector sources. Consistent control efficiencies of greater than 90% have been achieved by TRG Biofilter for many common air pollutants and up to 99.9% for H2S emitted from POTWs. In biofiltration, the polluted effluent air is passed through an all-natural, biologically active filter, or biofilter. Naturally occurring microorganisms in the biofilter convert the air pollutants into harmless by-products that are primarily carbon dioxide (CO2) and water (H2O). Biofiltration is based on a process that occurs naturally in soils and water and thus represents a safe, environmentally friendly "green" technology. The biofilter itself is non-hazardous and remains so. There are no hazardous by-products that need to be addressed. In competing, conventional technologies like carbon, absorption recycling and disposal typically are ongoing, increasing the costs of operation. This fact makes biofiltration a more cost-effective solution for air pollution control applications. Process Description Microorganisms live in a bed of biofilter packing material consisting of a mixture of rocks, compost, activated sludge, or other hard support material that avoids long-term compaction problems. The bed is housed in an open or an enclosed vessel ranging in size from small 1,000 gallon tanks to large buildings. A blower is used to move the air through the biofilter, and an air dispersion system ensures evenly distributed flow in the bed. High moisture is constantly maintained in the biofilter bed. The ideal operating temperature is 15ºC to 43ºC (59ºF to 110ºF). The microorganisms exist in a biofilm, or biologically active water film, located on the bed materials. Biofilters require moisture, nutrients, and enough energy to move air across the biofilter bed. Usually the head loss across a biofilter bed is only one to two inches of water. As the contaminated air passes through the bed, the contaminants make contact with the microorganisms in the biofilm and are consumed, much as people consume food for energy. As a result of this metabolism, harmless carbon dioxide (CO2) and water (H2O) are released, and the microorganisms in the biofilm thrive and are regenerated. Economics The startup costs for biofiltration are comparable to those for more conventional air pollution control technologies such as carbon adsorption and incineration, yet ongoing operating and maintenance costs are substantially lower. As a result, with the correct air pollution control applications, biofiltration becomes the clear economical choice over the life cycle of the air pollution control system. For example, with biofiltration, there are no long-term costs associated with recycling air pollutants, as there are in carbon filtration. There are no external fuel costs such as those associated with thermal oxidation technologies, where such costs are ongoing and increase with the cost of inflation. Controlling the costs of such unknowns must be considered when selecting competing technologies. Therefore, from a pure economic comparison, biofiltration is clearly superior, especially for high flow rates streams with low concentrations of pollutants. Biofiltration becomes more economical than carbon adsorption or oxidation when airflow rates are high and VOC pollutant concentrations are under 3000 PPM, which is a typical toxicity limit for the biomass. Most biofilters operate at VOC concentrations of 1000 PPM and below. Biofiltration is also superior from an environmental or "green" point of view. It consumes very little energy. Its all-natural and organic technology does not accumulate any residual toxic wastes, as does carbon adsorption, nor emit any NOx as oxidizers or incinerators do. Odorous air pollutants emitted at a fish processing plant in Baja California, Mexico. Applications Biofiltration is ideally suited for the treatment of volatile organic and odorous compounds in air resulting from a wide range of manufacturing operations or from organic decomposition, including H2S. The simplest compounds to treat are hydrocarbon molecules, ranging from alcohols and ketones to the heavy molecules found in JP-4 and JP-5 jet fuels. Fluorocarbons can also be treated, depending on type. Animal Feed Houses Baking Chemical Processing Composting Fiberboard Production Fish Procesing Food Production Meatpacking Metalworking Municipal Waste Paints & Coatings Petroleum Refining Pharmaceuticals Pulp & Paper Mills Printing Rubber Productions Soil Vapor Extraction Wastewater Treatment Biofiltration Technology While biofiltration looks simple on the surface, it is in fact a complex bio-mechanical system, which requires specialized knowledge and technology for efficient, long-term performance. Applying years of experience and state-of-the-art technical advancements, TRG Biofilter’s 7th generation products are unmatched worldwide for efficient and trouble-free long-term performance. TRG's modern line of biofilters resolve a number of challenges that thwart other biofilters. They overcome challenging conditions including the presence of acidic media that can terminate the activity of the microorganisms, channelization that can allow air streams to pass through the biofilter bed untreated, and compaction that can block the passage of the air streams across the biomass. In conjunction with its academic partners, TRG Biofilter has developed mathematical modeling tools to optimize the design of biofilters to meet specified throughput and efficiency objectives, plus remote monitoring tools to facilitate maintenance and optimize performance. TRG Biofilter’s measuring devices for determining the performance of the biofilter are the most advanced in the world. TRG Biofilter’s early applications include treating gasoline vapors from a soil extraction site, treating ethanol, MEK and MIBK from manufacturing sites, and treating JP-4 jet fuel vapors at a United States Air Force base. Most recently, TRG Biofilter won recognition and funding from the California Air Resource Board (CARB) for its large-scale and highly efficient air biofiltration system at the Ojai Valley Sanitary District (CA), a wastewater treatment facility (also referred to as a publicly owned treatment works or POTW). TRG Biofilter approached this challenge and provided a solution that won CARB approval. The Ojai project involved unique challenges and required a two-stage biofilter. The first stage holds an inert, readily drained, acid-resistant support medium that is capable of operating at low pH to allow the microorganisms to remove hydrogen sulfide gas (H 2S). Removal of the H2S is crucial, as it tends to form sulfuric acid (H2SO4) that can terminate the life of the microorganisms. The second stage uses a biofilter media that is appropriate for a normal pH and provides the environment for microorganisms to remove the remaining voltatile organic compounds (VOCs). TRG Biofilter Turnkey Biofiltration Systems Tel: (714) 730-5397 Fax: (714) 730-6476 250 El Camino Real #204 Tustin, CA 92780, USA E-mail: sales@trgbiofilter.com Contact TRG Biofilter m To TRG Biofilter Home Page Biofiltration Technology Overview Biofiltration Systems Overview Biofiltration is a low-cost and highly effective air pollution control (APC) technology that can significantly decrease capital and long-term operating costs compared to conventional competitive technologies such as carbon filtration or oxidation. Proven commercially in Europe since the early 1990’s, biofiltration has been used successfully to control a number of air contaminants such as noxious odors, Volatile Organic Compounds (VOCs), and Hazardous Air Pollutants (HAPs) stemming from a wide range of industrial and public sector sources. Consistent control efficiencies of greater than 90% have been achieved by TRG Biofilter for many common air pollutants and up to 99.9% for H2S emitted from POTWs. In biofiltration, the polluted effluent air is passed through an all-natural, biologically active filter, or biofilter. Naturally occurring microorganisms in the biofilter convert the air pollutants into harmless by-products that are primarily carbon dioxide (CO2) and water (H2O). Biofiltration is based on a process that occurs naturally in soils and water and thus represents a safe, environmentally friendly "green" technology. The biofilter itself is non-hazardous and remains so. There are no hazardous by-products that need to be addressed. In competing, conventional technologies like carbon, absorption recycling and disposal typically are ongoing, increasing the costs of operation. This fact makes biofiltration a more cost-effective solution for air pollution control applications. Process Description Microorganisms live in a bed of biofilter packing material consisting of a mixture of rocks, compost, activated sludge, or other hard support material that avoids long-term compaction problems. The bed is housed in an open or an enclosed vessel ranging in size from small 1,000 gallon tanks to large buildings. A blower is used to move the air through the biofilter, and an air dispersion system ensures evenly distributed flow in the bed. High moisture is constantly maintained in the biofilter bed. The ideal operating temperature is 15ºC to 43ºC (59ºF to 110ºF). The microorganisms exist in a biofilm, or biologically active water film, located on the bed materials. Biofilters require moisture, nutrients, and enough energy to move air across the biofilter bed. Usually the head loss across a biofilter bed is only one to two inches of water. As the contaminated air passes through the bed, the contaminants make contact with the microorganisms in the biofilm and are consumed, much as people consume food for energy. As a result of this metabolism, harmless carbon dioxide (CO2) and water (H2O) are released, and the microorganisms in the biofilm thrive and are regenerated. Economics The startup costs for biofiltration are comparable to those for more conventional air pollution control technologies such as carbon adsorption and incineration, yet ongoing operating and maintenance costs are substantially lower. As a result, with the correct air pollution control applications, biofiltration becomes the clear economical choice over the life cycle of the air pollution control system. For example, with biofiltration, there are no long-term costs associated with recycling air pollutants, as there are in carbon filtration. There are no external fuel costs such as those associated with thermal oxidation technologies, where such costs are ongoing and increase with the cost of inflation. Controlling the costs of such unknowns must be considered when selecting competing technologies. Therefore, from a pure economic comparison, biofiltration is clearly superior, especially for high flow rates streams with low concentrations of pollutants. Biofiltration becomes more economical than carbon adsorption or oxidation when airflow rates are high and VOC pollutant concentrations are under 3000 PPM, which is a typical toxicity limit for the biomass. Most biofilters operate at VOC concentrations of 1000 PPM and below. Biofiltration is also superior from an environmental or "green" point of view. It consumes very little energy. Its all-natural and organic technology does not accumulate any residual toxic wastes, as does carbon adsorption, nor emit any NOx as oxidizers or incinerators do. Odorous air pollutants emitted at a fish processing plant in Baja California, Mexico. Applications Biofiltration is ideally suited for the treatment of volatile organic and odorous compounds in air resulting from a wide range of manufacturing operations or from organic decomposition, including H2S. The simplest compounds to treat are hydrocarbon molecules, ranging from alcohols and ketones to the heavy molecules found in JP-4 and JP-5 jet fuels. Fluorocarbons can also be treated, depending on type. Animal Feed Houses Baking Chemical Processing Composting Fiberboard Production Fish Procesing Food Production Meatpacking Metalworking Municipal Waste Paints & Coatings Petroleum Refining Pharmaceuticals Pulp & Paper Mills Printing Rubber Productions Soil Vapor Extraction Wastewater Treatment Biofiltration Technology While biofiltration looks simple on the surface, it is in fact a complex bio-mechanical system, which requires specialized knowledge and technology for efficient, long-term performance. Applying years of experience and state-of-the-art technical advancements, TRG Biofilter’s 7th generation products are unmatched worldwide for efficient and trouble-free long-term performance. TRG's modern line of biofilters resolve a number of challenges that thwart other biofilters. They overcome challenging conditions including the presence of acidic media that can terminate the activity of the microorganisms, channelization that can allow air streams to pass through the biofilter bed untreated, and compaction that can block the passage of the air streams across the biomass. In conjunction with its academic partners, TRG Biofilter has developed mathematical modeling tools to optimize the design of biofilters to meet specified throughput and efficiency objectives, plus remote monitoring tools to facilitate maintenance and optimize performance. TRG Biofilter’s measuring devices for determining the performance of the biofilter are the most advanced in the world. TRG Biofilter’s early applications include treating gasoline vapors from a soil extraction site, treating ethanol, MEK and MIBK from manufacturing sites, and treating JP-4 jet fuel vapors at a United States Air Force base. Most recently, TRG Biofilter won recognition and funding from the California Air Resource Board (CARB) for its large-scale and highly efficient air biofiltration system at the Ojai Valley Sanitary District (CA), a wastewater treatment facility (also referred to as a publicly owned treatment works or POTW). TRG Biofilter approached this challenge and provided a solution that won CARB approval. The Ojai project involved unique challenges and required a two-stage biofilter. The first stage holds an inert, readily drained, acid-resistant support medium that is capable of operating at low pH to allow the microorganisms to remove hydrogen sulfide gas (H2S). Removal of the H2S is crucial, as it tends to form sulfuric acid (H2SO4) that can terminate the life of the microorganisms. The second stage uses a biofilter media that is appropriate for a normal pH and provides the environment for microorganisms to remove the remaining voltatile organic compounds (VOCs). TRG Biofilter Turnkey Biofiltration Systems Tel: (714) 730-5397 Fax: (714) 730-6476 250 El Camino Real #204 Tustin, CA 92780, USA E-mail: sales@trgbiofilter.com Contact TRG Biofilter m To TRG Biofilter Home Page Technical Papers on Biofiltration Reproduced with Permission The technical papers listed below will provide an excellent overview of the capabilities of biofiltration in reducing odorous and often toxic air pollutants. TRG Biofilter and its academic associates were involved in all of the papers either as writers or as project managers. Click on any of the titles for the full paper with tables and illustrations. 1. Biofiltration: An Old Technology Comes of Age. Paper by F. Edward Reynolds, Jr. & W. D. Grafton III of TRG Biofilter. Published in Environmental Technology, July/August 1999, pp 51-52. Recent improvements in biofilter technology makes biofiltration air pollution control technology a viable alternative to conventional approaches. Excellent survey paper. 2. Biological Air Pollution Control In North America. Report on the USC-TRG Conference on Biofiltration, October 5-6, 1995, Los Angeles, California. By George Skladany, Gero Leso, Douglas Hodge [Technical Director of The Reynolds Group] An overview of the state of the art of biofiltration in 1995. 3. Modeling of Air Contaminants by Biofiltration. Paper by Douglas S. Hodge, Member ASCE, Director of Bioremediation Services, The Reynolds Group; and Joseph S. Devinny, Associate Member, ASCE, Department of Civil. Engineering, University of Southern California. Published in Journal of Environmental Engineering, Vol. 121, No. 1, January, 1995, by the American Society of Civil Engineers (ASCE). A definitive paper on the quantitative aspects of biofiltration. A mathematical model was developed that describes basic transport and biological processes for a biofilter. The model described transfer between the air and solids/water phases, biological degradation of the substrate, CO2 production and accumulation, and pH changes resulting from CO 2 accumulation. Model equations were solved using a two-step, explicit, finite difference approximation technique, and solutions were tested on simplified problems with known analytical results. Experimental data were compared with the predictive model solutions for steady-state and nonsteady-state regimes. 4. Biofilter Pilot Unit: A Case Study. Section 10 of the Doctoral Thesis of Douglas Hodges at U.S.C. [Technical Director of The Reynolds Group]. Large commercial bakeries can emit several hundred pounds of VOCs per day. The known performance of biofilters for treating ethanol inspired the SCAQMD's Technology and Advancement Office (TAO), Southern California Edison (SCE), and Southern California Gas (SoCalGas) to jointly fund this biofilter pilot demonstration project at a local commercial bakery. 5. Full-Scale Biofilter: A Case Study. Section 11 of the Doctoral Thesis of Douglas Hodges at U.S.C., later Director of Marketing of The Reynolds Group (TRG). A two-story open biofilter was designed to control VOC emissions, mostly ethanol, from an investment casting process that releases VOC into the general working area. Changes to SCAQMD rules, limiting maximum uncontrolled daily emissions to 600 lbs per day, mandated the implementation of some form of VOC control. 6. Biofiltration System to Remove Toxic and Odorous Gases from Wastewater Treatment. From a proposal by TRG Biofilter to the Ojai Valley Sanitary District. Provides excellent overview of biofiltration. Includes technical background and project description; diagram of proposed system; pilot scale emission test results; environmental, technical & economic benefits; previous work by TRG Biofilter; project plans; and references. 7. Clearing the Air Biologically. Paper by Joseph S. Devinny, M.ASCE and Professor of Civil and Environmental Engineering at the University of Southern California. Published in Civil Engineering, September 1998, pp 46-49, by the American Society of Civil Engineers (ASCE). Excellent survey paper with details on the Ojai Valley POTW project, which was designed by TRG Biofilter. Across the country, an increasing number of wastewater treatment plants are enlisting biofiltration to remove odor and hazardous contaminants from air discharges. 8. Treatment of Hydrocarbon Fuel Vapors in Biofilters. Paper by Douglas S. Hodge, Victor F. Medina, Robert L. Islander, and Joseph S. Devinny. Published in Environmental Technology, Vol 12, 1991, pp 655-662. This paper reports on bench testing of biofilters using soil, carbon and diatomaceous earth as support media for treatment of JP-5 jet fuel and diesel fuel vapors. Activated carbon supported higher biodegradation rates than soil, and diatomaceous earth was least effective. Jet fuel was degraded more rapidly than diesel fuel. 9. Biofiltration of JP-4 Jet Fuel Vapors. Paper by Ann N. Chang and Joseph S. Devinny, University of Southern California. Bench scale experiments were conducted to evaluate the effectiveness of biofiltration for treating JP-4 jet fuel vapors from soil vapor extraction. Three biofilter columns were operated, using granular activated carbon, bark compost, and yard waste compost as packing materials. For the yard waste compost biofilter, acclimation was slow and medium compaction occurred, but excellent removal efficiency (>99%) was achieved. 10. Biofilter Treatment of JP-4 Vapors from a Soil Vapor Extraction System. Demonstration Project by TRG Biofilter and Black & Veatch. Excerpts from a proposal by TRG Biofilter to study removal efficiency as a function of concentration and as a function of vapor contact time. 11. Biofilter Performance Report, March Air Force Base. Report prepared by TRG Biofilter for Black & Veatch, Irvine, CA. During the period from August, 1995 to April, 1996, a full scale biofilter was applied to treat jet fuel air vapors that were emitted from an enhanced soil vapor extraction system at March Air Force Base, Site 18. During the testing period, removal efficiencies were measured independently by the University of Southern California as frequently as once per week. Removal efficiencies reached greater than 90%. 12. Final Report on Performance of a Pilot Scale Biofilter for Treatment of MIBK. Report submitted by TRG Biofilter to Metromedia, Los Angeles, CA. Includes analytical results from December 1995 thru January 1996. The report states that a 90% removal efficiency can be achieved with a 93 second air flow residence time. With a residence time of 47 seconds, a removal efficiency of 68% is achieved. 13. TRG Biofiltration Vapor Treatment Systems Overview. From a proposal by TRG Biofilter. This document covers technical fundamentals and presents applicable TRG Biofilter models. TRG Biofilter Turnkey Biofiltration Systems Tel: (714) 730-5397 Fax: (714) 730-6476 m 250 El Camino Real #204 Tustin, CA 92780, USA E-mail: sales@trgbiofilter.com Contact TRG Biofilter http://sfm-1.biology.ualberta.ca/english/pubs/PDF/PR_2000-14.pdf http://www.ch2m.com/bioclean/Portable/Portable.htm http://www.bioreaction.com/