Syllabus for Division of Chemistry and Physics (Ch/Phys) Fourth Year Chemistry Courses First semester Chem 411- Ch/Phys Hours Course Year Syllabus : : : : Lecture (2h) Lab (2h) Physical Chemistry (3) (A,B) Fourth A: Molecular Spectroscopy Introduction Rotational spectra Vibrational spectra Electronic spectra B: Electrochemistry (4) Corrosion Introduction Thermodynamics of corrosion Types of corrosion Pourbaix diagrams Protection against corrosion, cathodic, anodic Inhibition Chem 412- Ch/Phys Hours Course Year Syllabus : : : : Lecture (3h) Lab (3h) Inorganic Chemistry (6) and Analytical Chemistry (5) Fourth Inorganic Chemistry (6) • (A) Radioactive deay, isotopes and isobares, nuclear masses and unclear stability, nuclear spin moments, structure of nuclei, neutron activation and applications in Chemistry. • (B) Chemistry of lanthanides and actinides, separation of elements by ion exchange and solvent extraction techniques. Analytical Chemistry (5) Electro analytical -Methods of Analysis • Principles of electrolysis, Electrodeposition, coulometric methods of analysis, voltarnmetry, polarography and conductometric methods. Potentiometric methods, overview of potentiometric methods, indicator electrodes, ion-selective electrodes direct potentiometry, potentiometric titrations, potentiometric methods involving enzymes. Chem 413- Ch/Phys Hours Course Year Syllabus : : : : Lecture (3h) Lab (3h) Organic chemistry (8, 9) Fourth Organic Chemistry (8) • Electronic spectra – Electronic transitions-Beer's law. Solvents- Chromophores and auxochromes Hyptho and batho Chromic Shifts. • Molecular oribitals of polyenes- Woodward- Fieser rules –Fieser- Kuhnrules of polyenes. • Spectra of α,β- unsaturated carbonyl compounds. • Aromatic hydrocarbons and there spectra, effect of substituents. • IR Spectra – radiation –Molecular vibrations- Vibrationals transitions. • Hook's law- Characteristic bands of functional groups. • Structure frequency correlations – IR spectra of organic families of compounds. • Uses of IR spectra in structure conformational analysis. • Identification of reaction immdeiates and determination of Keto-Enol equilibria. Organic Chemistry (9) • Chemistry of petroleum, Natural gas and Petrochemicals - Composition of petroleum - physical properties and methods of purifications - Crud oil and methods of its treatment - Fractional distillation - Extraction of alkanes Preparation of saturated, unsaturated & aromatic hydrocarbons - important petrochemicals and their preparations - petroleum and petroleum industry in Egypt. Second semester Chem 421- Ch/Phys Hours Course Year Syllabus : : : : Lecture (3h) Lab (3h) Organic chemistry (10, 11) Fourth Organic Chemistry (10) Chemistry of Natural products • Introduction to the chemistry of terpenes: Classification - structural determination - Acyclic monocyclic and bicyclic terpenes and sesqueterpenes and polyterpenps. • Steroids: Nomenclature - Configuration and reactivity- sterols- Bile acids - Sex hormones- Sarponins and sapogenins - Adrenocortisol - Hormones -synthesis of steroids- Biosynthesis. • Alkaloids: Classification- structura illucidation - Some Examples. Organic Chemistry (11) Photochemistry and pericyclic Reactions • Photochemistry: Molecular excitations - Excited states - types of interconversions of excited states -reactions of - Excited states- photo reactions of olefins, dienes and carbonyl compounds • Pericyclic reactions: Molecular orbitals- Frontier molecular orbitals ssymmetry of mo's- Electrocyclic reactions - cycloaddition reactionscheleotropic reactionssigmatropic rearrangements -Fmo methods orpital correlations diagram and state correlation diagrams . Chem 422- Ch/Phys Hours Course Year Syllabus : : : : Lecture (3h) Lab (3h) Inorganic Chemistry (7) & Analytical Chemistry (6) Fourth Inorganic Chemistry (7) • Group theory, molecular symmetry and symmetrical elements, presentation of groups, molecular vibrations, Ligand field theory. Analytical Chemistry (6) Chromatographic Separations and Radiochemical -Methods • Liquid - liquid extraction, extraction of metal-organic complexes, extraction of ion association complexes. Chromatographic separations, general description of chromatography, the rate theory of chromatography, important relationships for chromatography. Principles of gas-liquid chromatography and gas-solid chromatography. High performance liquid chromatography, partition, adsorption, ion-exchange, size exclusion and supercritical- fluid chromatography. Palnar chromatography (paper and thin layer ) . Radiochemical methods, radioactive isotopes, instrumentation, activation methods, isotopic dilution methods and radiometric methods. Chem 423- Ch/Phys Hours Course : : Lecture (2h) Lab (2h) Physical Chemistry (3) (C,D,E,F) Year Syllabus C :Solid : : Fourth state chemistry Classification of solids The crystal lattice Bound theory of solids: Dislocation, defects and impurities The chemistry of solid surface Reaction of solids D: Phase Equilibria Thermodynamics and phase equilibrium One component system Two component systems Determination of phase equilibrium diagrams Hypothetical binary systems Binary systems and phase analysis Ternary systems Non equilibrium phases and reactions Quaternary systems Applications E: Physical Polymer Chemistry The scope of polymer physical science Polymerization: Condensation polymerization, thermodynamics and kinetics Determination of absolute molecular masses F: Statistical thermodynamics Molecular energy levels and Blotzrnan Canonical ensembles Calculation of partition and thermodynamic functions Physics Courses First semester Phys 411- Ch/Phys Hours Course Year Syllabus : : : : Lecture (2h) Lab (2h) Solid State physics (2) Fourth • Electrical properties of solids: free electron theory, Electric conductivity of metals, Structure dependence of resistivity and Matthiessen rule, WiedemannFranz law, Bloch theorem, Koring-Penny model, Band theory: metals, semiconductors and insulators, Temperature dependence of resistivity, Motion in magnetic field: Hall effect, Junctions properties: metal-metal, metalsemiconductor and P-N junctions, Dielectrics, Mechanism of polarization, Piezo-, pyro- and ferro-electric materials, Optical properties of semiconductors and insulators, Exitons, Color of crystals, Photo conductivity. Phys 412- Ch/Phys Hours Course Year Syllabus • Lecture (2h) Lab (2h) Nuclear physics (2) Fourth Nuclear reactions, Reaction cross sections, Induced reactions: proton, alpha, neutron and deuteron, Compound nucleus theory and its limitations, Reactions with light nuclear and their energy levels, Theory of nuclear fission: fission cross sections and thresholds, Mass and energy distributions of fission products, Neutron emission, Acceleration of Charged particles, Cochcroft – Walton machine, Van de Graaff machine, Cyclotron , Synchrocyclotron, Acceleration of electrons, Proton synchrotron, Lincar accelerators, Alternating – gradicnt synchrotron . Phys 413- Ch/Phys Hours Course Year Syllabus • : : : : : : : : Lecture (2h) Lab (2h) Physical electronics (2) Fourth Pulse technique: parameter, generation, Mono and bitable multivibrator, Operational amplifier and applications, Multivibration circuit ( flip – flop ), Summing amplifier, Phase shifter, Basic logic circuits, Digital electronics, conversion : D/A and A/D converter, Analog multiplexes . Phys 414- Ch/Phys Hours Course Year Syllabus • : : : : Lecture (2h) Lab (2h) Low temperature Fourth Production of low temperatures, Hydrogen and helium liquefiers – Liquefied gases: storage, transfer, Heat exchangers: construction, calculations, Temperature measurement, Cryostat: design, heat transfer, temperature control, Vacuum techniques, Superconductivity phenomena. Chem/Phys 411- Ch/Phys Hours Course Year Syllabus : : : : Lecture (2h) Research Essay Forth Second semester Phys 421- Ch/Phys Hours Course Year Syllabus • Lecture (2h) Metal physics Fourth Lab (2h) Structure of metals and close packed arrangement, Types and structure of alloys, Equilibrium diagrams: solid state reactions, Kinetics of phase changes, Diffusion in metals and alloys, order disorder changes in alloys, Theory of plasticity, material testing, Strengthening mechanisms, heat treatment: recrystallization, grain growth. Phys 422- Ch/Phys Hours Course Year Syllabus • : : : : : : : : Lecture (2h) Solar energy Fourth Lab (2h) Heat transfer, Radiation laws, Absorptivity, Reflectivity, Transitivity, Characteristic of solar spectrum, Solar constant, Rayleigh theory, Sky radiationEnergy balance equation, Solar cells: single crystal, polycrystalline, amorphous, Photovoltaic system : modules, panels, arrays, Solar selective coating : static and dynamic, Characterization performers, Flat plate collectors, Focusing collectors, Concentrators, Thermal performers, Storage of solar energy . Phys 423- Ch/Phys Hours Course Year Syllabus : : : : Lecture (2h) Lab (2h) Laser and its applications Fourth • Basics of coherence theory, electromagnetic wave in an optical cavity, propagation of electromagnetic wave in a thick, thin and medium with inversion population, three and four energy level system, active medium in a resonator and condition, properties of laser beam, some types of laser sources, kinds of resonators modes and their kinds, laser material interaction. Phy 424 - Ch/Phys Hours Course Year Syllabus : : : : Lecture (2h) Special course Fourth Lab (2h) To be specified by the Physics Department Chem/Phys 421- Ch/Phys Hours Course Year Syllabus : : : : Lecture (2h) Research Essay Forth