Resistivity and Temperature Dependence of Resistivity Introduction The resistance of a resistor depends on the geometry of the resistor and the resistivity of the material. For a resistor whose cross sectional area does not vary significantly, its resistance, R, can be calculated as follows: [1] R = ρL/A L = length A = cross sectional area = πd2/4 for a circle ρ = resistivity Resistivity is primarily a function of the material. Materials vary in their order at the atomic level and conduction-electron density, among other things. The resistivity of a material varies a bit with temperature. This variation can be simplified to a linear function for a reasonable temperature range as follows: [2] ρ = ρo[1 + α(T – To)] ρo = resistivity at temperature of To ρ = resistivity at temperature of T α = temperature coefficient of resistivity The temperature coefficient of resistivity is positive for most substances, so resistivity increases with temperature. Higher temperature corresponds to higher translational kinetic energy per particle in a substance. Higher translational kinetic energy per particle corresponds to higher root mean squared speed. Higher root mean squared speed increases the likelihood of a collision between a free electron and a particle. Another effect of increasing temperature is that the conduction-electron density can increase, thus decreasing the resistivity in substances where this effect dominates. Semiconductors exhibit this behavior, though we will not investigate this in lab. Using the above two equations, the temperature dependence of resistance can be derived as follows: [3] [4] [5] [6] R0 = ρ0L/A (resistance at temperature T0) R = ρL/A (resistance at temperature T) R = ρ0[1 + α(T – To)]L/A (equation [2] in [4]) R = R0[1 + α(T – To)] (equation [3] in [5]) Substance Resistivity (ρ) at 20°C (Ωm) Temperature Coefficient of Resistivity (°C-1) Copper 1.72E-8 0.0039 Nichrome 1.10E-6 0.0004 Copper has a low resistivity due to its high conduction electron density and ordered structure. Nichrome has a high resistivity for a metal due to the high resistivity of nickel and chromium plus the disorder created by the mixing of the two materials. Wire Gauge Diameter (mm) 28 0.321 ± 0.001 30 0.255 ± 0.001 32 0.202 ± 0.001 34 0.160 ± 0.001 36 0.127 ± 0.001 38 0.101 ± 0.001 Experimental Procedure Resistivity at Room Temperature 1) 2) 3) 4) 5) 6) 7) 8) Measure the resistance of the ohmmeter and probes by connecting the two probes. Measure or use a given value for the length of a piece of wire. Measure or use the above table for the diameter of the wire. Measure the resistance of the wire with the digital multi-meter configured as an ohmmeter. Make good contact with the wire by pressing firmly to either the ends of the wire for the nichrome or the bolts in the PVC for the copper. Subtract the value obtained in step 1 from the value obtained in step 4. Solve equation [1] for resistivity and calculate your experimental value. Scientifically compare your experimental value for resistivity to the theoretical value in the first table. Repeat steps 2 through 7 with 7 other wires. Use a variety of lengths, wire gauges, and materials. The temperature dependence of resistance 1) Set aside all of your data except for the resistance of the ohmmeter and probes. Don’t even be tempted to look at it or use it in this part of the experiment. 2) Place a beaker of water on the hot plate. 3) Plug in the hot plate and turn it to “HI”. 4) Fill a second beaker with ice water. 5) Place your highest resistance copper wire in the ice water. Leave the ends of the wire sticking out of the ice water. 6) Measure the resistance of the wire every minute or so (make firm contact with the probes) until you obtain a fairly constant value. Subtract the resistance of the ohmmeter and probes from your last measurement. Record this as R0. 7) Use your knowledge of physics to infer the temperature of the ice water and hence the temperature of the wire, T0. 8) Place the wire in the hot water. Leave the ends of the wire sticking out of the hot water. 9) Wait for the water to come to a boil, and then turn down the hot plate to simmer. 10) Measure the resistance of the wire every minute or so (make firm contact with the probes) until you obtain a fairly constant value. Subtract the resistance of the ohmmeter and probes from your last measurement. Record this as R. 11) Use your knowledge of physics to infer the temperature of the boiling water and hence the temperature of the wire, T. 12) Solve equation [6] for the temperature coefficient of resistivity (α) and calculate your experimental value based on To in ice water and T in boiling water. Don’t forget to subtract the resistance of the ohmmeter and probes from measured values for When calculating alpha, do not use any data obtained in the room temperature experiment except for the resistance of the ohmmeter and probes. resistance. 13) Scientifically compare your single experimental value for temperature coefficient of resistivity to the theoretical value. 14) Repeat steps 5 through 13 for your highest resistance nichrome wire. When calculating alpha, do not use any data obtained in the room temperature experiment except for the resistance of the ohmmeter and probes. 15) Re-read and obey the above sentence in gigantic bold font. If you disobey those instructions, you risk a zero on your report.