(http://web.nchu.edu.tw/pweb/users/wtluh) Some mathematical relations [Appendix C/p. 1015] Derivatives: (d/dx)(yz) = y(dz/dx) + z(dy/dx) df(y)/dx = [df(y)/dy](dy/dx) d(sin x)/dx = cos x dey/dx = ey(dy/dx) d(ln y)/dx = (1/y)(dy/dx) Integrals: [definite integrals/p. 43] xn dx = xn+1/(n + 1) + I eax dx = (1/a) eax + I (ln ax) dx = x(ln ax) - x + I Partial derivatives: f(x,y) --- a function of more than one variable df = (f/x)ydx + (f/y)xdy If x, y and z are mutually dependent, like P, V, and T, then we have (a) (f/x)z = (f/x)y + (f/y)x(y/x)z (b) (x/y)z = 1/[(y/x)z] (c) (x/y)z = -(x/z)y(z/y)x Eulers chain relation: (x/y)z(y/z)x(z/x)y = -1 (d) df = g(x,y)dx + h(x,y)dy is an exact differential if (g/y)x = (h/x)y If df is exact, then its integral between specified limits is independent of the path. Thermodynamical concepts, U, H, A, and G follow this behavior. Differential equations b(dy/dx) + cy = 0: a first-order differential equation a(d2y/dx2) + b(dy/dx) + c y =0 : a second-order differential equation a, b, and c may be functions of x Solution: y = f(x) a general solution a particular solution: which follows initial or boundary conditions --1--a(dx/x) + bydy = 0, a and b are constants a(dx/x) + bydy = 0 a ln x + b(y2/2) = I --2--dy/dx = axy rearranged: dy/y = axdx integrated: ln y = (1/2)ax2 + A : a general solution initial condition: y = y0 when x = 0 --> A = ln y0 we have a particular solution: ln y = (1/2)ax2 + ln y0 or y = y0exp[ax2/2] --3--dy/dt + ay = b; y(t=0) = 0 Use an integrating factor: exp[adt] = exp[at] (dy/dt)exp[at] + ay exp[at] = b exp[at] d{y exp[at]}/dt = b exp[at] y exp[at] = (b/a) {exp[at] - 1} y = (b/a) {1 - exp[-at]} useful for describing the kinetics of consecutive reactions --4--2y/t2 = a(2y/x2): a partial differential equation solved through a separation of variables procedure by setting y = T(t)X(x)