Differential algebraic description for third and fifth order aberrations of electromagnetic lenses Zhixiong Liu* Department of Electronics, Peking University,Beijing 100871, China Abstract In this paper the modern map method has been applied to the third and fifth order aberration analysis of electromagnetic lenses, focusing on the high order. It has also been emphasized that there exist three types of differential algebraic (DA) descriptions for electron optical aberrations. The numerical results of third and fifth order aberrations of a given electromagnetic lens computed through the DA technique are in excellent agreement with those evaluated by using the electron optical aberration integrals. In conclusion, the DA technique is concise, efficient, and precise for electron optical aberration analysis and COSY INFINITY has been proved to be an excellent computer code for such purposes. PACS: 41.85.-p; 41.85.Gy; 41.85.NE Keywords: Differential algebra; Map method; Electromagnetic lens; aberration Corresponding author: E-mail: zxliu@pku.edu.cn Fax: +86-10-6275-1762 1 1. Introduction In the previous work [1] it has been pointed out that there exist three types of DA descriptions for aberration analysis of electron optical rotationally symmetric systems. The main reason for this is that a rotating coordinate frame is always used for such systems in order to simplify the analytical expression of the paraxial trajectory equation and, as a result, the aberration is expanded in rotating coordinates and must be corrected by the object magnetic immersion (OMI) effect when the object is immersed in the lens magnetic field. Although the way developed in that work is suitable for aberration analysis through arbitrary order, the DA description in rotating coordinates for aberrations higher than third order becomes quite complicated. Therefore, in the present work the general electron trajectory equation expressed in rotating coordinates has been derived and the transfer map in rotating coordinates obtained by tracking this equation will be simplified considerably. The numerical calculation of third and fifth order aberrations of a given combined electromagnetic lens was carried out by using the two completely different methods, the DA technique and aberration integrals in electron optics, in order to make a cross-check with each other. The results were extremely consistent. It comes to conclusion that the DA descriptions for electron optical aberration analysis is very concise, efficient, and precise and that COSY INFINITY [2,3] is an excellent computer code for such purposes. In addition, the DA description in rotating coordinates derived in this work is superior to the previous one [1] in simplicity with high precision remaining unchanged. 2. General electron trajectory equation in rotating coordinates In electron optics the general electron trajectory equation is usually expressed in a fixed coordinate frame [4,5], X Y 2 ( 2 X 2 ( 2 Y X Y 2 ) ( BY Y Bt ) , Z 2 ) ( BX X Bt ) , Z (1) e 1 , 1 X 2 Y 2 , Bt ( BZ X BX Y BY ) , 2m where the uppercase letters, X , Y , and Z , indicate the fixed coordinates in this context. By using Eq. (1) and the rotating transform of coordinates [4,5] in electron 2 optics, we can switch Eq. (1) to another form of the trajectory equation, x 2 y 2 x y 2 2 [ ( x y ) ] [ by ( y x)bt ] , 2 x z y 2 x 2 y x 2 2 [ ( y x) ] [ bx ( x y )bt ] , 2 y z 1 ( x y ) 2 ( y x) 2 , bt 1 (2) [bz ( x y )bx ( y x)by ] . where the lowercase letters, x, y, and z imply the corresponding rotating coordinates, and b are the potential and magnetic induction depending on x, y, and z , and is the rotating angle of the rotating coordinate frame. Although Eq. (2) becomes more complicated than Eq. (1), it will clearly be seen later that it does take an important role in simplifying the DA description in rotating coordinates. 3. Three types of DA description for third and fifth order aberrations The DA description in fixed coordinates is produced by tracking Eq. (1) through a DA integrator from the object plane zo to the image plane zi . For third and fifth order aberrations we have X 3 i Y3i X 5 i Y5i k l m n 3 M (1, klmn) X ok X o'lYomYo'n , f k ,l , m , n 0 ,1, 2 , 3 k l m n 3 M f k ,l , m , n 0 ,1, 2 , 3 (3, klmn) X ok X o'lYomYo'n , (3) k l m n 5 M f k ,l , m , n 0 ,1,..., 5 k o 'l m 'n o o o (1, klmn) X X Y Y , k l m n 5 M f k ,l , m , n 0 ,1,..., 5 (3, klmn) X ok X o'lYomYo'n , while the DA description in rotating coordinates is obtained by tracking Eq. (2) and hve the form of x3i y3i x5i y5i k l m n 3 M r k ,l , m , n 0 ,1, 2 , 3 (1, klmn) xok xo'l yom yo'n , k l m n 3 M r k ,l , m , n 0 ,1, 2 , 3 (3, klmn) xok xo'l yom yo'n , (4) k l m n 5 M r k ,l , m , n 0 ,1,..., 5 k o 'l o m o 'n o (1, klmn) x x y y , k l m n 5 M r k ,l , m , n 0 ,1,..., 5 (3, klmn) xok xo'l yom yo'n . 3 In Eqs. (3) and (4) M f (i, klmn) and M r (i, klmn) for i 1 or 3 are the third and fifth order transfer map elements in fixed and rotating coordinates, respectively, the number of order depending on the sum of k , l , m, and n . Since the expansion of the third order aberration is known in the textbooks on electron optics, we only write the expansion of the fifth order one below, * r5i (ro ro) 2 ( A5 ro a5 ro* ) (ro ro) 2 ( B51ro b51ro ) * (ro ro)( ro ro )( B52ro b52ro* ) (ro ro)( ro ro )(C51ro c51ro ) (ro ro)( ro ro )(C52ro c52ro* ) (ro ro ) 2 (C53ro c53ro* ) * * (ro ro)( ro ro )( D51ro d 51ro ) (ro ro ) 2 ( D52ro d 52ro ) * (ro ro )( ro ro )( D53ro d 53ro* ) (ro ro )( ro ro )( E51ro e51ro ) * (ro ro ) 2 ( E52ro e52ro* ) (ro ro ) 2 ( F5 ro f 5 ro ) , * ro ( xo , yo ) , ro ( xo , yo ) , ro ( yo , xo ) , ro* ( yo , xo ) , (5) In comparison of Eq. (4) with these expansions of third and fifth order aberrations, the relationships between the map elements and aberration coefficients can be established. The total number of relationships is 2 20 40 for the third order aberration and 2 56 112 for the fifth order one. Among them the simplest set of relationships has been chosen. Third order aberration coefficients in Glaser’s notation are B M r (1,0300) , F M r (1,1002) , C M r (1,1011) / 2 , D M r (1,0120) , E M r (1,3000) , f M r (3,1002) / 3 , c M r (3,1011) / 2 , e M r (3,3000) ; (6) and the fifth order aberration coefficients in Eq. (5) are A5 M r (1,0500) , B51 M r (1,1004) , B52 M r (1,0311) , C51 M r (1,1013) , C52 M r (1,0320) , C53 M r (1,0122) C52 , D51 M r (1,3002) , D52 M r (1,1022) D51 , D53 M r (1,0131) , E51 M r (1,3011) , E52 M r (1,0140) , F5 M r (1,5000) , a5 M r (3,0500) , b51 M r (3,1004) , b52 M r (3,0311) , c51 M r (3,1013) , c52 M r (3,0320) , c53 M r (3,0122) c52 , d 51 M r (3,3002) , d 52 M r (3,1022) d 51 , d 53 M r (3,0131) , e51 M r (3,3011) , e52 M r (3,0140) , f 5 M r (3,5000) . 4 (7) The DA description in hybrid coordinates takes the form of x3mi y3mi x5 mi y5 mi k l m n 3 M h k,l,m,n 0 ,1, 2 , 3 k l m n 3 M h k,l,m,n 0 ,1, 2 , 3 k l m n 5 M h k,l,m,n 0 ,1,..., 3 k l m n 5 M h k,l,m,n 0 ,1,..., 3 (1, klmn) X ok X olYomYon , (3, klmn) X ok X olYomYon , (8) (1, klmn) X X o Y Y , k o l m n o o (3, klmn) X ok X olYomYon , where suffix " m " in aberration coefficients signifies that the aberrations have been corrected by the OMI effect [1,6], M h (1,klmn) and M h (3,klmn) are the transfer map elements in hybrid coordinates, which can be derived from M f (1,klmn) and M f (3,klmn) . As a result, the simplest set of relationships between the zmap elements in hybrid coordinates and the third and fifth order aberration coefficients with the inclusion of the OMI effect has been found. Third order isotropic aberration coefficients: Bm M h (1,0300) M f (1,0300) cos i M f (3,0300) sin i , Fm M h (1,1002) M f (1,1002) cos i M f (3,1002) sin i , Cm M h (1,1011) [ M f (1,1011) cos i M f (3,1011) sin i ]/2 , (9) Dm M h (1,0120) M f (1,0120) cos i M f (3,0120) sin i , Em M h (1,3000) M f (1,3000) cos i M f (3,3000) sin i ; Third order anisotropic aberration coefficients: f m M h (3,1002) [ M f (3,1002) cos i M f (1,1002) sin i ]/3 , cm M h (3,1011) [ M f (3,1011) cos i M f (1,1011) sin i ]/2 , (10) em M h (3,3000) M f (3,3000) cos i M f (1,3000) sin i ; Fifth order isotropic aberration coefficients: A5 m M h (1,0500) M f (1,0500)co s i M f (3,0500)si n i , B51m M h (1,1004) M f (1,1004)co s i M f (3,1004)si n i , B52m M h (1,0311) M f (1,0311)co s i M f (3,0311)si n i , C51m M h (1,1013) M f (1,1013)co s i M f (3,1013)si n i , C52m M h (1,0320) M f (1,0320)co s i M f (3,0320)si n i , C53m M h (1,0122) - C52m M f (1,0122)co s i M f (3,0122)si n i C52m , 5 (11) D51m M h ( 1 , 3 0 02M) f ( 1 , 3 0 0 2s) icoM f ( 3 , 3 0 0 2n)i s, i D52m M h ( 1 , 1 0 2- 2D51 ) m M f ( 1 , 1 0 2 2s) icoM f ( 3 , 1 0 2 2n)i s- iD51m , D53m M h ( 1 , 0 1 31M) f ( 1 , 0 1 3 1s) icoM f ( 3 , 0 1 3 1n)i s, i (12) E51m M h ( 1 , 3 0 11M) f ( 1 , 3 0 1 1s) icoM f ( 3 , 3 0 1 1n)i s, i E52m M h ( 1 , 0 1 40M) f ( 1 , 0 1 4 0s) icoM f ( 3 , 0 1 4 0n)i s, i F5 m M h ( 1 , 5 0 00M) f ( 1 , 5 0 0 0s) icoM f ( 3 , 5 0 0 0n)i s; i Fifth order anisotropic aberration coefficients: a5 m M h (3,0500) M f (3,0500)co s i M f (1,0500)si n i , b51m M h (3,1004) M f (3,1004)co s i M f (1,1004)si n i , b52m M h (3,0311) M f (3,0311)co s i M f (1,0311)si n i , (13) c51m M h (3,1013) M f (3,1013)co s i M f (1,1013)si n i , c52m M h (3,0320) M f (3,0320)co s i M f (1,0320)si n i , c53m M h (3,0122) - c52m M f (3,0122)cos i M f (1,0122)si n i c52m , d 51m M h (3,3002) M f (3,0300) cos i M f (1,3002) sin i , d 52m M h (3,1022) d 51m M f (3,1022) cos i M f (1,1022) sin i - d 51m , d 53m M h (3,0131) M f (3,0131) cos i M f (1,0131) sin i , (14) e51m M h (3,3011) M f (3,3011) cos i M f (1,3011) sin i , e52m M h (3,0140) M f (3,0140) cos i M f (1,0140) sin i , f 5 m M h (3,5000) M f (3,5000) cos i M f (1,5000) sin i ; 4. Fifth order aberrations of electromagnetic lenses in electron optics The basic idea of the derivation of the fifth order aberration coefficients is the same as that in references [7,8]. In the present work, however, the forms of the aberration integrals are somewhat different. According to Eq. (5) there are 12 isotropic (uppercase letters) and 12 anisotropic (lowercase letters) aberration coefficients: (spherical aberration), aberration), A5 , a5 B51 , B52 , b51 , b52 (coma), C51 , C52 , C53 , c51 , c52 , c53 (peanut D51 , D52 , D53 , d51 , d52 , d53 (elliptical coma), E51 , E52 , e51 , e52 (astigmatism and field curvature), and F5 , f 5 (distortion) [9], each of which includes both intrinsic and combined components. In order to save space we will not list all fifth order aberration integrals here, but they are available at request. What should be emphasized is that they have been proved to be correct because the aberration coefficients calculated through these analytical expressions have been cross-checked with those computed through the DA technique (see the next section). Nevertheless, 6 following the guidelines in reference [6], the OMI correction formulas of fifth order aberration coefficients are given here, A5 m A5 , B51m B51 5 o a5 , B52m B52 4 o a5 , C51m C51 o (4b51 3b52 ) 4 o A5 , 2 C52m C52 4 ob51 1 0 o2 A5 , C53m C53 2 ob52 4 o2 A5 , D51m D51 3 oc52 6 o2 B51 1 0 o3 a5 , D52m D52 o (2c51 c53 ) 2 o2 (2 B51 B52 ) - 4 o3 a5 , (15) D53m D53 2 o (c51 c53 ) 3 o2 B52 - 4 o3 a5 , E51m E51 o (2d 51 d 53 ) o2 (C51 2C52 ) o3 (4b51 b52 ) 4 o4 A5 , E52m E52 2 o d 51 3 o2C52 4 o3b51 5 o4 A5 , F5 m F5 oe52 o2 D51 o3c52 o4 B51 o5 a5 ; a5 m a5 , b51m b51 5 o A5 , b52m b52 4 o A5 , c51m c51 o (4 B51 3B52 ) 4 o a5 , 2 c52m c52 4 o B51 10 o2 a5 , c53m c53 2 o B52 4 o2 a5 , d 51m d 51 3 oC52 6 o2b51 10 o3 A5 , d 52m d 52 o (2C51 C53 ) 2 o2 (2b51 b52 ) 4 o3 A5 , (16) d 53m d 53 2 o (C51 C52 ) 3 o2b52 4 o3 A5 , e51m e51 o (2 D51 D53 ) o2 (c51 2c52 ) o3 (4 B51 B52 ) 4 o4 a5 , e52m e52 2 o D51 3 o2 c52 4 o3 B51 5 o4 a5 , f 5 m f 5 o E52 o2 d 51 o3C52 o4b51 o5 A5 . 5. Computational illustration The analytical model of the combined bell-shaped electromagnetic lens [10] was chosen, whose axial potential and magnetic induction distributions have the form of z V ( z ) V0 e x pk(a r c t a n) , a k z B0 e x p ( a r c t a n) 2 a . B( z ) 2 z 1 2 a (17) For numerical computation the lens parameters were V0 100 V, k 0.5 , a=0.05 m, and B0 0.01 T, and the object was properly positioned so that magnification was equal to -1000. The programs were written in COSY INFINITY [11]. The trajectory 7 equations, Eqs. (1) and (2), were tracked by using an eighth order Runge-Kutta integrator [12] to produce the transfer map in fixed and rotating coordinates, respectively. Then, all the third and fifth order aberration coefficients were calculated in terms of Eqs. (6-7) (without the inclusion of the OMI effect) and Eqs. (9-14) (with the inclusion of the OMI effect) for the given electromagnetic lens. A cross-check of these coefficients was made with those evaluated by using the third and fifth order aberration integrals and Mathematica [13] at the same condition. All the numerical results are shown in Tables 1 for the third order aberration coefficients and Tables 2-5 for the fifth order aberration coefficients. 6. Discussion and conclusion In section 2 it is very evident that the general electron trajectory equation in rotating coordinates, Eq. (2), has not been made simple by the rotating transform of coordinates. The equations are still coupled with one another, so it is out of use in electron optics. The simple form of the paraxial trajectory equation can be derived directly from the general trajectory equation in fixed coordinates [4,5]. However, Eq. (2) does become most important in the DA technique because it makes the DA description in rotating coordinates not only very simple, but easy to be extended to higher order aberrations (compare Eqs. (6-7 with Eqs. (8-9) in reference [1]). Obviously, the DA description developed in this paper is superior to that in the previous work [1]. As is shown in references [14,15], the present work has also proved that the DA technique is very concise, efficient, and precise for electron optical aberration analysis. Tables 1-5 have demonstrated that the numerical results computed through the DA technique are in excellent agreement with those calculated by using electron optical aberration integrals for the third and fifth order aberrations. It is confident that the same precision can be obtained for higher order aberration analysis and the DA technique will be extensively applied to electron optics. Acknowledgements The author is very grateful for Professor M. Berz to provide COSY INFINITY 8.1 for this work. 8 References [1] Z. Liu, The Seventh International Computational Accelerator Physics, Michigan State University, East Lansing, MI 48824, USA, October 22-25, 2002. [2] M. Berz, Nucl. Instr. and Meth. A 298 (1990) 473. [3] K. Makino, M. Berz, Nucl. Instr. and Meth. A 427 (1999) 338. [4] P.W. Hawkes, E. Kasper, Principles of Electron Optics, Academic Press, London, 1989. [5] J. Ximen, Aberration Theory in Electron and Ion Optics, Adv. in Electronics and Electron Phys. Supplement 17, Academic Press, New York, 1986. [6] J. Ximen, Z. Liu, Optik, 111 (2000) 355. [7] M. Wu, Acta Phys. Sinica, 13 (1957) 181. [8] P.W. Hawkes, Phil. Trans. A 257 (1965) 523. [9] Z. Liu, Nucl. Instr. and Meth. A 488 (2002) 42. [10] J. Ximen, Z. Liu, Optik, 111 (2000) 75. [11] M. Berz. COSY INFINITY Version 8, User's Guide and Reference Manual, Technical Report MSUCL-1173, National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, 2000. [12] B. Hartmann, M. Berz. H. Wollnik, Nucl. Instr. and Meth. A 297 (1990) 343. [13] S. Wolfram, The MATHEMATICA book, Third edition, Cambridge University Press, Cambridge, 1996. [14] L. Wang, T. Tang, B. Cheng, J. Cai, Optik, 110 (1999) 408. [15] M. Cheng, T. Tang, Z. Yao, Optik, 112 (2001) 250. 9 Table 1 Third order aberration coefficients without and with the inclusion of the object magnetic immersion effect for a combined bell-shaped electromagnetic lens with B0 0.01 T, V0 100 V, a 0.05 m, and K 0.5 and under the magnification of -1000. Note: The value in the second column is chosen as the criterion in the relative error. --------------------------------------------------------------------------------------------------------Aberr. coeff. DA technique Aberr. integral Relative error --------------------------------------------------------------------------------------------------------B (m) 2.85456035214 10 -1 2.85456035210 10 -1 1.235 10 11 F 8.25795388659 8.25795378007 1.290 10 8 C (m -1 ) 2.37432784958 10 2 2.37432785020 10 2 -2.616 10 10 D (m -1 ) 2.71994620417 10 2 2.71994620479 10 2 -2.286 10 10 E ( m -2 ) 7.63653380978 10 3 7.63653380975 10 3 3.453 10 12 f 6.49587925428 10 -1 6.49587925425 10 -1 4.701 } 10 12 c (m -1 ) 3.48851564964 101 3.48851564963 101 2.182 10 12 e ( m -2 ) 5.95569993408 10 2 5.95569993406 10 2 3.803 10 12 B m (m) 2.85456035214 10 -1 2.85456035210 10 -1 1.235 10 11 Fm 8.25795388659 8.25795378007 1.290 10 8 C m (m -1 ) 2.38466506135 10 2 2.38466506197 10 2 -2.609 10 10 D m (m -1 ) 2.68893456886 10 2 2.68893456948 10 2 -2.301 10 10 E m ( m -2 ) 7.60940292147 10 3 7.60940292134 10 3 1.772 10 11 fm 3.56205732871 10 -1 3.56205732872 10 -1 c m (m -1 ) 1.79106573203 101 1.79106575391 101 e m ( m -2 ) 3.17771580676 10 2 3.17771580610 10 2 10 -2.252 10 12 -1.222 10 8 2.068 10 10 Table 2 Fifth order isotropic aberration coefficients without the inclusion of the object magnetic immersion effect for a combined bell-shaped electromagnetic lens under the same conditions as those in Table 1. --------------------------------------------------------------------------------------------------------Aberr. coeff. DA technique Aberr. integral Relative error --------------------------------------------------------------------------------------------------------2.213 10 8 A5 (m) 4.11524978819 4.11524969711 B51 1.17392977649 10 2 1.17392979463 10 2 -1.545 10 8 B52 5.12551884960 10 2 5.12551888575 10 2 -7.053 10 9 C51 (m -1 ) 1.45629574927 10 4 1.45630343531 10 4 -5.278 10 6 C52 (m -1 ) 8.29257364254 10 3 8.29261191267 10 3 -4.615 10 6 C53 (m -1 ) 1.56399264890 104 1.56399266852 104 -1.254 10 8 D51 ( m -2 ) 2.34517151844 10 5 2.34517151695 10 5 6.353 10 10 D52 ( m -2 ) 4.42630983925 10 5 4.42630983684 10 5 5.445 10 10 D53 ( m -2 ) 4.98640409322 10 5 4.98642487358 10 5 -4.167 10 6 E51 ( m -3 ) 1.40423272443 107 1.40423214128 107 4.153 10 7 E52 ( m -3 ) 3.91684999270 10 6 3.91684871207 10 6 F5 ( m -4 ) 1.09746204513 108 1.09746204599 108 11 3.270 10 7 -7.836 10 10 Table 3 Fifth order anisotropic aberration coefficients without the inclusion of the object magnetic immersion effect for a combined bell-shaped electromagnetic lens under the same conditions as those in Table 1. --------------------------------------------------------------------------------------------------------Aberr. coeff. DA technique Aberr. integral Relative error --------------------------------------------------------------------------------------------------------- a5 (m) 1.85428793710 10 -1 1.85428793712 10 -1 -1.079 10 11 b51 4.32709988901 101 4.32709984297 101 1.064 10 8 b52 -1.02433684537 101 -1.02433681910 101 2.565 10 8 c51 (m -1 ) 4.23204041645 10 3 4.23204611502 10 3 -1.347 10 6 c52 (m -1 ) -5.19729347955 10 2 -5.19729348120 10 2 -3.175 10 10 c53 (m -1 ) -1.29834906864 10 3 -1.29834909761 10 3 -2.231 10 8 d 51 ( m -2 ) 5.36807062376 104 5.36808655466 104 -2.968 10 6 d 52 ( m -2 ) 9.67804447458 104 9.67804536999 104 -9.252 10 8 d 53 ( m -2 ) -6.21228596368 104 -6.21228730784 104 -2.164 10 7 e51 ( m -3 ) 2.26018791456 10 6 2.26018791478 10 6 -9.734 10 11 e52 ( m -3 ) -6.48270015136 10 5 -6.48270014473 10 5 1.023 10 9 f 5 ( m -4 ) 1.17037727110 107 1.17037593832 107 1.139 10 6 12 Table 4 Fifth order isotropic aberration coefficients with the inclusion of the object magnetic immersion effect for a combined bell-shaped electromagnetic lens under the same conditions as those in Table 1. --------------------------------------------------------------------------------------------------------Aberr coeff. DA technique Aberr integral Relative error --------------------------------------------------------------------------------------------------------2.213 10 8 A 5m (m) 4.11524978819 4.11524969711 B51m 1.18345865298 102 1.18345867112 102 -1.533 10 8 B52m 5.11789574840 102 5.11789578456 102 7.065 10 9 C51m ( m-1 ) 1.46918762494 104 1.46919531091 104 C52m ( m-1 ) 8.15815324433 10 3 8.15819151539 10 3 -4.691 10 6 C53m ( m-1 ) 1.56435942500 104 1.56435944461 104 -1.253 10 8 D51m ( m -2 ) 2.33660699683 10 5 2.33660699545 10 5 D52m ( m -2 ) 4.48416046488 10 5 4.48416057916 10 5 D53m ( m -2 ) 4.92633057337 10 5 4.92635123671 10 5 -4.194 10 6 E51m ( m -3 ) 1.40868442909 107 1.40868387734 107 3.917 10 7 E52m ( m -3 ) 3.83262100944 10 6 3.83261952262 10 6 3.879 10 7 F5 m ( m -4 ) 1.09327222645 108 1.09327222732 108 13 -5.231 10 6 5.887 10 10 -2.548 10 8 -7.967 10 10 Table 5 Fifth order anisotropic aberration coefficients with the inclusion of the object magnetic immersion effect for a combined bell-shaped electromagnetic lens under the same conditions as those in Table 1. --------------------------------------------------------------------------------------------------------Aberr coeff. DA technique Aberr integral Relative error --------------------------------------------------------------------------------------------------------am (m) 1.85428793710 10 -1 1.85428793712 10 -1 -1.079 10 11 b51m 2.21234164808 101 2.21234164886 101 -3.504 10 10 b52m 6.67469747375 6.67469736192 c51m ( m-1 ) 2.16829539214 10 3 2.16830107210 10 3 -2.620 10 6 c52m ( m-1 ) -3.51603069621 101 -3.51602996698 101 2.074 10 7 c53m ( m-1 ) -2.45565079762 102 -2.45565101297 102 -8.770 10 8 d 51m ( m -2 ) 2.83417818669 104 2.83418231757 104 -1.458 10 6 d 52m ( m -2 ) 5.06282873816 104 5.06281381460 104 2.948 10 6 d 53m ( m -2 ) -1.51571440920 104 -1.51569208785 104 1.473 10 5 e51m ( m -3 ) 1.27014537030 10 6 1.27014324111 10 6 1.676 10 6 1.675 10 8 e52m ( m -3 ) -1.67348360027 10 5 -1.67348359663 10 5 2.174 10 9 f 5m ( m -4 ) 7.72590894110 10 6 7.72589705622 10 6 1.538 10 6 14