CHAPTER 04 1. CALCULATOR USE FOR SCIENTIFIC NOTATION • PUT INTO SCIENTIFIC NOTATION ______ TO GET ANSWERS IN SCI NOT • PUT INTO ________ MODE TO GET DECIMAL NUMBERS 2. TI-83 PLUS MODE BUTTON AND ARROW KEYS 3. TI-83 CHANGING MODES • PRESS “_____” KEY, THEN USE ARROW KEYS TO HIGHLIGHT “____”, THEN PRESS “ENTER” 4. TI-83 EXITING MODES • PRESS “2ND” THEN “_____”, WHICH IS SAME KEY AS “_____” KEY 5. TI-30X CHANGING MODES • PRESS 2ND BUTTON, THEN PRESS ________ BUTTON • USE ARROW KEYS TO HIGHLIGHT “____” 6. TI-83 ENTERING NUMBERS IN SCI NOT • ENTER ___________ • PRESS “2ND”, THEN “___” NOT “_____”, THEN ENTER EXPONENT 7. TI-83 SCREEN VIEW • “E” REPRESENTS “______” • NUMBER AFTER “E” IS ________ 1 CHAPTER 04 8. TI-30X ENTERING NUMBERS IN SCI NOT • ENTER ______________ • PRESS “2ND”, THEN “____” NOT “X 10”, THEN ENTER EXPONENT 9. TI-30X SCREEN VIEW • “E” REPRESENTS “_____” • NUMBER AFTER “E” IS _______ 10. ENTERING NEGATIVE EXPONENTS • PRESS ________________ KEY JUST BEFORE ENTERING EXPONENT 11. NEGATIVE EXPONENT SCREEN VIEW • NOTE NEGATIVE SIGN BEFORE EXPONENT 2 CHAPTER 04 3 12. SCI NOT MATH EXAMPLES • DO NOT NEED TO ENTER PARENTHESES • (2.4 x 105) + (5.8 x 104)= ? • (9.3 x 107) (5.1 x 102) = ? • (8.5 x 10-5) / (2.7 x 10-3) = ? • (4.6 x 10-3) - (3.1 x 10-4) = ? 13. FACTOR LABEL • A METHOD OF CHANGING ______ (LABELS) BY MULTIPLYING BY A CONVERSION _______ • ALIGN UNWANTED UNITS DIAGONALLY SO THEY _______ 14. CONVERSION EXAMPLE • CONVERT 55 MILES TO km • • • • THIS ARRANGEMENT CANCELS MILES AND LEAVES KILOMETERS PER HOUR ANSWER IS _______ UNITS MUST ACCOMPANY ANSWER! 15. CONVERSION EXAMPLE CONTINUED • TABLE BELOW SHOWS ANOTHER WAY TO SET THIS UP (NOTICE RED DIAGONAL UNITS WILL CANCEL) • UNITS DETERMINE NUMBER PLACEMENT! • MULTIPLY LIKE FRACTIONS TO GET ANSWER 55 miles 1.609 km 1 mile 16. CONV. EXAMPLE 2 • CONVERT 20 FEET TO METERS • _____________ • ANSWER IS _____ • TABLE FORM SHOWN BELOW (DIAGONAL UNITS CANCEL) 20 ft 1 m 3.3 ft CHAPTER 04 17. CONV. EXAMPLE 3 • CONVERT 15,250 INCHES TO METERS • ________ • ANSWER IS ___ • TABLE FORM SHOWN BELOW (NOTICE HOW DIAGONAL UNITS CANCEL 15,250 in 1 ft 1m 12 in 3.3 ft 18. CONV. EXAMPLE 4 • CONVERT 2350 SECONDS TO HOURS • ______ • ANSWER IS ____ 2350 s 1 min 1 h 60 s 60 min 19. COLLECTIVE UNITS • MEAN A SPECIFIC NUMBER • PAIR = • QUARTET = • DOZEN = • 1 MOLE = = _____ – CALLED ______________ NUMBER 20. MOLE-PARTICLE CONVERSIONS • USE 1 MOLE = 6.02 x 1023 AS A CONVERSION FACTOR 21. MOLE-PARTICLE EXAMPLES • HOW MANY ATOMS IN 2.3 MOLES OF HELIUM? • HOW MANY MOLECULES IN 4.7 MOLES OF O2? • HOW MANY MOLES IN 5.9 x 1025 ATOMS OF ARGON? • HOW MANY MOLES IN 3.7 x 1030 MOLECULES OF Cl2? 22. ATOMIC MASS REVIEW • WEIGHTED AVERAGE _____ OF THE NATURALLY OCCURING ISOTOPES OF AN ELEMENT • UNITS ARE _____ • FOUND ON THE PERIODIC TABLE • ROUND OFF TO MATCH DATA IN PROBLEM, IF NO DATA, USE __ DECIMAL PLACE 4 CHAPTER 04 23. WHAT IS THE ATOMIC MASS OF… • H • Li • O • Na • Cu • Cl 24. MOLAR MASS • THE MASS OF ________ OF A SUBSTANCE • SAME NUMBER AS ATOMIC MASS, BUT UNIT IS _____ 25. WHAT IS THE MOLAR MASS OF… • He • Mg • S • K • Cr • Br 26. MOLAR MASS OF A COMPOUND • H2O IS MADE OF 2 ATOMS OF H AND 1 ATOM OF O • CALCULATE THE MOLAR MASS BY _______ 27. FIND THE MOLAR MASS OF… • MgCl2 • CaCrO4 • Al2(SO4)3 • Ga2(CO3)3 28. MASS TO MOLES • USE FACTOR-LABEL CONVERSION • INCLUDE SUBSTANCE AS PART OF THE UNIT • CONVERSION FACTOR IS MOLAR MASS OF SUBSTANCE Given in grams 1 mole Molar mass in grams 5 CHAPTER 04 6 29. MASS TO MOLES EXAMPLES • HOW MANY MOLES IS 15.0 g OF CARBON? • HOW MANY MOLES IS 250.0 g OF IRON? 30. MOLES TO MASS • REVERSE THE PROCESS 31. MOLES TO MASS EXAMPLES • WHAT IS THE MASS OF 3.2 MOLES OF LEAD? • WHAT IS THE MASS FO 0.8 MOLES OF COPPER? 32. HOW ABOUT COMPOUNDS • USE THE SAME PROCESS, BUT USE THE MOLAR MASS OF THE COMPOUND IN THE CONVERSION FACTOR 33. MASS OF COMPOUNDS TO MOLES EXAMPLES • HOW MANY MOLES IS 20.5 g OF WATER? • HOW MANY MOLES IS 42.8 g OF NaCl? 34. MOLES OF COMPOUNDS TO MASS EXAMPLES • WHAT IS THE MASS OF 6.4 MOLES OF WATER? • WHAT IS THE MASS OF 0.75 MOLES OF KBr? 35. STANDARD CONDITIONS FOR GASES • ___ ATMOSPHERE OF PRESSURE • ____ FOR TEMPERATURE • TOGETHER THESE ARE CALLED STANDARD TEMPERATURE AND PRESSURE • ABBREVIATION IS ___ 36. STANDARD MOLAR VOLUME • 1 MOLE OF GAS OCCUPIES _____ L AT STP • 1 MOLE = _____ L IS A CONVERSION FACTOR FOR ALL GASES 37. MASS-VOLUME PROBLEMS • USE THE MOLAR VOLUME TO CALCULATE THE VOLUME OF GAS IN REACTIONS AT STP 38. MOLAR VOLUME EXAMPLE • WHAT IS THE VOLUME OF 32.4 MOLES OF H2? CHAPTER 04 39. SOLUTION COMPOSITION • HAS TWO PARTS: _________ AND ___________ • AMOUNT OF SOLUTE IS ______ • DILUTE MEANS _______ SOLUTE • CONCENTRATED MEANS _____ OF SOLUTE • QUANTIFIED BY CONCENTRATION UNITS 40. MOLARITY • UNIT OF CONCENTRATION • _______ OF SOLUTE PER _______ OF SOLUTION • VOLUME OF SOLUTION ≠ VOLUME OF SOLVENT • UNIT IS ___ FOR MOLAR • C = _____ 41. CONCENTRATION EXAMPLES • WHAT IS THE CONCENTRATION OF – 1.25 L OF SOLUTION CONTAINING 20.0 g OF CaCl2 AS THE SOLUTE? – 500 mL OF SOLUTION CONTAINING 15.0 g of NaOH? 42. MORE CONC. EXAMPLES • HOW MANY MOLES OF SOLUTE ARE IN – 325 mL OF 0.1 M KNO3? – 1.5 L OF 0.4 M NaCl? 43. EVEN MORE CONC. EXAMPLES • WHAT VOLUME OF 0.5 M BaBr2 SOLUTION CONTAINS 0.25 MOLES OF SOLUTE? • WHAT VOLUME OF 0.8 M Mg(OH)2 SOLUTION CONTAINS 0.5 MOLES OF SOLUTE? 44. CONVERSION REVIEW 7 CHAPTER 04 45. TWO STEP CONVERSION EXAMPLES • HOW MANY MOLECULES ARE IN 25.0 g OF SODIUM? • WHAT IS THE VOLUME OF 100.0 g OF O2? • WHAT MASS OF SOLUTE IS IN 25 mL OF 0.1 M KOH? 46. PERCENT COMPOSITION • MASS OF AN _________ / MASS OF __________ • THIS GIVES A DECIMAL THAT IS CONVERTED TO PERCENT 47. PERCENT COMPOSITION FROM FORMULA • ASSUME 1 ______ • DETERMINE MOLAR MASS OF EACH CONSTITUENT • MULTIPLY BY SUBSCRIPTS • DIVIDE BY MOLAR MASS OF COMPOUND 48. PERCENT COMPOSITION EXAMPLE • FIND PERCENT COMPOSITION OF – Al2O3 – MgC2O4 49. EMPIRICAL FORMULA FROM PERCENT COMPOSITION • ASSUME _____ g OF COMPOUND • CHANGE PERCENTS TO MASS • FIND MOLES OF EACH ELEMENT • FIND SMALLEST RATIO OF MOLES • USE AS SUBSCRIPTS 50. EMPIRICAL EXAMPLES • FIND EMPIRICAL FORMULAS – 17.09% Mg, 37.39% Al, 44.98% O – 26.57% K, 35.36% Cr, 38.07% O 51. EMPIRICAL FORMULA FROM MASS DATA • CONVERT MASS TO MOLES • FOLLOW PREVIOUS STEPS FOR FORMULA FROM PERCENT COMPOSITION 8 CHAPTER 04 9 52. MORE EMPIRICAL EXAMPLES • FIND EMPIRICAL FORMULAS – 88 g OF COMPOUND CONTAINS 24 g OF CARBON, REMAINING IS OXYGEN – 0.2636 g OF PURE Ni REACTS WITH OXYGEN, FINAL MASS OF NICKEL OXIDE IS 0.3354 g 53. MOLECULAR FORMULAS • MOLECULAR FORMULA = ____________ • n = (MOLAR MASS OF COMPOUND) / (MASS OF EMPIRICAL FORMULA) 54. MOLECULAR EXAMPLES • FIND MOLECULAR FORMULAS – 65.2% ARSENIC, 34.8% OXYGEN, MOLAR MASS IS 459.6 g – 71.65% Cl, 24.27% C, AND 4.07% H, MOLAR MASS IS 98.96 g 55. HYDRATE • A SUBSTANCE THAT HAS ________ CHEMICALLY ATTACHED • A _____ SYMBOLIZES THE CHEMICAL BOND (NOT A MULTIPLICATION SIGN) • A ____________ INDICATES THE NUMBER OF WATER MOLECULES ATTACHED TO EACH FORMULA UNIT 56. HYDRATE EXAMPLES • CuSO4 5H2O • Na2CO3 10H2O 57. HYDRATE COMPONENTS • WATER OF ____________ – THE WATER ATTACHED TO THE HYDRATE • OFTEN CAN BE REMOVED BY _______ • ___________________ – COMPOUND LEFT AFTER WATER OF HYDRATION REMOVED 58. DEHYDRATING A HYDRATE CHAPTER 04 59. EMPIRICAL FORMULA OF HYDRATE • NEED MASS OF HYDRATE AND MASS OF ANHYDROUS SALT (AFTER HEATING) • MASS OF WATER = MASS OF ________ - MASS OF _________ • CALCULATE MOLES OF ANHYDROUS SALT AND WATER OF HYDRATION • MAKE RATIO AND SIMPLIFY TO SMALLEST WHOLE NUMBERS • SHOULD BE 1 TO SOMETHING 60. HYDRATE EXAMPLE • MASS OF HYDRATE IS 154.0 g AND MASS OF ANHYDROUS SALT (Na2S) IS 50.0 g • MASS OF HYDRATE IS 50.0 g AND MASS OF ANHYDROUS SALT (CaCl2) IS 37.8 g 10