SEDIMENTOLOGY AND STRATIGRAPHY OUTLINE AND HANDOUTS Introduction I. Course Logistics II. Why study Sed./Strat? III. The sedimentary cycle A. Weathering; transportation; deposition; diagenesis; upheaval SECTION I: WEATHERING AND SILICICLASTIC ROCKS Weathering I. Mechanical weathering Processes A. Exfoliation B. Crystal, frost, and plant wedging C. Heat expansion Enchanted Rock, Tx II. Chemical weathering Processes A. Solution Lapworth Church, England (early teens) B. Hydration C. Oxidation 1. Fe, Mn, Cu, Ti (Boggs, 1987) D. Hydrolysis 1. CO2 + H2O = H2CO3 = H+ + (HCO3)- = 2H+ + (CO3)-2 E. Chemistry and effected minerals in chemical weathering III. Chemical weathering/early diagenesis in soil and sediment environments A. Early precipitation, solution, and replacement Petrified wood 1. Solubility diagrams (Blatt, et al., 1980) 2. Eh/PH diagrams a. Eh = E0 + 2.303RT/nflog [Y]y[Z]z/[B]b[D]d b. Importance of Oxygen i. Photosynthesis / Respiration = CO2 + H2O = CH2O + O2 IV. Relative resistance to chemical weathering A. Mafic vs. felsic B. Soluble (e.g., gypsum) vs. insoluble (e.g., quartz) C. Residual vs. fresh V. Conditions and locations which favor chemical weathering A. Rainfall B. Surface area C. Time and Stability D. Temperature Spheroidal weathering southern California E. Plant decay Ivanpah Mts. southwestern U.S. NE Australia VI. Products of weathering A. Congruent vs. incongruent dissolution B. Mechanical vs. chemical weathering products VII. Mineralogy of residuals A. Example phylosilicate mineral prior to weathering B. The illite step C. The smectite step D. The kaolinite step E. The gibbsite step VIII. Relationship between residual mineralogy and chemical-weathering intensity IX. Relationship between weathering processes and composition of average clastic rock X. Dating of weathering rates A. Dating weathering products Radiometric dates of weathering rinds (Boggs, 2006) B. Dating denudation rates (Impact of relief, climate, bedrock ) (Blatt, et al., 1980) (Longbein and Schumm, 1947) C. Cosmogenic nuclides Radionuclides measured at PRIME Lab Radion uclide 10Be Half-life (years) Detection limit (10-15) 1,500,000 5 14C 5,730 3 26Al 730,000 5 36Cl 301,000 1 41Ca 100,000 5 16,000,00 0 20 129I Properties of Clastic Sediment -Weathering products -Detritus vs. Solutes -Siliciclastic sediments I. Grain size and grain-size distribution A. Wentworth scale B. Phi Scale Krumbein, 1934 1. Phi = -log2S i. S = grain diameter in millimeters II. Measurement methods for clast size A. >Pebbles 1. The hard way B. Pebbles - sand 1. Sieving 2. Settling tube (principles discussed later) 3. Thin sections C. Silt and smaller 1. Pipette 2. Black-box approaches (e.g., laser diffraction, Coulter counter, etc.) 3. Microscopes, SEM, TEM 4. Good old sense of touch III. Statistical textural descriptions A. Graphical 1. Histogram and frequency curve 2. Cumulative curve B. Mathematical 1. Central tendencies i. Mode ii. Median iii. Mean iv. Standard deviation iv. Skewness 2. Calculation methods i. Graphical ii. Moment IV. Grain shape A. Sphericity 1. General features 2. Significance B. Roundness 1. Powers scale 0 1 2 3 4 5 6 V. Application of textural data A. What can be told from texture 1. Travel history/travel distance i. Concept of textural maturity a. Sorting (well at 101 km in water and less in wind) b. Rounding (wind at 102 -103 shorter distance than water; water see Quartz pebbles rounded in km’s and quartz sand in 102-103 kms) 2. Energy conditions during transport i. Coarse vs. fine grained ii. In detail in Section III 3. Rock physical strength and expansion characteristics Proximal Delta Front Sandstones with thin mudstone interbeds B. Uses for textural data 1. Depositional conditions/environment i. Sediment transport thresholds and flux rates Distal Delta Front Interbedded mudstones and sandstones ii. Distance from source and level of reworking 2. Stratigraphic distinctions 3. Geoengineering i. Slope stability, sediment compressibility, soil expansion, etc. (USGS) VI. Fabric A. Cubic vs. rhombohedral packing B. Imbrication C. Grain contacts D. Sedimentary structures 1. See Section III VII. Mineralogy A. Importance of durability 1. Order of resistance 2. Quartz, K-spar, secondary minerals vs. mafics and soluble B. What can be told from mineralogy? 1. Travel history/distance i. Concept of maturity a. Immature (<75%) submature (75-95%), mature (95-99%), supermature (99-100%) 2. Diagenetic history i. See below 3. Provenance i. Source rocks ii Source weathering conditions Diagenesis of Siliciclastic Sediment I. Introduction A. Eogenesis vs. mesogenesis vs. telogenesis B. Diagenetic vs. depositional environments II. The diagenetic environment A. Pressure 1. Lithostatic gradient 2. Hydrostatic gradient B. Temperature 1. Geothermal gradient i. Average 250C/km ii. Sources of variability C. Formation waters 1. Meteoric vs. connate vs. juvenile 2. Changes with depth i. Increases in salinity and pH ii. Decreases in pCO2 and Eh III. Alteration and Authigenesis A. Alteration vs. Authigenesis (Blatt, et al., 1980) (Blatt, et al., 1980) B. Key framework minerals 1. Quartz 2. Feldspar 3. Lithic fragments 4. Clays 5. Other changes i. Thermal maturation Humble-Inc.com ii. Compaction iii. Replacement A. The Calcite/Quartz example V. Cementation A. Cementation and the range of cementing agents 1. Silica, calcite, Fe minerals. 2. Feldspar, pyrite, anhydrite, zeolite, clays, etc B. Silica 1. Role of in situ sources i. Pressure solution; dissolution of glass; hydrolysis 2. Problems 3. Role of external sources i. Circulation model C. Calcite 1. Role of sea water and >2x saturation D. Fe-oxides 1. Destruction of Detrital accessory minerals 2. Fe(OH)3 conversion Classification of Siliciclastic Rocks I. Features of a good classification scheme II. Mudstone A. Primarily silt and clay B. Approx. 50% of all sedimentary rocks III. Sandstone A. The Turner/Gilbert, Folk, and McBride schemes (McBride, 1963) (Folk et al, 1970) IV. Conglomerates A. >10-30% grains >2mm B. A classification scheme Images in Siliciclastic Petrology Quartz and Quartz Arenites Milliken, Choh, and McBride, 2005 Sandstone Petrology: A Tutorial Petrographic Image Atlas Angular Non-undulose Quartz Grain Colorado River Sand, TX Quartz Grain with Undulose Extinction Colorado River Sand, TX Undulose Quartz Grain Chert Grain Highly Undulose Quartz and Chert Grain Colorado River Sand, TX Monocrystalline Quartz Grain Calcite Cement Polycrystalline Quartz Grain Polycrystalline and Monocrystalline Quartz in Calcite Cement Cambrian Hickory Ss, TX Quartz Grain with Inclusions showing Pseudotwinning Jurassic Norphlet Fm, AL Overgrowth Grain Boundary Transported and Rounded Quartz Overgrowths South Padre Island Beach Sand, TX Well-rounded Quartz Grains in Quartz Overgrowth Cement Quartz Arenite, Permian Lyons Ss, CO Quartz Overgrowth Non-undulose Quartz Grain Chalcedony Cement Quartz Arenite with Chalcedony Cement Cretaceous Cox Ss, TX Microquartz Cement Included Quartz Grains Undulose Quartz Grains Non-undulose Quartz Grains Quartz Arenite with Microquartz Cement Cretaceous Cox Ss, TX Quartz Cement Longitudinal Contact Concavo-Convex Contact Quartz Arenite with Concavo-Convex and Longitudinal Grain Contacts Location Unknown Images in Siliciclastic Petrology Feldspars and Arkoses Milliken, Choh, and McBride, 2005 Sandstone Petrology: A Tutorial Petrographic Image Atlas Plagioclase Grain with Albite Twinning Quartz Grain Twinned Plagioclase and Quartz Grains Colorado River Sand, TX Calcite Cement Zoned Plagioclase (Similar Appearance to Zoned Quartz) Zoned Un-twinned Plagioclase in Calcite Cement Miocene Zia Fm, NM Un-twinned Plagioclase Eocene Jackson Group, TX (Similar appearance to some K-spar) Stained K-spar River Sand, Alberta Microcline Grain Colorado River Sand, TX Albite Stained K-Spar Cleavage Plains Perthite Grain Plio-Pleistocene, Offshore, LA Tangential Contacts Feldspar Grain Dissolving at Cleavages Trinity River Sand, TX Sericite Albite Twins Sericite Conversion of Plagioclase Grain Colorado River Sand, TX Quartz Grain Quartz Grain Complete Sericite Conversion of Plagioclase to Pseudomatrix Pennsylvanian Breathitt Fm, Eastern KY Stained K-spar Overgrowth Leached Plagioclase K-spar Overgrowth on Leached Plagioclase Oligocene Frio Fm, TX K-spar Albite Albitized Feldspar Grain Oligocene Frio Fm, TX Images in Siliciclastic Petrology Lithic Fragments and Litharenites Milliken, Choh, and McBride, 2005 Sandstone Petrology: A Tutorial Petrographic Image Atlas Intraclasts Limestone Clast with Intraclasts Cemented by Sparry Calcite Location Unknown Volcanic Rock Fragment Volcanic Glass Clast River Sand, New Zealand Fractured K-spar Shale Clast Fractured K-spar Compacted Shale Clast among Fractured K-spar Grains Cretaceous, WY Compaction-Deformed Shale Clast Cretaceous, WY Pelite Pelite Quartz grains Compacted Pelidic (mostly Phillite or Slate) Fragments Ordovician Martinsburg Fm, VA Plagioclase Kaolinized Pelidic Fragments K-spar with Carlsbad Twinning Quartz Grains Pelidic (Schist) Fragment Quartzite or Siltstone Grain Litharenite with Kaolinized Muscovite within in Pelitic Fragments Tertiary, North Sea Phillite Pseudomatrix Siltstone Grain Pelidic Metamorphic Grains Slate Pseudomatrix Litharenite with Mix of Grains in Pseudomatrix Martinsburg Fm, VA Mica Pseudomartix Quartz Grain with Inclusions Sutured Contact Quartz Grain with Inclusions Sutured Quartz Grains in Mica Pseudomartix Pennsylvanian Breathitt Fm, Eastern KY Chlorite (Altered or Authogenic?) Matrix Chlorite-Replaced Volcanic Grains Chlorite Pore Filling and Chlorite Replacement of Glass and Volcanic Rock Fragments Cretaceous Woodbine Fm, TX