ELENCO DELLE PUBBLICAZIONE E DEI BREVETTI DEL PROF. G. CAVINATO 83) E. Negro, S. Polizzi, K. Vezzù, L. Toniolo, G. Cavinato, V. Di Noto. Interplay between morphology and electrochemical performance of “core–shell” electrocatalysts for oxygen reduction reaction based on a PtNix carbon nitride “shell” and a pyrolyzed polyketone nanoball “core”. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, (2014)28282841. 82) V. Di Noto, E. Negro, S. Polizzi, K. Vezzù, L. Toniolo, G. Cavinato. Synthesis, studies and fuel cell performance of “core–shell” electrocatalysts for oxygen reduction reaction based on a PtNix carbon nitride “shell” and a pyrolyzed polyketone nanoball “core”. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 39 (2014)2812-2827. 81) E. Amadio, G. Cavinato, P. Harter, L. Toniolo. An NMR study on the mechanism of ethene hydromethoxycarbonylation catalyzed by cationic Pd(II)-PPh3 complexes. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 745-746 (2013)115-119. 80) L. Calore, G. Cavinato, P. Canton, L. Peruzzo, R. Banavali, K. Jerabek, B. Corain Metal catalysis with nanostructured metals supported inside strongly acidic cross-linked polymer frameworks. Influence of reduction conditions of Au(III)-containing resins on metal nanoclusters formation in macroreticular and gel-type materials. Inorganica Chimica Acta, 391(2012)114-120. 79) Sartori Andrea, El Habra Naida, De Zorzi Chiara, Sitran Sergio, Casarin Maurizio, Cavinato Gianni, Sada Cinzia, Gerbasi Rosalba, Rossetto Gilberto Zirconocene Alkoxides, Promising Precursors for MOCVD of Zirconium Dioxide Thin Films Chemical Vapor Deposition, 18(4-6)(2012)151-158. 78) G. Cavinato, S. Facchetti, L. Toniolo Oxidative carbonylation of ethene catalyzed by Pd(II)-PPh3 complexes in MeOH using benzoquinone as stoichiometric oxidant. Journal of Molecular Catalysis A: Chemical, 352(2012)63-69. 77) Vito Di Noto, Matteo Piga, Guinevere A. Giffin, Micheal Sschuster, Gianni Cavinato, Luigi Toniolo, Stefano Polizzi New Sulfonated Poly(p-phenylenesulfone)/Poly(1-oxotrimethylene) Nanocomposite ProtonConducting Membranes for PEMFCs. Chemistry of Materials, 23 (2011)4452-4458. 76) Calore L., Cavinato G., Canton P., Peruzzo L., Tauro L., Corain B. Metal catalysis with nanostructured metals supported on strongly acidic cross-linked polymer frameworks. Part I. The behaviour of M2+ ions (M = Ni, Pd, Pt, Cu) supported on Rohm & Haas's resin A70 and Du Pont's SAC-13, towards H2 in the solid state and NaBH4 in aqueous medium. Reactive & Functional Polymers, 70(2010)639-646. 75) Gianni Cavinato, Sarah Facchetti, Luigi Toniolo Ethene hydromethoxycarbonylation catalyzed by cis-[Pd(SO4)(PPh3)2]/H2SO4/PPh3. Journal of Molecular Catalysis A: Chemical, 333(2010)180-185. 74) Calore L., Cavinato G., Canton P., Peruzzo L., Tauro L., Corain B. Metal catalysis with nanostructured metals supported on strongly acidic cross-linked polymer frameworks. Part I. The behaviour of M2+ ions (M = Ni, Pd, Pt, Cu) supported on Rohm & Haas's resin A70 and Du Pont's SAC-13, towards H2 in the solid state and NaBH4 in aqueous medium. Reactive & Functional Polymers, 70(2010)639-646. 73) Amadio E., Cavinato G., Dolmella A., Toniolo L. Catalytic Properties of [Pd(COOMe)nX(2-n)(PPh3)2] (n=0, 1, 2; X = Cl, NO2, ONO2, OAc and OTs) in the Oxidative Carbonylation of MeOH. Inorganic Chemistry, 49(2010)3721-3729. 72) Vavasori A., Dall'Acqua F., Cavinato G., Toniolo L. Influence of the operating conditions on the catalytic activity of [PdCl2(dapp)] in the CO-ethene copolymerization in the H2O-CH3COOH as a solvent (dapp = 1,3-bis(di(2-methoxyphenyl) phosphino)propane). Journal of Molecular Catalysis A: Chemical. 332(2010)158-164. 71) Vavasori A., Ronchin L., Amadio E., Toniolo L., Cavinato G. Terpolymerisation of 1-olefin and ethene with CO catalysed by the [PdCl2(dppp)] complex in methanol as a solvent[dppp= 1,3-bis(diphenylphosphino)propane]. Journal of Molecular Catalysis A: Chemical, 299 (2009)5-11. 70) Ronchin L., Vavasori A., Bernardi D., Cavinato G., Toniolo L. Selective hydrogenation of ethyl-benzoylacetate to 3-hydroxy-3-phenyl-propionate catalyzed by Pd/C in EtOH as a solvent in the presence of KOH: The role of the enolate ion on the reaction mechanism. Applied Catalysis A: General, 355(2009)50-60. 69) Ronchin, L., Vavasori, A., Amadio E., Cavinato G., Toniolo L. Oxidative carbonylation of phenols catalyzed by homogeneous and heterogeneous Pd precursors. Journal of Molecular Catalysis A: Chemical, 298(2009)23-30. 68) Ronchin L., Vavasori A., Bernardi D., Cavinato G., Toniolo L. Selective hydrogenation of ethyl-benzoylacetate to 3-hydroxy-3-phenyl-propionate catalyzed by Pd/C in EtOH as a solvent in the presence of KOH: The role of the enolate ion on the reaction mechanism. Applied Catalysis A: General, 355(2009)50-60. 67) Amadio E., Cavinato G., Dolmella A., Ronchin L., Toniolo L., Vavasori A. New carboalkoxybis(triphenylphosphine)palladium(II) cationic complexes: Synthesis, characterization, reactivity and role in the catalytic hydrocarboalkoxylation of ethene. X-ray structure of trans-[Pd(COOMe)(TsO)(PPh3)2]·2CHCl3. Journal of Molecular Catalysis A: Chemical, 298(2009)103-110. 66) G. Carta, N. El Habra, G. Rossetto, L. Crociani , G. Torzo, P. Zanella, M. Casarin, G. Cavinato, G. Pace, S. Kaciulis, A. Mezzi Chemical vapor deposition of hafnium dioxide thin films from cyclopentadienyl hafnium Compounds. Thin Solid Films, 516(2008)7354-7360. 65) G. Carta, N. El Habra , G. Rossetto, G. Torzo, L. Crociani , M. Natali, P. Zanella, G. Cavinato, V. Matterello, V. Rigato, S. Kaciulis, A. Mezzi Growth of hafnium dioxide thin films by MOCVD using a new series of cyclopentadienyl hafnium compounds. Chemical Vapor Deposition, 13 (2007) 626-632. 64) G. Carta, G. Rossetto, F. Benetollo, P. Zanella, G. Cavinato Synthesis and physico-chemical characterization of [Hf(NEt2)2Cl2(DME)] and it use as catalyst for ethylene polymerization. Inorganic Chemistry Communications, 110(2007)930-932. 63) Vavasori A., Bellini L., Ronchin L., Dall’Acqua F., Toniolo L., Cavinato G. Selective copolymerisation of carbon monoxide and ethene catalysed by [PdCl2(dppf)] in acetic acid-water as a solvent [dppf = 1,1’-bis(diphenylphosphino)ferrocene]. Journal of Molecular Catalysis A: Chemical 263(2007)9-14. 62) G. Cavinato, A. Vavasori, E. Amadio, L. Toniolo CO-ethene copolymerisation catalysed by [PdCl2(PPh3)2]/PPh3/HCl in MeOH. Journal of Molecular Catalysis A: Chemical 278(2007)251-257. 61) G. Cavinato, L. Toniolo, A, Vavasori Carbonylation of ethene in methanol catalysed by cationic phosphine complexes of Pd(II): from polyketones to monocarbonylated products. Topics in Organometallic Chemistry, 18(2006)124-164. 60) G. Cavinato, A. Vavasori, L. Ronchin, F. Dall’Acqua, A. Dolmella Synthesis, characterization and X-ray structure of [Pd(SO4)(dppp)]·H2O, a catalyst for the COethene copolymerisation [dppp = 1,3-bis(diphenylphosphino)propane]. Inorganica Chimica Acta, 358(2005)4555-4562. 59) G. Cavinato, A. Vavasori, L. Toniolo, A. Dolmella Synthesis, characterization and catalytic activity in the carbonylation of ethene of cis-[Pd(H2O)2(PPh3)2]X2·nH2O(X = p-CH3C6H4SO3, n = 2; X = CH3SO3, n = 0). X-ray structure of cis-[Pd(H2O)2(PPh3)2]( p-CH3C6H4SO3)2·2H2O and of cis-[Pd(H2O)2(PPh3)2](CH3SO3)2·2CH2Cl2. Inorganica Chimica Acta, 357 (2004 )2737-2747. 58) G. Cavinato, A. Vavasori, L. Toniolo Characterization and catalytic activity of trans-[Pd(COCH2CH3)(TsO)(PPh3)2], isolated from the hydro-methoxycarbonylation of ethene catalysed by [Pd(TsO)2(PPh3)2], J. Mol. Catal. Chem. A, Chemical, 219(2004)233-240. 57) F. Benetollo, G. Carta, G. Cavinato, L. Crociani, G. Paolucci, G. Rossetto, F. Veronese, P. Zanella New η2-Formamidinyl Zirconium Complexes: Synthesis, Characterization and Catalytic Activity. Organometallics, 22(20) (2003) 3985-3990. 56) A. Vavasori, L. Toniolo, G. Cavinato Carbon monoxide-ethylene copolymerisation catalysed by [PdCl2(dppp)] in methanol-water or in acetic-water as solvents (dppp = 1,3-bis(diphenylphosphine)propane). J. Mol. Catal. Chem. A, Chemical, 215 (2003) 63-72. 55) G. Cavinato, A. Vavasori, L. Toniolo, F. Benetollo Synthesis, characterization and X-ray structure of trans-[Pd(COOCH3)(H2O)(PPh3)2](TsO), a possible intermediate in the catalytic hydroesterification of olefins ( TsO = p-toluensulfonate). Inorg. Chim. Acta, 343 (2003) 183-188. 54) A. Vavasori, L. Toniolo, G. Cavinato, F. Visentin Highly active [Pd(AcO)2(dppp)] catalyst for CO-C2H4 copolymerization in H2O-CH3COOH solvent [dppp =1,3-bis(diphenylphosphino)propane] J. Mol. Catal. Chem. A, Chemical, 204-205 (2003) 295-303. 53) A. Vavasori, L. Toniolo, G. Cavinato Hydroesterification of cyclohexene using the complex Pd(PPh3)2(TsO)2 as catalyst precursor. Effect of a hydrogen source (TsOH, H2O) on the TOF and a kinetic study ( TsOH: p-toluene sulfonic acid). J. Mol. Catal. Chem. A, Chemical, 191 (2003) 9-21. 52) A. Vavasori, G. Cavinato and L. Toniolo Carbon Monoxide-Ethylene Copolymerization Catalyzed by a Pd(OAc)2/Dppp/Fornic Acid System [dppp=1,3-bis(diphenylphosphino)propane]. J. Mol. Catal. Chem. A, Chemical, 191 (2003) 209-215. 51) G. Carta, G. Rossetto, P. Zanella, S. Battaini, S. Sitran, P. Guerriero, G. Cavinato, L. Armelao, E.Tondello Synthesis and characterization of metal oxide multilayers obtained via MOCVD as protective coatings of graphite against oxidation. Surface and Coatings Technology,160 (2002)124-131. 50) G. A. Battiston, G. Carta, G. Cavinato, R. Gerbasi, M. Porchia and G. Rossetto MOCVD of Al2O3 Films Using New Dialkylaluminium Acetylacetonate Precursors: Growth Kinetics and Process Yields. Chemical Vapor Deposition, 7 (2001) 69-74. 49) A. Vavasori, G. Cavinato, L. Toniolo Effect of Hydride Source ( Water, Hydrogen, p-Toluensolfonic acid) on the Hydroesterification of Ethylene to Methyl Propinate Using a Pd(PPh3)2(TsO)2 ( TsO = p-Toluensulfonate anion) Catalyst Precursor. J. Mol. Catal. Chem. A, 176 (2001) 11-18. 48) D. Barreca, F Benetollo, M. Bozza, S. Bozza, G. Carta, G. Cavinato, G. Rossetto and P. Zanella Metal Organic Chemical Vapor Deposition of Co-, Mn-, Co-Zr And Mn-Zr Oxide Thin Films. Mat. Res. Soc. Symp. Proc., 606(2000) 69-74. 47) U. Casellato, G. Cavinato R. Graziani and L. Toniolo Crystal Structure of (cyclohexanonetriphenylphosphonium)(trichlorotriphenyl)palladate(II)benzene(1/1), [(C2H5)3P(CHCH2CO(CH2)3)][(C6H5)3PPdCl3]·C6H6. Z. Kristallogr. NCS 215 (2000) 377-379. 46) G. Cavinato, L. Toniolo [PdCl2(PPh3)2]- PPh3 Catalyzed Regiospecific Alkoxycarbonylation of alfa-chloroexylketone to β-ketoester. J.Mol. Catal. Chem. A, 143 (1999) 325-330. 45) F. Benetollo, G. Cavinato, L. Crosara, F. Milani, G. Rossetto, C. Scelza, P.Zanella New O- and N-bonded Zirconocene Complexes and their Catalytic Properties in Ethylene Polymerization. X-ray Crystal Strutture of (C5H5)2Zr{2,6-OC6H3(CH3)2}2, (C5H5)2Zr{2,4,6 OC6H2(CH3)3}2 and (C5H5)2Zr(CH3){CH(NC6H5)2}. J. Organomet. Chem., 555 (2) (1998) 77-185. 44) L. Ronchin, L. Toniolo, G. Cavinato Hydrogenation of Mandelic Acid Derivatives to the Corresponding Phenyl Acetic Acid Derivative Catalyzed by Pd/C. A kinetic Study. Applied Catalysis A, 165 (1997) 133-145. 43) G. Cavinato, M. Pasqualetto, L. Ronchin, L. Toniolo Palladium Catalyzed Hydrodechlorination of α-chloroacetophenones by Hydrogen Transfer from the H2O-CO System. J. Mol. Catal. Chem. A, 125 (1997) 15-22. 42) G. Cavinato, L. Toniolo Highly Selective Transfer Hydrogenation from Formates to the C=C Double Bond of γ-ketoα,β Unsaturated Carboxylic Acids Catalyzed by Pd/C. J. Mol. Catal. Chem. A, 106 (1996) 25-30. 41) G. Cavinato, L. Toniolo On the Mechanism of the Hydrogen Transfer from H2O-CO to γ-keto-α-hydroxy Carboxylic Acid to Yield γ-keto Acids Catalyzed by a PdCl2(PPh3)2 Precursor in Combination with Hydrochloric Acid. J. Mol. Catal. Chem.A, 105 (1996) 9-15. 40) G. Cavinato, L. Toniolo Synthesis of γ-ketocycloalkanecarboxylic Acid Esters by Regiospecific Alkoxycarbonylation of α,β-ketocycloolefins Catalyzed by Palladium. J. Mol. Catal. Chem. A, 104 (1996) 221-227. 39) G. Cavinato, L.Ronchin, L. Toniolo Synthesis of Arylacetic acid Derivatives from Mandelic acid Derivatives by Hydrogen Transfer from H2O-CO Catalyzed by a Pd/C-HCl System. J. Mol. Catal., 102(1995)129. 38) G. Cavinato, L. Toniolo, G. Vasapollo, F. Bigoli, M. Lanfranchi, M. A. Pellinghelli Bis(alkoxycarbonyl) Complexes of Platinum Preparation, Reactivity and their Role in Carbonylation Reactions. J. Organomet. Chem., 481(1994)173. 37) G. Cavinato, G. De Munno, M. Lami, M. Marchionna, L. Toniolo and D.Viterbo Isolation and Characterization of the Acyl Complexes trans-[Pt(PPh3)2(COR)Cl] ( R = nBu or s Bu) and their Relevance to the Hydroformylation of Linear Butenes Catalyzed by PlatinumTin- Triphenylphosphine Catalytic Systems. Molecular Structure of cis-[Pt(PPh3)2Cl(SnCl3)]. J. Organomet. Chem., 466 (1994) 277. 36) Cavinato, L. Ronchin, L.Toniolo Highly Selective Palladium Catalyzed Hydrogrn Transfer from H2O-CO to the C=C Double Bond of β-benzoylacrylic acid. J. Mol. Catal., 94 (1994) 173. 35) G. Cavinato, P. Bertani, G. Facchin, L. Toniolo, A. Vavasori New Aspects of the Carbonylation of Allylpalladium Complexes. J. Organomet. Chem., 466 (1994)273. 34) Cavinato, L. Toniolo, A. Vavasori Synthesis of γ-ketocarboxylic Acid via Reduction of γ-keto-α-hydroxycarboxylic Acids with Carbon Monoxide Catalyzed by Pd-HCl System. J. Mol. Cata., 89 (1994) 93. 33) R. Bertani, G. Cavinato, L. Toniolo and G.Vasapollo New Alkoxycarbonyl Complexes of Palladium(II) and Their Role in Carbonylation Reactions Carried Out in the Presence of an Alkanol. J. Mol. Catal., 84 (1993) 165-176. 32) G. Cavinato and L. Toniolo Syntheses of γ-keto Carboxylic Acids from γ-keto-α-chlorocarboxylic Acid via Carbonylation Decarboxylation Reactions Catalyzed by a Palladium System. J. Mol. Catal., 78 (1993) 121-129. 31) G. Cavinato and L, Toniolo Palladium-Catalvzed Carbonylation of Benzvl Alcohol Derivatives to Phenylacetic acid Derivatives. J. Mol. Catal., 78 (1993)131-142. 30) G. Cavinato and L. Toniolo Influence of the Reaction Parameters on the Pd-HCl Catalyzed Synthesis of Phenylacetic Acid Derivatives via Reduction of Mandelic Acid Derivatives with Carbon Monoxide. J. Mol. Catal., 78 (1993) 9-20. 29) G. Cavinato and L. Toniolo New Aspects of the Synthesis of Dimethyl Carbonate via Carbonylation of Methyl Alcohol Promoted by Methoxvcarbonyl Complexes of Palladium(II). J. Organomet. Chem,, 444 (1993) C65-C66. 28) G. Cavinato and L Toniolo Synthesis of Arylacetic Acid Derivatives via Reductive Carbonylation of Mandelic Acid Derivatives Catalyzed by a Highly Active Pd-HCl System J. Mol. Catal., 75 (1992) 169. 27) G. Cavinato and L. Toniolo Carbonilation of Aromatic Aldehydes to Phennylacetic Acid Derivatives Catalyzed by a PdPPh3-HCl System. J. Mol. Catal., 69 (1991) 283. 26) G. Cavinato, L. Toniolo On the Mechanism of the Hydrocarbalkoxylation of Olefins Catalyzed by Palladium Complexes. J. Organomet. Chem., 398 (1990) 187. 25) G. Cavinato, L. Toniolo Levulinic Acid Synthesis Via Regiospecific Carbonylation of Methylvinyl Ketone or of its Reaction Products with Hydrocloric Acid or an Alkanol or of a Mixture of Acetone with a Formaldheyde Precursor Catalyzed by a Highly Active Pd-HCl System. J. Mol. Catal., 58 (1990) 251. 24) R. Graziani, G. Cavinato, U. Casellato, L. Toniolo The Isolation and Molecular Structure of trans-[PtCl(COCH2CH2Ph)(PPh3)2]. EtOH, an Intermediate in the Hydroformylation of Styrene Promoted by the cis-[PtCl2(PPh3)2]-SnCl2 Catalytic System. J. Organomet. Chem. 353 ( 1988) 125. 23) R. Bardi, A.M. Plezzesi, A. Del Pra, G. Cavinato and L. Toniolo Metals in Organic Syntheses XIII. The Isolation and Molecular Structure of trans-[PdCl(COC6H13-n)(PPh3)2], an Intermediate in the Hydrocarboalkoxylation of 1-Hexene Catelyzed by the Precursor trans-[PdCl2(PPh3)2]. Inorg. Chim. Acta, 102 (1985) 99. 22) G. Cavinato, L. Toniolo, and C. Botteghi, Meltals in Organic XII. Hydrocarboalkoxylation of Ethyl 3-Butenoate Catalyzed by Palladium Complexes. J. Mol. Catal. 32, (1985) 211. 21) A. Scrivanti, G. Cavinato, Toniolo and C. Botteghi Metals in Organic Syntheses XI. 31P NMR and Reactivity Studies on the System trans-[PtCl(CO-n-hexyl)(PPh3)2]-SnCl2, an Active Intermediate in the Catalytic Hydroformylation of 1-hexene. J. Organomet. Chem., 286 (1985) 115. 20) L. Toniolo, G. Cavinato Processo per la Preparazione di γ-chetoacidi Chetoni e Acido Gliossilico Brevetto Italiano n° 23201A/84, CNR 62. 19) L. Toniolo, G. Cavinato Processo per la Preparazione di γ-chetoacidi da γ-chetoaloacidi Brevetto Italiano n° 23202A/84, CNR 61. 18) L. Toniolo, G. Cavinato Processo per la Preparazione di γ-chetoacidi da γ-chetoossiacidi Brevetto Italiano n° 23200A/84, CNR 60. 17) L. Toniolo, G. Cavinato Processo per la Preparazione di γ-chetoacidi Saturi da γ-chetoacidi α,β insaturi Brevetto Italiano n° 23199A/84, CNR 59. 16) L. Toniolo, G. Cavinato Processo per la Preparazione di γ-chetoacidi da Chetoni Brevetto Italiano n° 22736A/83, CNR 29. 15) L. Toniolo, G. Cavinato Processo per la Preparazione di γ-chetoacidi o Chetoesteri Brevetto Italiano n° 22738A/83, CNR 35. 14) L. Toniolo, G. Cavinato Processo per la Preparazione di γ-chetoacidi o Chetoesteri Brevetto Italiano n° 22735A/83, CNR 36. 13) L. Toniolo, G. Cavinato Processo per la Preparazione di γ-chetoacidi o loro Esteri Brevetto Italiano n° 22539A/83 CNR 34. 12) G. Cavinato and L. Toniolo Metals in Organic Syntheses X. Olefin Hydroformylation and Hydrocarboalkoxylation Competitively Catalyzed by a [PtCl2(PPh3)2]-SnCl2 System. J. Organomet. Chem., 241 (1983) 275. 11) R. Bardi, A.M. Píazzesi, A. Del Pra, G. Cavinato, and L. Toniolo Metals in Organic Syntheses IX. The Isolation and Molecular Structare of trans-[PtCl(COC6H13-n)(PPh3)2 , an Intermediate Precursor in the Catalytic Hydroformylation of 1-Hexene. J. Organomet. Chem. , 234 (1982) 107. 10) G. Cavinato, L. Toniolo, C. Botteghi and S. Gladiali Hydrocarboalkoxylation of N-Vinylphtalimide Catalyzed by Palladiun Complexes. J. Organomet. Chem., 229 (1982) 93. 9) R. Bardi, A.M. Piazzesi., G. Cavinato, P. Cavoli and L. Toniolo Metals in Organic Syntheses VII. The Isolation of trans-[Pt(COPr-n)Cl(PPh3)2] (I) and trans-[Pt(SnCl3)(COPr-n)(PPh3)] (II) , Active Intermediates in the Hydroformylation of Propene Catalyzed by a [PtCl2(PPh3)2]-SnCl2 Precursor. The Crystal and Molecular Structure of Complex I and a Comparison with its Palladium Analog. J. Organomet. Chem., 224 (1982) 407. 8) G. Cavinato and L. Toniolo Metals in Organic Syntheses VI. The Solvent Effect on the Hydrocarboalkoxylation of Propene Promoted by a [PdCl2 (PPh3)2]-PPh3 Catalyst Precursor. J. Mol. Catal., 10 (1981) 161. 7) G. Cavinato and L. Toniolo Metals in Organic Syntheses II. The Effect of Molecular Hydrogen on the Highly Regioselective Hydrocarboxylation of Propene Promoted by a [PdCl2(PPh3)2 –PPh3 Catalyst Precursor. Chimia, 33 (1979) 28. 6) G. Cavinato and L. Toniolo The Effect of Molecular Hydrogen on the Highly Regioselective Hydrocarboxylation of Propene Promoted by dichlorobis(triphenyl phosphine)palladium-triphenyl phosphine as catalytic precursor. Atti Congr. Naz. Chim. Inorg. 12th, (1979) 430-2 Chemical Abstract vol 95 (1981) [95:41799x]. 5) G. Cavinato and L.. Toniolo Metals in Organic Syntheses I. Propene Hydrocarboxylation with Various Alkanols and [PdCl2(PPh3)2] as Catalyst Precursor. J. Molec. Catal., 6 (1979) 111. 4) R. Bardi, A.M. Piazzesi, A. Del Pra, G. Cavinato and L. Toniolo Reactivity of Functionalized Halo -Derivatives with Transition Metal Complexes. Synthesis and X-Ray Diffraction Study of [Ph3P(CH2CH2COCH3)]+ [PdCl(PPh )]- Obtained by Reaction of trans-[PdCl2(PPh3)2] with CH3COCH2CH2Cl. Inorg. Chim. Acta, 75 (1983) 15. 3) G. Cavinato and L. Toniolo Convenient One-Step Synthesis of Substituted Phosphine Complexes of Platinum (II) Directly from Hexachloroplatinic Acid. Inorg. Chim. Acta, 52 (1981) 39. 2) L.Toniolo and G. Cavinato A 1H NMR Study of trans-Hydrido(1,3-diaryltriazenido)bis(triphenylphosphine)platinum(II) Complexes. Inorg. Chim. Acta, 26 (1978) L5. 1) L.Toniolo and G. Cavinato Reactivity of [M(ArN-N=NAr)(CO)(PPh3) with Aryldiazonium Salts (M=Rh(I), Ir(I); Ar = p-CH3C6H4 , p- FC6H4). Inorg. Chim. Acta, 35 (1979) L 301.