The Mole The following provides an overview of moles and the skills necessary for performing mole conversions Definition of a Mole A dozen is a number that has been given a name. The same can be said for a mole. The only difference is that the number defined as a mole is very, very, very, very, very, very, very ,very, very, very, very, very, very, very, very, very, very, big!!! 1 mole = 6.02 x 1023 (602,000,000,000,000,000,000,000) Avogadro’s Number Is A Mole Really That Big? If an atom were the size of a marble and one mole of marbles were spread over the surface of the Earth, our planet would be covered by a 50 mi-thick layer. Is A Mole Really That Big? A new supercomputer can count all of the people in the United States in one-quarter of a second, but it would take almost two million years for it to count one mole of people at the same rate. Is A Mole Really That Big? If you made $40,000 (4,000,000 pennies) every second at your job that you had been working at since the formation of earth 4.5 billion years ago, you would not yet have earned Avogadro’s number of pennies. So How is a Mole Helpful? Scientists obviously can’t mass quantities of chemicals in amu because an amu is far too small. When scientists work with a substance like H2O, they can’t deal with single molecules – we can’t see or mass 2 atoms of hydrogen and one atom of oxygen. Scientists obviously have to work with much larger quantities. To solve this problem, scientists use the mole. To be useful the mole has to be somehow related to amu. Officially, the mole (symbol mol) is the SI term for the amount of substance containing as many elementary particles as there are atoms in 0.012 kg of carbon-12 (which is about 6.02 x 1023atoms) Where do you find how much a mole of something weighs? The atomic mass given on the periodic table is not only the mass of one atom of that element, but it is also the mass (in grams) of 1 mole of the atoms of that element. Therefore, since the mass of one carbon atom is 12 amu, the mass of one mole of Carbon atoms would be 12 grams. When dealing with a molecule or compound you simply calculate the molecular/formula mass using the periodic table, and this (like with atoms) is not only the mass of one molecule/compound, but it is also the mass (in grams) of 1 mole of the molecule/compound. Therefore, since the mass of one molecule of ozone (O3) is 48 amu, the mass of one mole of ozone molecules would be 48 grams. How much does it weigh? You may want to use your periodic table! 1 mole of Oxygen 1 mole of Sodium 2 moles of Carbon 3 moles of Hydrogen 1 mole of H2O 16 grams 23 grams 24 grams 3 grams 18 grams Mole Map This map is to help you navigate mole problems Mass (Grams) Excuse me, how do I get to Atoms? Moles If you use the map, you won’t get lost!!! Atoms, Molecules, Particles, Etc. Just start at grams, go straight through moles and you will get to atoms. Sample One Step Problem Calculate the mass of 7.5 moles of Carbon. Use the “map” to help figure it out Mass (Grams) Moles Atoms, Molecules, Particles, Etc. What is the starting point in this problem? What is the final destination in this problem? How many steps/fractions will it take you to get there? One Step Problem Calculate the mass of 7.5 moles of Carbon. 7.5 moles of C grams of C (7.5 moles of C) (____________) 12 grams of C (1) = 90 grams of C ( 1 mole of C) Explanation Mass (Grams) Use Periodic table Moles Atoms Use 1 Mole = 6.02x1023 #6 –Finally, multiply across the top, #4 –Since you are aware that itat isthe #2 #3 #5 #1 –Since –Place –Multiply –Now that your you between have you starting have already fractions arrived point found over and your multiply across the bottom, and divide the necessary to travel to grams you can one. make final starting destination In sure this point, the case bottom final (grams) you destination, will unit you beof placing can the and simply new the product of top by the product simply place that the topunit ofof the 7.5 fraction cancel number moles all of isother of steps the carbon same diagonal itunit will over ason take, the units. one. top you should ofthe the bottom. This will give you the final answer, fraction. To determine the mass ofunit a is previous now writefraction. down a little In this reminder case the of which incarbon this case 90 the grams of C. table. mole youisuse periodic “mole all ofof this of carbon.” information. In this case, one mole of carbon has a mass of 12 grams. You plug these numbers into the fraction, letting the units guide you. You have now transitioned from moles to grams. Sample Two Step Problem How many atoms are in 45.8 grams of Na? Use the “map” to help figure it out Mass (Grams) Moles Atoms, Molecules, Particles, Etc. What is the starting point in this problem? What is the final destination in this problem? How many steps/fractions will it take you to get there? Two Step Problem How many atoms are in 45.8 grams of Na? 45.8 grams atoms of Na 6.02x1023atoms of Na (45.8 grams of Na) (_____________) 1 mole of Na (________________) (1) ( 23 grams of Na ) = 1.20 x 1024 atoms of Na Mass (Grams) Use Periodic table Moles Atoms Use 1 Mole = 6.02x1023 ( 1 mole of Na) Explanation #4 –Since you are aware that it over istop, #2 –Since –Placethat your starting point #3 –Multiply between fractions and #6 #5 #7 #1 –Now you are have you at have already moles, arrived found it is at now the moles it your #8 –Finally, multiply across the necessary to travel to atoms, according to one.be In this case you will beof placing make sure the bottom unit the new possible will final starting destination necessary for point, you final to (atoms) to travel destination, continue you to atoms; can your and simply travels the multiply across the bottom, and divide the the “Mole Map,” you must stop at moles 45.8 grams of should sodium over one. fraction is the same as the top the therefore to cancel number atoms all of since other you steps moles diagonal it by will place isthe take, not units. that your youunit unit final should on product the top product ofof the first. Therefore you should place that unit previous fraction. In this case the unitthe is the destination. now top write of down the Once fraction. afraction. little again, reminder To you determine need ofto bottom. This will give you the final answer, on the top of the To determine 24sodium “grams sodium.” number multiply all of this between atoms fractions mole of and make you sure which inof this is atoms of the mass ofinformation. a case molein ofa1.20x10 sodium you use the 23 simply the bottom use 1 unit mole = 6.02x10 the newone fraction . mole You plug sodium. periodic table. In of this case, ofis the these same numbers the topinto unit ofgrams. fraction, the previous sodiumas has a mass ofthe 23 Youletting plug the fraction. units guide In this you. case You the have unit now is “mole of these numbers into the fraction, letting the transitioned sodium.” from to atoms. units guide you. Youmoles have now transitioned from grams to moles. Sample Problem That Requires Some Prep Work Before Converting Calculate the mass of two moles of the compound Ca(NO3)2. What is different about this problem when compared to the others? Ca(NO3)2 - it is not an atom You should calculate Ca = the 40gmolar x 1 =mass 40 using g/molyour periodic table prior to using subsequently N =your 14gmap x 2and = 28 g/mol converting O = 16g x 6 = 96 g/mol 1 mole of Ca(NO3)2 = 164 g Now that you know the molar mass of Ca(NO3)2 you can use your map and convert Sample Problem That Requires Some Prep Work Before Converting Calculate the mass of two moles of the compound Ca(NO3)2. Use the “map” to help figure it out Mass (Grams) Moles Atoms, Molecules, Particles, Etc. What is the starting point in this problem? What is the final destination in this problem? How many steps/fractions will it take you to get there? Continuation of Problem After Prep Work is Complete Calculate the mass of two moles of the compound Ca(NO3)2. 2 moles of Ca(NO3)2 grams of Ca(NO3)2 1 mole of Ca(NO3)2 = 164 g 164 grams of Ca(NO3)2 (__________________) (2 moles of Ca(NO3)2) ( 1 mole of Ca(NO3)2 ) (1) = 328 grams of Ca(NO3)2 Mass (Grams) Use Periodic table Moles Compounds Use 1 Mole = 6.02x1023 Explanation #4 –Since you are aware that itat is #2 #3 #5 #1 –Since –Placethat –Multiply –Now your you between have you starting have already fractions arrived point done over and some your #6 –Finally, multiply across the top, necessary to travel todetermined grams you can one. make final preliminary destination In sure this the work case bottom (grams) and you will unit you beof placing can the simply the new the multiply across the bottom, and divide simply that unit on the topunit ofof the 2 fraction cancel mass moles ofplace allof aof isother mole Ca(NO the same of diagonal )by over the units. )one. found the ofthe the product top the product 3Ca(NO 2 as 3 2,top fraction. To determine the mass ofunit atheis previous starting point, fraction. final In destination, this case the and bottom. This will give you the final mole of )2)this have already used of “mole number ofCa(NO of Ca(NO steps it .”will take, you should answer, which in case is 328 grams 33 2you your periodic table and reminder you calculated now write a little of a Ca(NO 3)2.. down mass 164 grams. You plug these all of of this information. numbers into the fraction, letting the units guide you. You have now transitioned from moles to grams.