Liquid Fluoride Thorium Reactors without equations ∑x<+-=-*± An overview of liquid-fueled liquid-cooled thermal spectrum Thorium breeder reactors and why they matter. Rob Morse Science Engineer- Nuclear Option 2012 1 Power makes a difference. 2 Fuel for a lifetime? You consume a ball of coal 10 meters in diameter… …or a ball or thorium 37mm in diameter. LFTR wo Equations. Thorium power conference, Oct 2009 3 Reactor Basics Reactors make heat through fission and decay. The heat is then converted into mechanical power and then to electrical power. Fission is controlled by the neutron population around the nuclear fuel. More neutrons produce more fissions and more heat. The neutron economy is tightly controlled by material properties, physics, and design. 4 The Absolutes A power source must be Self regulating when it is ON “Walk away” safe when it is OFF Inherently safe in case of an ACCIDENT LFTR wo Equations. Thorium power conference, Oct 2009 6 The Relative Strengths Little or no radioactive waste No bomb materials Low cost per power delivered Small physical size Power on demand A wide choice of building sites. LFTR wo Equations. Thorium power conference, Oct 2009 7 Core Options Standard pressurized water reactor (PWR) – Water flows over a core of ceramic fuel pins. Water acts as coolant and moderator. Reactivity is controlled by the moderator density and by control rods. Liquid Fluoride Thorium reactor (LFTR) – A liquid fuel flows though a core of graphite. The fuel acts as coolant, the graphite as moderator. Reactivity is controlled by the fuel density. 8 LFTR Processing Details Metallic Thorium feed stream Bismuth-metal Reductive Extraction Column Pa-233 Decay Tank Fluoride Volatility 233UF 6 7LiF-BeF2 Uranium AbsorptionReduction Pa Recycle Fertile Salt Recycle Fuel Salt 7LiF-BeF -UF 2 4 UF6 Fission Product Waste Return Two-Fluid Reactor Hexafluoride Distillation “Bare” Salt Core Blanket 232,233,234 Vacuum Distillation Fertile Salt xF6 Fluoride Volatility Fuel Salt MoF6, TcF6, SeF6, RuF5, TeF6, IF7, Other F6 Molybdenum and Iodine for Medical Uses9 Metal Reduction Column 10 Temperature Stability A power plant with a built in thermostat! inlet outlet Fuel-coolant Graphite Moderator reactivity temperature LFTR wo Equations. Thorium power conference, Oct 2009 11 Improved reactor design reactivity temperature LFTR wo Equations. Thorium power conference, Oct 2009 12 The Reactor at “idle” Fuel Loop LFTR wo Equations. Thorium power conference, Oct 2009 13 Walk-Away Safe 14 Size matters! Your nuclear waste is the size of a few grains of rice! LFTR wo Equations. Thorium power conference, Oct 2009 15 Uranium vs Thorium as a Fuel 0.7 % of Uranium is fissionable. The rest becomes nuclear waste. Thorium is isotopically pure and converted to U233 for fuel. For fuel cycle side-reactions seehttp://en.wikipedia.org/wiki/Thorium_fuel_cycle 16 Lets Make Power This is a picture of the waste heat coming from the original LFTR test cell. The heat transfer fluid (molten salt) is at low pressure. We can use a gas cycle, like a jet engine, to convert heat into mechanical power. (highly efficient) These plants can run at partial load. LFTR wo Equations. Thorium power conference, Oct 2009 17 Fuel or Waste We want the fuel to fission rather than transmute. U233- 90% fissions U235- 83% fissions P239- 50% fissions P241- 25% fissions LFTR wo Equations. Thorium power conference, Oct 2009 18 Myth of Half Life What makes a radioactive material dangerous? – Even low energy beta decays can break organic bonds. Is a material with a 1 second half life dangerous? – It is very dangerous..today. Tomorrow it is inert. Is a 15 billion year half life dangerous? (Half of it has decayed since the big bang.) It has a very low activity, and we used it for hundreds of years. How about a thousand year half life? It is both active and persistent. 19 Myth of Creating Radioactivity If radiation is dangerous then we should do what we can to eliminate it from the environment. That is exactly what nuclear reactors do. They are the nuclear analog to chemical catalysis reactors; they accelerate natural processes. The only way to “create” nuclear radiation is with particle accelerators. Conventional reactors simply accelerate decay towards stable elements. 20 Myth of Concentration Thorium and uranium are dispersed in nature and they decay naturally. We concentrate them, and so concentrate their natural toxicity. For safe disposal, should we re-disperse them and lower their effective activity, or sequester them and decrease our contact? 21 References http://en.wikipedia.org/wiki/Liquid_fluoride_thorium_reactor http://www.scribd.com/doc/59204103/Thorium-presentation-GreenEnergy-Forum-2008-07-25 http://www.thoriumenergyalliance.com/ThoriumSite/resources.html http://moltensalt.org/references/static/downloads/pdf/NAT_MSBRrecycle.p df Thorium in 5 minutes (remix video) http://www.youtube.com/watch?v=uK367T7h6ZY 22 Outline Motivations for Nuclear Power LFTR overview Nuclear Chemistry Chemistry Myths Questions 23 Binding energy 24 Cross Section The probability that the neutron interacts with the nucleus depends on the neutron’s speed. We describe the probability as an apparent SIZE of the nucleus. The larger the apparent size, the higher the probability. This is a geometric interpretation of a probabilistic quantum mechanical event. Reaction equations are of the formNumber of events/time = (neutron flux) (spatial density of target nuclei) ( cross section for the event ) Moderation and Rx Probabilities Neutron Cross Sections barns (10e-28 m-sq) 500 400 300 200 100 0 Fast U-233 fission Fast Thorium absobtion Thermal U-233 fission Thermal Thorium absorbtion >>Fast to Slow>> LFTR wo Equations. Thorium power conference, Oct 2009 26 Speed? LFTR wo Equations. Thorium power conference, Oct 2009 27 Nuclear Fission 28 Chart of the Nuclides for LFTR Fissile Fuel! Ref: http://www.nndc.bnl.gov/nudat2/reCenter.jsp?z=90&n=142 Uranium (92) ~27 days half-life Protactinium (91) ~22 min half-life Thorium (90) Raw Material! +N 29