Which salt solution has the greatest concentration? [ ] is a measure of the amount of solute in a given amount of solution Beaker A 3 molecules 100 mL solution Beaker B 5 molecules 100 mL solution Beaker C 7 molecules 200 mL solution Ppm, % Composition, Molarity , and pH Get out your calculator! 1. A bottle contains 500. mL of water. If this solution has 15.5 mL of pure hydrogen peroxide, what is the concentration of hydrogen peroxide in this solution? amount of solute % Compositio n X 100 amount of solute amount of solvent % Hydrogen Peroxide % Hydrogen Peroxide 15.5 mL X 100 15.5 mL 500 mL 15.5 mL X 100 3.01% 515.5 mL percent composition = amount solute 100 amount solution 2. I dilute 10.0 mL of HBr to make a 42.5% HBr solution. What will the total volume of the solution be? 42.5 = 10.0 ml 100 x 42.5 x = ___________ 10.0 ml (100) ______ 42.5 42.5 x = 23.5 ml Hmmmm…..how much of the solution is just solvent (water)? percent composition = amount solute 100 amount solution 3. If a concentrated solution of hydrogen peroxide has a percent composition of 65%, how many mL of pure hydrogen peroxide would be contained in a 0.750 L solution? 65 = x_ 65 (0.750 L) = x 100 0.750 L 100 0.49 L = x 0.49 L (1000 ml) = 490 ml 1L percent composition = amount solute 100 amount solution 4. What mass (in grams) of NaCl is necessary to make a 5.0% NaCl solution using 82 ml (82 GRAMS) of water? JUST WATER! 5.0 = x _ 100 x + 82 5.0 (x + 82) = x (100) 5.0x + 410 = 100x 410 = 95x x = 4.3 grams NaCl ppm 106 = amount solute amount solution 5. For cavity prevention, the recommended concentration of fluoride ions in our drinking water is 0.7 to 1.2 parts per million (ppm). Too much fluoride can result in discolored teeth. If the concentration of F- in Orange County is 0.85 ppm, what mass of fluoride would be contained in a 7.2 gram tap water sample from and OCHSA bathroom? 0.85 = 106 x grams F7.2 gram 0.85 (7.2 gram ) = x grams F106 6.1 x 10-6 g F- ppm = amount solute 106 amount solution 6. What is the concentration of mercury (in ppm) if 3 grams mercury is found in a 15 kg sample of ocean water? 15 kg (1000g) = 15000 g 1kg x ppm = 3g 106 15000 g x = 200 ppm x ppm = 3 g (106 ) 15000 g ppm = amount solute 106 amount solution 7. What mass of mercury (in grams) would be contained in a 40.0 kg sample of ocean water at this same concentration? 40.0 kg (1000g) = 4 x 104 g 1kg 200 ppm = x g Hg 106 4 x 104 g 200 ppm(4 x 104 g) = x = 8 g Hg 106 El Agua Cristal es mejor porque ha sido filtrada por la naturaleza durante décadas, adquiriendo de manera natural los minerales necesarios para un perfecto equilibrio del organismo. Análisis químico mg/l (ppm) La NSF certifica que Agua Cristal Calcio 11.9 cumple con las más estrictas Magnesio 10.3 normas de calidad requeridas 0.1 por la FDA de los Estados Unidos. Hierro menos de Flúor menos de 0.1 Sodio 7.0 Un envase de 600 ml contiene: pH 6.63 Potasio 4.7 Sulfatos 4.0 Dureza del calcio 29.7 Dureza del 35.7 magnesio Alcalinidad total 67.8 S.T.D 184 8. You have 0.800 L of a 0.500 M HCl solution. How many moles of HCl does this solution contain? mol M L mol M x L mol 0.5 M x 0.8 L mol 0.400 mol HCl 9. You have 3.50 L of solution that contains 90.0 g of sodium chloride, NaCl. What is the molarity of that solution? 90.0 g NaCl (1 mol NaCl) = 1.54 mol NaCl (58.44 g NaCl) mol M L 1.54 mol NaCl 3.50 L 0.440 M NaCl mol 0.440 NaCl L 10. What volume of a 0.500 M solution of HBr is needed for a reaction that requires 32.5 g of HBr? 32.5 g HBr (1 mol HBr) 80.91 g HBr mol M L mol L M = 0.402 mol HBr 0.402 mol HBr 0.500 M 0.804 L of solution 2 problems, 5 minutes! The answers should add up to 82.6 11. Calculate the volume of water (in ml) needed to make a 4.00 M solution using 50.6 grams barium fluoride? ANSWER: 72.1 ml (formula = BaF2) 12. How many grams of potassium iodide must be added to 0.450 L water to make a 0.140M solution of this salt? ANSWER: 10.5 g (formula = KI) 13. What is the pOH of a 0.0075M nitric acid (HNO3)solution? pH = -log(0.0075) = 2.1 pOH = 14 – pH = 11.9 1 HNO3 1H+ + 1NO3Nitric acid is an acid and produces H+ in solution…..remember? [H+] = Macid Formulas: 14. What is the pH of a 0.0010 M solution of sodium hydroxide (NaOH)? pH = -log[H+] pOH = -log(0.0010) pOH = -log[OH-] [H+] = 10-pH = 3.0 [OH-] = Mbase [OH-] = 10-pOH NaOH is a base and produces pH = 11 OH- in solution…remember? 1NaOH 1Na+ + 1OH- pH + pOH = 14 15. What is the pH of a solution that contains 0.75 moles of hydrochloric acid (HCl) dissolved in 1.5 liters of water? pH = -log[H+] [H+] = [acid] [acid] = M = 0.75 moles/1.5L Formulas: = 0.50M pH = -log(0.50) pH = -log[H+] pOH = -log[OH-] pH = 0.30 [H+] = 10-pH [OH-] = 10-pOH pH + pOH = 14 16. What is the pH of a solution that contains 5.6 grams of sulfuric acid (H2SO4) dissolved in 650 ml water? pH = -log[H+] [H+] = [acid] [acid] = M = moles/L moles: 5.6 g H2SO4 (1 mole H2SO4 ) 98.09 g H2SO4 = 0.057090 moles Formulas: Liters: 650 ml water 0.65 L M = 0.057090 moles/ 0.65 L pH = -log[H+] pOH = -log[OH-] = 0.0878307 M +] = 10-pH [H pH = -log(0.0878307) [OH-] = 10-pOH = 1.1 pH + pOH = 14