Overview of Earth’s HeatTrapping Gases LESSON 4 Electromagnetic Spectrum http://9-4fordham.wikispaces.com/Electro+Magnetic+Spectrum+and+light Earth’s Magnetosphere The Earth’s Atmosphere (60 miles thick) http://www.grc.nasa.gov/WWW/k-12/airplane/atmosphere.html Sun’s Emission Spectrum able to penetrate Earth’s atmosphere The blue line indicates the approximate intensity of radiation that penetrates Earth's atmosphere at wavelengths from the ultraviolet (UV) through the visible to the infrared. Light at low UVC wavelengths is completely absorbed by the atmospheric ozone layer, so organisms on Earth have developed no tolerance to it. http://www.nature.com/nature/journal/v441/n7091/fig_tab/441299a_F1.html What does this penetrating energy do to Earth? Being light, infrared travels through space at the speed of light. Matter is not space and the Earth’s atmosphere is obviously matter. Heat is a property of matter. The rate of transmission is slowed as this energy enters the atmosphere. Work is thereby done; so heat is created. Some atmospheric molecules are more sensitive to this energy than others based on their molecular shape and bonds. http://www.windows2universe.org/physical_science/chemistry/molecules_vibrate.html Earth’s atmosphere http://www.agci.org/classroom/atmosphere/index.php Earth’s Atmospheric Composition CONSTITUENT CHEMICAL SYMBOL 99% BONDING Nitrogen N2 78.084 1 triple Oxygen O2 20.947 1 double Argon Ar 0.934 - CO2 0.035 2 double Carbon Dioxide Neon Ne 0.00182 - Helium He 0.00052 - CH4 0.00017 4 single Methane 1% MOLE % Krypton Kr 0.00011 - Hydrogen H2 0.00005 1 single 0.00003 2 bonds (1 triple, 1 single) - Nitrous Oxide N2O Xenon Xe 0.00001 Ozone O3 trace to 0.00080 2 single http://www.globalchange.umich.edu/globalchange1/current/lectures/Perry_Samson_lectures/evolution_atm/index.html What is a “Heat-Trapping Gas”? Objects that absorb all radiation incident upon them are called "blackbody" absorbers. The earth is close to being a black body absorber. Gases, on the other hand, are selective in their absorption characteristics. While many gases do not absorb radiation at all some selectively absorb only at certain wavelengths of energy. Those gases that are "selective absorbers" of solar energy are the gases we know as “heat-trapping gases”. http://www.globalchange.umich.edu/globalchange1/current/lectures/Perry_Samson_lectures/evolution_atm/index.html 2500 nm 3330 nm 5000 nm 10000 nm 1000000 nm http://www.elmhurst.edu/~chm/vchembook/images/irgreengas.JPEG http://www.elmhurst.edu/~chm/vchembook/images/irwater.JPEG http://www.elmhurst.edu/~chm/vchembook/images/irmethane.JPEG http://www.elmhurst.edu/~chm/vchembook/images/irN2O.JPEG Greenhouse gas ABSORBANCE (in white) http://en.wikipedia.org/wiki/File:Atmospheric.transmittance.IR.jpg Effect of Heat-Trapping Gases http://mrsdlovesscience.com/greenhouse/greenhouse.htm l CO2 levels (parts per million) over the past 10,000 years. Blue line from Taylor Dome ice cores (NOAA). Green line from Law Dome ice core (CDIAC). Red line from direct measurements at Mauna Loa, Hawaii (NOAA). This Is What Worries Many Scientists 0 http://www.realclimate.org/index.php/archives/2004/12/temperaturevariations-in-past-centuries-and-the-so-called-hockey-stick/ Simplified Example of a Combustion Reaction