TMT science & instrument workshop Oct. 16-17, 2013 @ Tokyo Water and Organic Molecules in Protoplanetary Disks - High-R Spectroscopy Hideko Nomura (Tokyo Tech.) Matthew J. Richter (UC Davis) §1 Introduction From protoplanetary disk to planets (e.g., Hayashi et al. 1985) Dust growth & settling Planetisimal Observationally diagnose formation planet formation theory and origin of materials Collisional growth in our Solar System of planetisimals Planet formation (C) Newton Press Dispersal of gas Obs. of Gas in Protoplanetary Disks UV H2 Lyman-Werner (sub)mm band transitions TMT will be able to 12 observe IR lines CO 6-5, 3-2, 2-1, 1-0, Optical 13CO 3-2, 2-1, 1-0, with high-R & high sensitivity [OI] 6300A C18O 2-1, 1-0, NIR HCN, HNC, DCN, CN, H2 v=1-0 S(1), S(0), 34S, C H, H CO, CS, C 2 2 CO Dv=2, Dv=1, etc. +, H13CO+, DCO+, HCO MIR H2 v=0-0 S(1), S(2), S(4) N2H+, HC3N, c-C3H2, etc. H2O, OH, HCN, C2H2, CO2, NH3 (Ground & Spitzer Space Telescope) 100AU ALMA SV TW Hya FIR [OI] 63um, 145um, CO, H2O, CH+, HD, etc. (Herschel Space Observatory) HCO+(4-3) Need for High-R Spectroscopy Typical width of IR lines from PPDs ~ 10-20km/s →need high-R spectroscopy (R~15,000) for detection need very high-R (R~100,000) for analysing profiles AB Aur Gemini/TEXES (R>80,000) H2 S(4)@8mm S(2)@12mm S(1)@17mm F~10-14erg/s/cm2, Dv~10-20km/s (Bitner et al. 2007, 2008) Kepler rotation Need for High-R Spectroscopy Typical width of IR lines from PPDs ~ 10-20km/s →need high-R spectroscopy (R~15,000) for detection High-R spectroscopy@TMT will need very high-R (R~100,000) for analysing profiles enable us to detect fainter lines VLT/CRIRES Subaru/IRCS (R=20,000) (R=100,000) & analyse profiles of weaker lines SR21 HD141569 Inner hole @ 7AU (Goto et al. 2006) 4.7mm CO line MICHI profiles (Y.K. Okamoto) Kepler rotation → Line emitting Inner hole @ 11AU regions (Pontoppidan+ 2008) → See also Matt Richter’s poster Water & Organic Mol. in PPDs Detect H2O snow lines Detect complex organic molecules with high-R spectroscopy @ TMT ESA H2O, CO2, CH4, CH3OH, H2CO, NH3, etc. Halley §3 H2O snow line a §2 formation of organic mol. §2 Formation of Organic Moleclues in PPDs Observed Interstellar Molecules CH+ HCN H2CO HC3N CH3OH HC5N HCOOCH3 HC7N CS HNC H2CS HCOOH CH3CN CH3CCH CH3C3N HC9N CO HCO H2CN CH2NH CH3NC CH3NH2 CH3COOH HC11N CN OCS HNCO CH2CO CH3SH CH3CHO CH2CHCHO C2H5CN C2 CH2 HNCS NH2CN NH2CHO CH2CHCN CH2OHCHO CH3C4H C6H H2C6 CH3C5N Aminoc-C3H acids in comet CO+ C3 c-C3H2 H2C4 STARDUST CF+ CO2 @ C3N H2C3 HC3NH+ CH CN- C2H C2O C3H C4H C5H (Elsila et CH2CN al. 2009)C5NC3O c-C2H4O CH3OCH3 CH2CHOH C2H5OH C6H- CH3CONH2 Amino acids in meteorites HCO+ CH3 HNCCC ⇔ C2H2 relation HOC+ CH4 with HCS+ HOCO+ H2COH+ interstellar molecules ? C2S C3S HCNH+ C3N- HCCNC C4H- by ~1975 CH3COCH3 OHCH2CH2OH C2H5OCHO → amino acids NH2CH2COOH? ? after ~1997 C8H- Complex Molecule Fomration on Grain Surface cold: < 20K H C, O, N, S, CO, … grain surface desorption UV, CR, X-rays themal warm: 30-50K NH2, HCO, … UV CH3O grain surface \ migrate Saturated mol. CH4, H2O, NH3, H2S, CH3OH, … Unsaturated mol. HCOOCH3, NH2CHO, … (e.g., Garrod+ 2006, 2008) Complex molecules are formed on grains More complex molecules on warm grains Complex Molecules on Warm Grains (Harada et al. 2010, Garrod et al. 2008) CH3OH Z/R Tdust Methanol will be observable only at 30-50K CH3OH line spectra disk even with ALMA… 3 4 6outer 7 8 9 10 ↓ Detect complex molecules & understand C2H5OH CH3COCH3 grain surface reactions at planetaceton forming region with TMT! Z/R Density [Jy] Flux ALMA band Frequency R [AU] [GHz] R [AU] Strong methanol lines Complex mol. are formed on warm grains at will be observable T~30-35K(~50A) = cometary region (Walsh, Millar, HN et al. 2013, submitted) OSU chemical network MIR HCOOH Lines @ TMT! telluric HCOOH Try first detection of MIR formic acid lines 2 Line flux [erg/s/cm ] 5e-17 from protoplanetary Line widthdisks [km/s]with TMT! 20 Z/R ALMA TMT! R [AU] R NELF [erg/s/cm2] S/N Integration time [min] 15,000 5e-16 3 15 §3 H2O Snow Line CO Snow Lines in Disks HD163296 SMA CO6-5@691GHz 13CO2-1@220GHz CO3-2@346GHz C18O2-1@220GHz dust settling CO2-1@231GHz C17O3-2@337GHz H2O snow lines aroundCOlow mass stars will snow line @ R~155AU et al. 2011) be difficult to access even with(QiALMA… TW Hya ↓ ALMA SV ALMA Detect@band7, H2O snow lines by cycle 0 + 5-4 DCO obs. with high-spectral res. @ TMT! N2H+ 5-4 [DCO+] /[HCO+] =0.3 (Mathews et al. 2013) CO snow line @ R~30AU (Qi et al. 2013c) Obs. of water lines from PPDs H2O, OH, HCN, C2H2 Spitzer/IRS AA Tau (Riviere-Marichalar+ 2012) [OI] Herschel/HIFI TW Hya H2O Herschel/PACS (Hogerheijde+ 2011) AA Tau cold FIR lines (Carr & Najita 2008) hot MIR lines warm FIR lines Spitzer hot H2O@10-35mm, TTSs: detect, HAEBEs: upper limits Herschel warm H2O TTSs, HAEBEs: @55-180mm Herschel cold H2O @267mm, 539mm, TW Hya, HD100546 H2O snow lines in PPDs Spitzer/IRS model TW Hya Spitzer/IRS Inner hole AA Tau H2O line ratios + disk model DR Tau → predict H2O snow lines Herschel PACS HIFI AS 205 The results are model dependent… model with snow line H2O Snow line @ ~1AU (Meijerink+ 2009) H2O Snow line @ ~4AU H2O Snow Line by High-R Obs. Line width ~ 10-20km/s →need high-R spectroscopy (R~100,000) for analysis Line fluxes @ Spitzer > 1e-14 erg/s/cm2 (Carr & Najita 2011) TMT will be able to analyze statistical TMT/MICHI properties of snow lines! 2] LineH2O flux [erg/s/cm 1e-15 Kepler rotation Line width [km/s] R NELF [erg/s/cm2] S/N Integration time [min] 20 120,000 2e-16 25 20 Summary High-R spectroscopy of transition lines of water & organic molecules in PPDs Detect H2O snow line by very high (R~100,000) spectroscopy for understanding rocky/gaseous planet forming regions Detect complex organic molecules and understand grain surface reactions in planet forming regions by high (R~15,000) spectroscopy for predicting formation of more complex molecules