Chapter 8 Describing Chemical Change Types of Chemical Reactions Reactions in Aqueous Solution Chapter 8.1 Describing Chemical Change Word Equations Chemical Equations Balancing Chemical Equations Word Equations Reaction – one or more substances (the reactants) change into one or more new substances(the products) Reactants Products =? Yields, gives or reacts Word Equations As reactants are converted to products, the bonds holding the atoms together are broken and new bonds are formed. REMEMBER: The atoms are neither created nor destroyed, just rearranged. (Law of Conservation of Mass) Word Equations Rust Iron reacts with oxygen to produce iron(III) oxide (rust) Iron + Oxygen Iron(III) Oxide (reactants) (yields) (products) Word Equations Hydrogen peroxide reacts to form water and oxygen gas. Hydrogen peroxide water + oxygen MnO2 H2O2(aq) H2O(l) + O2(g) Word Equations Burning of Methane Methane + Oxygen Carbon Dioxide + Water Chemical Equations Iron + Oxygen Iron(III) Oxide Fe + O2 Fe2O3 Now add physical states Fe(s) + O2 (g) Fe2O3 (s) Chemical Equations Reactions with a catalyst Catalyst – a substance that speeds up the rate of a chemical reaction, but is not used up in the reaction. A catalyst is written above the arrow Chemical Equations Manganese(IV) oxide catalyzes the decomposition of hydrogen peroxide. Balancing Chemical Reactions Each side of the equation has the same number of atoms of each element. C(s) + O2(g) 1 carbon, 2 oxygen 1 carbon, 2 oxygen CO 2(g) Balancing Chemical Reactions H2(g) + O2(g) H2O(l) 2 hydrogen, 2 oxygen 2 hydrogen, 1 oxygen Balance 2 H2(g) + O2(g) 2 H2O(l) Balancing Chemical Reactions Rules 1) Determine the correct formulas 2) Write the formulas for the reactants on the left and the products on the right. Place a in between. If there are two or more reactants or products, use a + in between. 3) Count the number of atoms of each element. Balancing Chemical Reactions Rules 4) Balance the elements one at a time until you have equal numbers of elements on each side 5) Make sure all numbers are in their smallest whole number ratio. Chapter 8.2 Types of Chemical Reactions Classifying Reactions Combination Reactions Decomposition Reactions Single-Replacement Reactions Double-Replacement Reactions Combustion Reactions Predicting Products of Reactions Classifying Reactions Identify the five general types or reactions: Combination Reactions Decomposition Reactions Single-Replacement Reactions Double-Replacement Reactions Combustion Reactions Combination Reactions Two or more substance combine to form a single substance. General Reaction: R + S = RS Example: 2Mg(s) + O2(g) 2 MgO(s) Decomposition Reactions A single compound is broken down into two or more substances. General Reaction: RS = R + S Example: 2HgO(s) 2 Hg(l) + O2(g) Single-Replacement Reactions (Single Displacement Reactions) One element replaces a second element in a compound. General Reaction: T + RS = TS + R Example: 2K(s) + 2H2O(l) 2KOH(aq) + H2(g) http://www.kentchemistry.com/links/Kinetic s/PredictingSR.htm Double-Replacement Reactions Exchange of positive ions between two reacting compounds. General Reaction: RS + TU = RU + TS R+S- + T+U- = R+U- + T+S- Example: K2CO3(aq) + BaCl2(aq) 2KCl(aq) + BaCO3(s) http://www.kentchemistry.com/links/Kinetic s/DRFlash.htm Combustion Reactions An element or compound reacts with oxygen often producing energy as heat or light. General Reaction: CxHy + (x + y/4) O2 xCO2 + (y/2)H2O Example: CH4 (g) + 2O2 (g) CO2(g) + 2H2O (g) Name each type of reaction 1) 2Mg(s) + O2(g) 2 MgO(s) 2) 2HgO(s) 2 Hg(l) + O2(g) 3) CH4 (g) + 2O2 (g) CO2(g) + 2H2O (g) 4) 2K(s) + 2H2O(l) 2KOH(aq) + H2(g) 5) K2CO3(aq) + BaCl2(aq) 2KCl(aq) + BaCO3(s) Name each type of reaction 1) 2Mg(s) + O2(g) 2 MgO(s) 2) 2HgO(s) 2 Hg(l) + O2(g) Combustion 4) 2K(s) + 2H2O(l) 2KOH(aq) + H2(g) Decomposition 3) CH4 (g) + 2O2 (g) CO2(g) + 2H2O (g) Combination Single Replacement 5) K2CO3(aq) + BaCl2(aq) 2KCl(aq) + BaCO3(s) Double Replacement Chapter 8.3 Reactions in Aqueous (aq) Solutions Net Ionic Equations Predicting the Formation of a Precipitate Net Ionic Equations AgNO3(aq) + NaCl (aq) AgCl(s) + NaNO3 (aq) Double Replacement Reaction Most ionic compounds dissociate (separate) into ions (cations and anions) when they dissolve in water. When all ions dissociate, we write the equation with the charges on it. = Complete Ionic Equation Complete Ionic Equation Ag+(aq) + NO3-(aq) + Na+(aq) Cl-(aq) AgCl(s) + Na+(aq) + NO3-(aq) The equation can be simplified by crossing out any ions that do not participate in the reaction. You do this by canceling out ions that appear on both sides. Ag+(aq) + NO3-(aq) + Na+(aq) Cl-(aq) AgCl(s) + Na+(aq) + NO3-(aq) You are left with the Net Ionic Equation: Ag+(aq) + Cl-(aq) AgCl(s) Pb(s) + AgNO3(aq) Ag(s) + Pb(NO3)2(aq) Pb(s) + Ag+(aq) + NO3 -(aq) Ag(s) + Pb2+(aq) + 2NO3-(aq) Pb(s) + Ag+(aq) Ag(s) + Pb2+(aq) Need to balance charges Pb(s) + 2Ag+(aq) 2Ag(s) + Pb2+(aq) Predicting the Formation of a Precipitate Table F in reference table