1 Tempelet (Svalbard) Loggelinje Silicified Carbonates Carbonates Midterhuken (Svalbard) Loggelinje chalk 2 1) Porosity Ideal Porosity: Cubic packing = 47.6 % Vp Vtot 100 % Vtot Vmatrix 100 % Vtot Vp = pore volume Vmatrix = grain volume Vtot = bulk volume Rombic packing = 26 % Porous sandstone Cubic packing, different grain size = 12.5 % water Pore size: 10 - 50 m oie Sand grain 3 3 Effective porosity eff is the porosity of interconneceted pores Residual porosity res is the porosity of the remaining pores Total porosity: tot = eff + res Typical effective Sandstone: = 10 - 40 % depending on grain shape Limestone and dolomite: = 5 - 25 % depending on fractures porosity: How do we measure the porosity eff ? 1. In situ measurements in the reservoir (well logging) 2. Core analysis: drilling cores from the reservoir followed by laboratory analysis • Drilled cores (d = 2,5 - 5´´) • Drilling sylindrical core plugs (d = 1,5´´, h = 3 ´´) • Clean and dry plugs 4 4 2) Saturation A porous medium (reservoir or core plug) usually contains several fluids: water, oil, gas Saturation = the fraction of the total pore volume Vp which contains the actual fluid Water saturation:S w Vw Vp Oil saturation: S o Vo Vp Gas saturation: S g Vg Vp Normally, the entire pore volum will be filled be fluids, hence: S w So S g 1 The porosity determines the amount of oil in the reservoir unit Rm3 OIP = V So = V (1 - Swc) Oil In Place (OIP): V = the totale pore volume (PV) So = the oil saturation Swc = “connate water” – the original water saturation Stock Tank Oil Originally In Place (STOOIP): STOOIP = OIP /Bo=V (1 - Swc)/Bo unit Sm3 Bo = “oil formation volum factor” = the ratio between the oil volume in the reservoir and the oil volume in the stock tank at the surface (Rm3/Sm3). Often Bo > 1 because gas is released from the oil when brought to the surface. 5 5 3) Miscible and immiscible fluids The molecules in a liquid is held together by electrostatical forces (van der Waals forces) acting between the molecules a) water and oil are immiscible The van der Waals force is larger between like molecules. b) water and alcohol (ethanol) are miscible The van der Waals force is larger between unlike molecules. 6 6 4) Wettability Pipette with water Wettability is the ability of one fluid to spread on a solid surface in the presence of other fluids The wettability is defined by the wetting angle Oil Water drop Water wet oil wet Neutrally wet oil water water oil 180o oil solid water Vann solid =0 = 90o = 0 - 30o strongly water-wet = 30o - 90o preferably water-wet = 90o – neutrally wet = 90o - 150o preferably oil-wet = 150o - 180o strongly oil-wet Wettability may also be quantified by capillary pressure properties. We will return to this later. solid 180o Most oil reservoirs are water wet: water oil Sand grain 7 7 5) Viscosity Viscosity is internal fluid friction Shear forces act between different fluid layers and between the fluid and container walls v F y dv v F The velocity gradient in the y-direction: Shear tension: dy y A Empirical studies dv = the viscosity coefficient or shows that for simply the viscosity dy most fluids: This is a Newtonian fluid Unit: 1 Pas = 1 Ns/m2 = 10 P (poise) 8 6) Darcy’s law og permeability A pressure difference p is needed for a fluid to flow through a porous medium. Henri Darcy (1856) discovered that the volume flow rate Q through a filter of cross section A: Q a A p where the proportional constant a depends on both the fluid and the filter The modern version av Darcy’s law for fluid flow in a porous medium (e.g a core plug): L Q KA pB p A Q L core plug A pB pA Q = volume per unit time (volume flow rate) K = the absolute permeability of the medium = the fluid viscosity Q L m3 m Permeability 2 K Pa s m unit A pB p A s m 2 Pa This is a rather large unit. Therefore we define a new unit der:1 darcy (D) 1cm3 /s 1cm 3 1 cm 2 / s 12 2 1 darcy 1cP 10 Pa s 0.98692 10 m 2 5 cm 1atm 1.01325 10 Pa 1 millidarcy (mD) = 10-3 D = 0.98692·10-15 m2 9 9 7) Relative permeability Single phase flow: The absolute pemeabilitty K i Darcy’s equation is independent of the fluid, and depends only on the properties of the porous medium. Multiphase flow: Several immiscible fluid phases (water, oil, gas) flow simultaneously through the porous medium A sentral question arises: Does Darcy’s law and the permeability concept also apply when there are more than one fluid flowing in the porous medium? The flow possibility for one fluid may then depend on the saturation of the fluids present Oil may flow more easily in this case: water along the Sand grain pore walls (water wet) than here: oil olje Sand grain Sand grain Sand grain oil Water will flow more easily than the oil We see that the oil will flow more easily when more oil is present (large So) 10 Capillary pressure curves in capillary tubes One simple capillary tube oil h water pc g 2 ow cos 1 g R oil Height; Cap. press A battery of tubes with varying radius and therefore varying capillary pressure: oil Water/oil contact (OWC) water 0 Fre water level Siw Water sat. (Sw) (FWL) 1.0 water small Tube radius (R ) large • There is a linear relation between capillary pressure pc and height h. 11 • The total water saturation Sw below h in all tubes decrease when the tubes get thinner Darcy’s equations u1 K1 p1 1 g u2 K2 p2 2 g 3 equations 1 1 ( p1 ) og 2 2 ( p2 ) Equations of state Viscosity 3 equations 1 1 ( p1 ) og 2 2 ( p2 ) Continuity of equation Saturation The capillary pressure ( 1S1 ) 0 t ( 2 S2 ) ( 2u 2 ) 0 t ( 1u1 ) S1 S2 1 p2 p1 pc (S1 ) Total 14 equations 2 equations 2 equations 1 equation 1 equation 1 equation 1 equation 12 From the continuity equations we have: uw S w ( f wu ) S w f w S w u 0 x t x t x t Hence Introduce Finally we get: u f w S w 0 x t S w f w w w x u d w S w S w S w w 0 dS w x x x t This is called the saturation equation 2. order partiell differential equation for Sw(x,t); non-linear with coeffisients which are functions of the independent variable Sw . The equation must be solved numerically. When Sw has been found, we may calculate fw and uw og uo, and finally pw the po, all as functions og x and t. 13 1414 Well logging Goal: Petrophysics as function of depth in reservoir •lithological (rock type) •porosity •saturation tool A tool with instruments lowered into the borehole. The instruments in the probe measures the properties of formation and transmits data via mud to the surface Reservoir 15 Tempelet (Svalbard) Loggelinje Silicified Carbonates Carbonates Midterhuken (Svalbard) Loggelinje chalk 16 Two methods a) Measurement While Drilling (MWD) Logging While Drilling (LWD) Tool at the bottom of the drill string. Signals transmitted as pressure waves through mud. Loggesonde Kraftkilde Øvre transmitter Slammotor Øvre transmitter Mottaker antenne Resisitivitetssensor Borekrone Gammasensor b) Wireline Logging Drill string is pulled up and the probe is sent down with a wire that transfer data to / from the logging instruments. Expensive, less common 17 Log tools must withstand: high reservoir pressure, 1000 atm high reservoir temperatures, 120 ° C large mechanical stresses For time-efficient electronics The tools measure into the formation outside invasion zone for drilling fluids Drilling Fluids (mudfiltratet) penetrates the formation (invasion). This may give false results. 18 1. Neutron-log Atom nuclei consist of positively charged protons and neutrons without charge Protons and neutrons have roughly the same mass. Sonde Clamp from a source in the tool (1 MeV = 1.6 ° 10-13 Joules) • Neutrons lose energy when colliding with atomic n Neutron source Gammadetector • Neutrons with energy 3-4 MeV sent into the formation Formation n n n n Si kjerne nuclei, hydrogen, in the formation •When the energy is reduced to a they may be “captured” by nuclei • This excited nuclei emit gamma rays • This radiation can be detected in a gamma- detector in the tool 19 Most effective if the neutrons collide with protons (p), ie hydrogen nuclei Much hydrogen ….. Increased gamma radiation. Sonde Clamp Formation p p n n Neutronsource Gammadetector n n p p n Si kjerne If the detector detects gamma radiation we have a neutron-gamma log Most probes simultaneously measure the epithermal neutrons (En> 1 eV). It is called the neutron-neutron log The response from nøytronloggen is a measure of hydrogen-containing fluid (oil, water, gas) in the formation ie, hydrogen index (HI) Since these fluids are located in the pores, it is a measure of porosity. Problem 1: Response from all hydrogen. Also from water bound to clay.. Problem 2: The gas has a low HI, - underestimation of porosity. - Detect gas layer. 20 2. Gamma-log It measures naturally occurring radioactivity in the formation. Only gamma-rays have sufficient penetration ability in the formation of reaching the detector in the logging tool Sonde Formatjon Radioactive isotopes: Gammadetector 40K nuclei 238U nuclei • Occur in the earth (crust) • Type and rate of radioactivity depends on the mineral typ • Depends on rock type, occurs particularly in shale • Radioactivity is a "finger print" of great interest to the lithologic and stratigraphic description of the reservoir 21 Important isotopes 1) 40K ; T1/2 = 1.3·1010 year 40K + E=1.46 MeV 40Ca 40Ar 2) 232Th ; T1/2 = 1.4·1010 year Thorium-series: 232Th + 228Ra 208Pb 3) 238U ; T1/2 = 4.5·109 year Uranium-series: 238U + 234Th 8 6 206Pb 22 The most important minerals that may contain radioactivity are: 1) Quartz [SiO2] (sandstone) – Clean regular lattice – little room to accommodate radioactive isotopes 2) Carbonates (chalk) [ CaCO3 ] – Deposits of living organisms - clean 3) Dolomitt [ CaMg(CO3)2 ] – Traces of Uranium 4) Feltspat [KAlSi3O8] and mica clay and shale - Crystalline, containingAl, K, Na, Ca, Ba – silicates poor crystal structure, ie foreign atoms (eg. radioactive) can take place: thus much radioactivity 23 Petrophysics from gamma-log: 1) Lithology (rock type) – Identify shale and clean sand (in addition to mud log) 2) Clay content. Gamma-index: GRlog GRmin I GR GRmax GRmin 0 < IGR < 1 GRmin = intensity of the clean zone (without clay / shale) GRmax = intensity of the assumed pure clay zone GRlog = intensity of the current zone 3) The turning points in the IGR-curve defines the transition between the layers. 4) Depth Reference. Can be used to determine casing need. 24 3. Density log (gamma-gamma log) mud Formation Principal: A radioactive source (60Co, 137Cs) - gamma radiation. tool clamp Gammadetectors Radioactiv source Gamma radiation (photons) scattered from electrons of atoms in the formation. Photons lose energy. Those who lose the most energy are those scattered back the probe. This decreases the number of electrons with the original energy recorded in the detectors. led Borehole Absoprbsjonskoeffisienten is proportional to the number electrons in the Z atom (molecule) which in turn depends mass density b . Gamma-gamma log measures density in formation 25 Bulk Mass of formation is the sum mass of pore volume (liquid) and matrix (rock) : b f (1 ) m Porosity: m b m f The matrix density m and the fluid density f til reservoir fluids is known, porosity may be found vi by measuring b with the density log. We must expect that the density-log records: •High density of shale and cemented layers •Greater density in the oil-bearing sandstone layers than the layer of gas •Greater density in lower porosity layers •Slightly greater density in the water zones than in the oil zones 26 Gamma-log Neutron-log Density-log Sandstone Gas Sandstone Semented gamma-log: Sandstone: low natural gamma • high for shale Low neutron pga gas (low HI) • fingerprint for minerals Cemented sandstone: high density • identify layers Oil Shale Takbergart Oil Semented Shale High Shale:for highoil/water gamma, much water • high • low for gas Sandstone with oil: density log and for neutron log depends • high shale Increasing effect on the density log the transition to the water zone Low Sandstone Sandstone with oil: HI high, high neutron-log, high density Cemented sandstone: high density Neutronlog: on porosity Sandstone Density-log (gamma-gamma log): • high in shale and cemented layers • higher in oil/water compared to gas Vann Semented Coal Shale: high radio activity, A lot of water (bound in clay), high density Cementert sandstone: high density Coal: high water content, inc. neutron Sandstones with low porosity, Increased density, less water 27 Phase Coherency 28 CPMG Sequence 29 Slow Relaxation Fast Relaxation T2 is a measure of Poresize 30 Poresize Distribution -NMR 31 NMR 1 S 1 S 1 1 Ti V Tib V Tis i = 1,2 1H 1H 32 MWD forts … PTEK100 H2011 - Boreteknologi Azimuthal Deep Resistivity (ADR) tool 3333 BAT Sonic tool 3434